Skip to main content
Log in

Self-propagating high-temperature synthesis for the deposition of thermal-sprayed coatings

  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

Abstract

The paper reviews the relevant literature and results of the author’s research into self-propagating high-temperature synthesis (SHS) used to deposit protective thermal-sprayed coatings. The compositions of different SHS-produced powders, which are used to deposit thermal-sprayed coatings, are indicated. The combination of spraying and synthesis of the material to form coatings by the interaction of composite powder particles is considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. G. Merzhanov and I. P. Borovinskii, Self-Propagating High-Temperature Synthesis of Inorganic Compounds [in Russian], Moscow (1970), p. 150.

  2. A. G. Merzhanov, V. M. Shkiro, and I. P. Borovinskaya, A Method to Synthesize Refractory Inorganic Compounds [in Russian], Inventor’s Certificate No. 255221 USSR, Otkryt. Izobret., No. 10 (1971).

  3. E. A. Levashov, A. S. Rogachev, V. I. Yukhvid, and I. P. Borovinskaya, Physical, Chemical, and Technological Fundamentals of Self-Propagating High-Temperature Synthesis [in Russian], BINOM, Moscow (1999), p. 176.

    Google Scholar 

  4. V. I. Itin and J. S. Naiborodenko, High-Temperature Synthesis of Intermetallic Compounds [in Russian], Izd. Tomsk. Univ., Tomsk (1989), p. 214.

    Google Scholar 

  5. Yu. Borisov and A. Borisova, “Application of self-propagating high-temperature synthesis in thermal spraying technology,” in: Proc. of NTSC’93 (Anaheim, USA, June 7–11, 1993), ASM Int. (1993), pp. 139–144.

  6. V. I. Yukhvid, “SHS-metallurgy: Casting and surfacing,” in: Technology: Equipment, Materials, and Processes [in Russian], Moscow (1988), pp. 57–64.

  7. A. S. Shteinberg and V. B. Solomonov, “SHS-welding,” in: Technology: Equipment, Materials, and Processes [in Russian], Moscow (1988), pp. 75–85.

  8. Yu. Borisov, A. Borisova, and L. Shvedova, “Transition metal — nonmetallic refractory compound composite powders for thermal spraying,” in: Proc. of ITSC’86 (Montreal, Canada, September 8–12, 1986), Pergamon Press (1986), pp. 323–330.

  9. R. W. Smith, M. Mohanty, E. Shtessel, and A. Verstak, “Self propagating high temperature synthesis (SHS) of thermal spray powders,” in: Proc. of ITSC’95 (Kobe, Japan, May 22–26, 1995), High Temperature Soc. Jap. (1995), pp. 1121–1126.

  10. S. Yu. Sharivker and A. G. Merzhanov, SHS-Powders and Their Processing [in Russian], Chernogolovka (2000), p. 123.

  11. B. M. Vol’pe, V. V. Yevstigneev, I. V. Milyukov, et al., “SHS of disperse nickel aluminides and their protective coatings,” Fiz. Khim. Obrab. Mater., No. 1, 50–54 (1996).

  12. B. M. Vol’pe, V. V. Yevstigneev, I. V. Milyukov, et al., “SHS of disperse Ti-Al materials and their protective coatings,” Fiz. Khim. Obrab. Mater., No. 2, 73–79 (1995).

  13. P. A. Vitiaz, A. F. Ilyushchenko, T. L. Talako, et al., “High-speed gas-flame and detonation spraying of powders iron aluminides produced by self-propagating high-temperature synthesis,” in: Powder Metallurgy [in Russian], Issue 26, Minsk (2003), pp. 135–141.

  14. P. Lintula, J. Maunu, P. Vuoristo, and T. Mäntylä, “Production of TiC-based cermet and TiC-Al2O3 thermal spray powders by SHS,” in: 5th Int. Symp. Self-Propagating High-Temperature Synthesis (SHS-99), Moscow (1999), pp. 81–82.

  15. Yu. S. Borisov, B. A. Polyanin, I. N. Gorbatov, et al., “Production and properties of plasma-sprayed composite-powder coatings based on refractory compounds,” in: Abstracts of Sci.-Tech. Conf. on Composite Coatings [in Russian], Zhitomir (1981), pp. 24–25.

  16. A. G. Merzhanov, “SHS and powder metallurgy,” Adv. Powder Metallurgy Particulate Materials, 9, 341–368 (1992).

    Google Scholar 

  17. I. N. Gorbatov, V. M. Shkiro, A. S. Terent’ev, et al., “Studying the properties of thermal-spray coatings and composite powders of titanium and chrome nickel-carbides,” Fiz. Khim. Obrab. Mater., No. 4, 102–106 (1991).

