Abstract
The major principles of Samsonov’s quasichemical configuration model are discussed in terms of the many-electron theory of condensed systems. It is shown that the interrelation between the order of the s-and d-levels in isolated atoms of transition elements and the occupation of the corresponding bands in metals can be interpreted with quasiparticle theory that takes the d-d-and s-d-electronic correlations into account more accurately than ordinary one-electron theory does.
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Translated from Poroshkovaya Metallurgiya, Vol. 47, No. 1–2 (459), pp. 29–36, 2008.
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Pryadko, L.F., Ristic, M.M. Configuration model of matter and its role in theoretical science of materials. Powder Metall Met Ceram 47, 21–25 (2008). https://doi.org/10.1007/s11106-008-0005-4
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DOI: https://doi.org/10.1007/s11106-008-0005-4