    Google Scholar 

  18. I. N. Gorbatov, N. S. Il’chenko, A. S. Terent’ev, et al., “Effect of cladding double titanium-chrome carbide on the properties of plasma-sprayed coatings,” Fiz. Khim. Obrab. Mater., No. 3, 69–73 (1991).

    Google Scholar 

  19. I. N. Gorbatov, A. D. Panasyuk, L. K. Shvedova, et al., “Thermal-sprayed composite-powder coatings based on titanium-chrome carbide,” Zashch. Pokryt. Metal., No. 25, 22–25 (1991).

    Google Scholar 

  20. R. Radhakrihnan, S. B. Bhaduri, and C. N. Henager, “Reactive synthesis of Ti3SiC2-SiC composites,” in: 5th Int. Symp. on Self-Propagating High-Temperature Synthesis (SHS-99), Moscow (1997), p. 115.

  21. R. Knight, R. W. Smith, M. Mohanty, and E. A. Shtessel, “Low pressure plasma sprayed SHS MoSi2/SiC composite coatings,” in: Proc. of NTSC’95 (Houston, USA, September 11–15, 1995), ASM Int. (1995), pp. 743–748.

  22. P. Vitiaz, A. Belyaev, T. Talako, and V. Koval, “Plasma coating from synthesized composite powders,” in: Proc. of UTSC’99 (Düsseldorf, Germany, March 17–19, 1999), DVS-Verl., Düsseldorf (1999), pp. 293–295.

    Google Scholar 

  23. P. A. Vitiaz, A. V. Belyaev, T. L. Talako, et al., “Structure and properties of thermal-sprayed composite coatings based on iron and nickel aluminides,” in: Proc. Int. Conf. on Laminated Composite Materials [in Russian], Volgograd (1998), pp. 159–161.

  24. E. D. Manoilo, T. L Talako, and A. V. Belyaev, “Gas-flame spraying of coatings of synthesized composite materials with solid-phase inclusions,” in: Powder Metallurgy [in Russian], Issue 21, Minsk (1998), pp. 69–73.

  25. K. G. Show, K. P. Mc. Coy, and J. A. Trogolo, “Fabrication of composite spray powders using reaction synthesis,” in: Proc. 7th NTSC (Boston, USA, June 20–24, 1994), ASM Int., Boston (1994), pp. 509–514.

    Google Scholar 

  26. B. A. Veprik, M. V. Kurylev, V. A. Korenkov, and V. A. Mukazhanov, “Composite SHS-powder of aluminum oxide with chrome for a plasma spraying,” in: Abstracts Region. Conf. of Young Scientists and Experts of Research Organizations and Enterprises on Modern Materials in Mechanical Engineering [in Russian], Perm (1990), p. 14.

  27. B. A. Veprik, M. V. Kurylev, and V. A. Korenkov, “Structure of Cr-Al2O3 SHS-composite coatings,” in: Superhard and Composite Materials and Coatings and Their Application [in Russian], Kiev (1991), pp. 57–59.

  28. P. Vitiaz, A. Verstak, T. Azarova, and T. Talako, “Titanium carbide in wear resistant coatings,” in: Proc. of 9th NTSC (Cincinnati, USA, October 7–10, 1996), ASM Int., Cincinnati (1996), pp. 169–176.

    Google Scholar 

  29. P. Vitiaz, T. Azarova, T. Talako, and A. Ilyuschenko, “Composite Fe/TiC powders for wear resistance coatings using plasma spray process,” in: Proc. 1st UTSC (Indianapolis, USA, September 15–18, 1997), ASM Int., Indianapolis (1997), pp. 131–139.

    Google Scholar 

  30. A. Ilyuschenko, T. Azarova, B. Wielage, et al., “Microstructure-properties relationship,” in: Proc. UTSC (Düsseldorf, Germany, March 17–19, 1999), DVS-Verl., Düsseldorf (1999), pp. 35–38.

    Google Scholar 

  31. B. Wielage, S. Steinhauser, T. Schnick, et al., “Thermal spraying of titanium carbide composite materials,” in: Proc. UTSC (Düsseldorf, Germany, March 17–19, 1999), DVS-Verl., Düsseldorf (1999), pp. 301–305.

    Google Scholar 

  32. T. Azarova, P. Vitiaz, B. Wielage, et al., “Coherences between structure and properties of TiC containing thermal spraying coatings,” in: Proc. ITSC (Essen, Germany, March 4–6, 2002), DVS-Verl., Essen (2002), pp. 96–101.

    Google Scholar 

  33. J. M. De Paco, J. Nutting, J. M. Guilemany, et al., “Structure-properties relationships of TiC-Ni-Ti and (Ti, W)C-Ni powders manufactured by the SHS process and the resultant HVOF-sprayed coatings,” in: Proc. UTSC (Cincinnati, USA, October 7–10, 1996), ASM Int., Cincinnati (1997), pp. 935–942.

    Google Scholar 

  34. J. M. Guilemany, J. M. De Paco, J. R. Miguel, et al., “Corrosion resistance HVOF coatings based upon TiC + NiTi and(Ti, W) C + Ni,” in: Proc. 15th ITSC (Nice, France, May 25–29, 1995), ASM Int., Nice (1998), pp. 57–61.

    Google Scholar 

  35. M. Mohanty and R. W. Smith, “Plasma spray processing of TiC-reinforced coatings for wear protection,” in: Proc. 8th NTSC (Houston, USA, September 11–15, 1995), ASM Int., Houston (1995), pp. 561–566.

    Google Scholar 

  36. K. G. Shaw and J. H. Reinshagen, “Powder production of nickel and iron aluminides,” in: Proc. 4th Conf. on Nickel and Iron Aluminides, Cincinnati, USA (1996), pp. 1–11.

  37. A. Borisova, Yu. Borisov, A. Tunik, et al., “Thermal spraying of coatings containing sold lubricants,” in: Proc. UTSC’99 (Düsseldorf, Germany, March 17–19), DVS-Verl., Düsseldorf (1999), pp. 174–181.

    Google Scholar 

  38. A. L. Borisova, L. I. Adeeva, A. Yu. Tunik, et al., “Structure and properties of thermal-sprayed coatings based on titanium carbide and titanium and chrome oxides with solid lubricants,” Avtomat. Svarka, No. 1, 22–27 (1999).

    Google Scholar 

  39. M. T. Blatchford, A. J. Horlock, D. G. McCartney, et al., “Production and characterization of HVOF sprayed NiCr-TiC coatings using SHS powder feedstock,” in: Proc. 1st ITSC (Montreal, Canada, May 8–11, 2000), ASM Int., Montreal (2000), pp. 515–522.

    Google Scholar 

  40. M. Vaisanen, P. Vuoristo, T. Mantyla, et al., “Microstructure and properties of TiC-CrNiMo SHS spray powder and thermally sprayed coating,” in: Proc. 1st ITSC (Montreal, Canada, May 8–11, 2000), ASM Int., Montreal (2000), pp. 429–434.

    Google Scholar 

  41. T. A. Azarova, P. A. Vitiaz, B. Vilage, and Z. Shtankhaizer, “Structure and properties of composite materials based on titanium carbide with copper additives,” in: Powder Metallurgy [in Russian], Issue 25, Minsk (2002), pp. 85–89.

  42. B. Wielage, S. Steinhauser, T. Schrick, et al., “HVOF sprayed titanium carbide composite coatings for wear protection,” in: Proc. 1st ITSC (Montreal, Canada, May 8–11, 2000), ASM Int., Montreal (2000), pp. 537–542.

    Google Scholar 

  43. A. Ilyuschenko, P. Vitiaz, A. Belyaev, and T. Talako, “SHS powder materials for protective coatings in power industry,” in: Proc. ITSC (Singapore, May 28–29, 2001), ASM Int., Singapore (2001), pp. 1299–1302.

    Google Scholar 

  44. C. Bartuli and R. W. Smith, “Composition between Ni-Cr-40 vol.% TiC wear-resistant plasma sprayed coatings produced from self-propagating high-temperature synthesis and plasma densified powders,” J. Therm. Spray Techn., 3, No. 3, 335–342 (1996).

    Article  Google Scholar 

  45. A. Verstak, P. Vitiaz, E. Lugsheider, et al., “New coatings for elevated temperature erosion application,” in: Proc. TS’96 (Essen, Germany, March 6–8, 1996), DVS-Verl., Essen (1996), pp. 71–76.

    Google Scholar 

  46. M. T. Blatchford, M. Jones, A. J. Horlock, et al., “Improvements in HVOF sprayed cermet coatings produced from SHS powders,” in: Proc. ITSC (Singapore, May 28–29, 2001), ASM Int., Singapore (2001), pp. 221–230.

    Google Scholar 

  47. B. Q. Wang and K. Luer, “The relative erosion-corrosion resistance of commercial thermal sprayed coating in a simulated circulating fluidized bed combustor (CFBC) environment,” in: Proc. 7th NTSC (Boston, USA, June 20–24, 1994), ASM Int., Boston (1994), pp. 115–120.

    Google Scholar 

  48. A. F. Ilyushchenko, A. B. Belyaev, T. L. Talako, et al., “SHS-powders for thermal-sprayed coatings subjected to the joint effect of corrosion and wear,” in: Powder Metallurgy [in Russian], Issue 23, Minsk, (2000), pp. 54–57.

  49. A. Borisova, Yu. Borisov, L. Adeeva, et al., “Heat-resistance of plasma spray coatings from composite powders produced by SHS-method,” in: Proc. 16th Int. Plansee Seminar (Austria, 30 May–3 June, 2005), RVF, Vienna (2005), pp. 434–447.

    Google Scholar 

  50. A. F. Ilyushchenko, V. A. Okovityi, and A. I. Shevtsov, Formation of Wear-Resistant Plasma-Sprayed Coatings based on Self-Lubricating Composite Materials [in Russian], Bestprint, Minsk (2005), p. 253.

    Google Scholar 

  51. A. Saidi, J. V. Wood, and J. L. F. Kellie, “Development of carbide coating materials for thermal spraying,” in: Proc. 5th World Seminar on Heat Treatment and Surface Engineering, Iranian Soc. Sci. Eng. Technol., Isfahan (1995), pp. 451–456.

    Google Scholar 

  52. E. Lugscheider, E. Remek, Yu. Borisov, et al., “NiCr-Cr3C2 and NiCr-TiC high wear-resistant coatings for protective applications in steam turbines,” in: Proc. ITSC’95 (Kobe, Japan, May 22–26, 1995), Kobe (1995), pp. 235–240.

  53. P. Vitiaz, A. Verstak, T. Azarova, et al., “Titanium carbide in wear resistant coatings,” in: Proc. NTSC’96 (Cincinnati, USA, October 7–11, 1996), ASM Int. (1996), pp. 169–176.

  54. A. Ya. Kulik, Yu. S. Borisov, A. S. Mnukhin, and M. D. Nikitin, Thermal Spraying of Composite Powders [in Russian], Mashinostroenie, Leningrad (1985), p. 199.

    Google Scholar 

  55. Yu. S. Borisov, A. L. Borisova, L. K. Shvedova, et al., “Thermal-sprayed Ti-BN composite powder coatings,” in: Proc. 11th All-Union Workshop on Heat-Resistant Coatings (Tula, May 31–June 2, 1983) [in Russian], Nauka, Leningrad (1985), pp. 127–131.

    Google Scholar 

  56. A. L. Borisova, Yu. S. Borisov, L. K. Shvetsova, I. S. Martsenyuk, “Reactions in powder Ti-BN composites,” Powder Metall. Met. Ceram., 23, No. 4, 273–276 (1984).

    Article  Google Scholar 

  57. Yu. S. Borisov, A. L. Borisova, Yu. A. Kocherzhinskii, et al., “Reactions in the Ti-Si3N4 system under ordinary and plasma heating conditions,” Powder Metall. Met. Ceram., 17, No. 3, 216–221 (1978).

    Article  Google Scholar 

  58. Yu. S. Borisov, A. L. Borisova, L. I. Adeeva, et al., “Plasma sprayed Ti-Si-C composite coatings,” Probl. Spets. Électrometall., No. 3, 62–70 (1995).

  59. Yu. Borisov, A. Borisova, and E. Dyad’ko, “Composite Ti-Si-C system coatings,” Mat. Manufac. Proc., 1, No. 4, 831–835 (1995).

    Article  Google Scholar 

  60. A. L. Borisova, Yu. S. Borisov, B. A. Polyanin, et al., “The reaction in Ti-SiC composite powders and the properties of the sprayed coatings,” Powder Metall. Met. Ceram., 24, No. 10, 769–773 (1985).

    Google Scholar 

  61. Yu. S. Borisov, A. L. Borisova, L. K. Shvedova, et al., “Reaction of boron carbide with titanium under ordinary and plasma heating conditions,” Powder Metall. Met. Ceram., 19, No. 9, 621–626 (1980).

    Article  Google Scholar 

  62. A. L. Borisova, Yu. S. Borisov, L. K. Shvedova, et al., “Reactions in the Cr-SiC system under conditions of ordinary and plasma heating,” Powder Metall. Met. Ceram., 18, No. 10, 722–728 (1979).

    Article  Google Scholar 

  63. Yu. Borisov, A. Borisova, and I. Mits, “Wear-resistant plasma coatings of the Cr-Si-C system,” in: Proc. TS’93 (Aachen, Germany, March 3–5, 1993), DVS Berichte (1993), pp. 350–354.

  64. A. L. Borisova and L. K. Shvedova, “High-temperature oxidation resistance and compatibility with the substrate of Cr-SiC composite powder coatings,” Zaschit. Pokryt. Metal., No. 18, 42–44 (1984).

    Google Scholar 

  65. A. L. Borisov, M. L. Knyaz’, A. Yu. Tunik, et al., “Examining plasma-sprayed coatings based on nickel and iron with thermally reactive Ti/SiC composite powder additives,” Probl. Spets. Électrometal., No. 1, 45–63 (1999).

  66. A. G. Tsidulko and F. I. Kitaev, “Kinetics of particle heating during the plasma-deposition of a thermally reactive Ni-Al powder,” Powder Metall. Met. Ceram., 17, No. 9, 678–682 (1978).

    Article  Google Scholar 

  67. Yu. S. Borisov and S. L. Fishman, “Exothermically reacting compositions in thermal spraying of coatings,” in: Combustion Processes in Chemical Technology and Metallurgy [in Russian], Chernogolovka (1975), pp. 150–156.

  68. F. I. Kitaev, A. G. Tsidulko, V. N. Litvinenko, et al., “Effect of alloying on the formation and property of thermally reactive Ni-Al-powder coatings,” in: Proc. 8th All-Union Workshop on Heat-Resistant Coatings [in Russian], Nauka, Leningrad (1979), pp. 112–114.

    Google Scholar 

  69. T. P. Geleishvili, Z. Sh. Okrostsvaridzem, B. D. Vardosanidze, et al., “Interphase interactions in composite clad powders during plasma spraying,” in: Theory and Practice of Thermal Spraying of Coatings [in Russian], Vol. 1, Dmitrov (1992), pp. 188–192.

    Google Scholar 

  70. G. Chich and S. Dallaire, “Synthesis and deposition of TiC-Fe coatings by plasma spraying,” Surf. Coat. Technol., 46, No. 2, 199–206 (1991).

    Article  Google Scholar 

  71. Liu Chagcong, Huang Yi-Hua, Zhao Yong, et al., “TiC-Fe coating prepared by flame spray synthesis process,” Trans. Nonferrous Metals Soc. China, No. 3, 405–407 (2000).

  72. Yu. S. Borisov, V. G. Gopienko, and V. V. Rishin, “Effect of alloying on the properties of plasma-sprayed intermetallic composite powder coatings,” in: Proc. 8th All-Union Workshop on Heat-Resistant Coatings [in Russian], Nauka, Leningrad (1979), pp. 123–127.

    Google Scholar 

  73. S. Z. Pustotina, N. N. Novikov, B. M. Solov’ev, et al., “Development and analysis of the properties of multilayer insulation coatings based on plasma-sprayed thermally reactive ceramic-metal compositions,” in: Proc. 10th All-Union Workshop on Heat-Resistant Coatings [in Russian], Nauka, Leningrad (1983), pp. 122–127.

    Google Scholar 

  74. A. Ya. Kulik, A. S. Mnukhin, and A. Yu. Mezernitskii, “Enhancing the adhesion of plasma coatings by spraying thermally reactive metal-oxide powders,” in: Proc. 8th All-Union Workshop on Heat-Resistant Coatings [in Russian], Nauka, Leningrad (1979), pp. 96–100.

    Google Scholar 

  75. Yu. S. Borisov, A. S. Zatserkovnyi, and I. V. Krivtsun, “Mathematical simulation of plasma spraying of composite powders, considering the exothermic synthesis of coating material,” Avtomat. Svarka, No. 1, 23–26 (2004).

  76. Yu. S. Borisov, I. V. Krivtsun, A. F. Muzhichenko, et al., “Computer simulation of plasma spraying,” Avtomat. Svarka, No. 12, 42–51 (2000).

  77. I. Ozdemir, I. Hamanaka, Y. Tsunekawa, and M. Okumiya, “In-process exothermic reaction in HVOF and plasma spraying with SiO2/Ni/Al-Si-Mg composite powder,” in: Proc. ITSC’2004 (Osaka, Japan, May 10–12), DVS-Verl., Osaka (2003), p. 15.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Translated from Poroshkovaya Metallurgiya, Vol. 47, No. 1–2 (459), pp. 105–125, 2008.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borisova, A.L., Borisov, Y.S. Self-propagating high-temperature synthesis for the deposition of thermal-sprayed coatings. Powder Metall Met Ceram 47, 80–94 (2008). https://doi.org/10.1007/s11106-008-0012-5

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-008-0012-5

Keywords

Navigation