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Phase diagram of the Al2O3-ZrO2-Sm2O3 system. I. Triangulation and isothermal sections at 1250 and 1650°C

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Abstract

Isothermal sections at 1250 and 1650 °C have been constructed for the Al2O3-ZrO2-Sm2O3 phase diagram, and phase equilibria at those temperatures have been demonstrated. No ternary compounds are found and nor are areas of solid solutions based on components and binary compounds in the system. Partially quasibinary sections Al2O3-F, SmAlO3-(66.7% ZrO2 · 33.3% Sm2O3), and Sm4Al2O9-F have been detected, which triangulate the ternary system, and a demonstration is given of the mechanism for penetration of a phase Sm2Zr2O7 with the structure of the pyrochlore into the middle of the Al2O3-ZrO2-Sm2O3 system.

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References

  1. Yoshio Sakka, Tohru S. Suzuki, Koji Morita, and Keijiro Hiraga, “Colloidal processing and superplastic properties of fine-grained zirconia-based ceramics,” Key Eng. Mat., 206–213, 645–648 (2002).

    Google Scholar 

  2. E. Gregorova, J. Havrda, and W. Pabst, “ATZ ceramics prepared by slip-casting and centrifugal slip casting,” Key Eng. Mat., 206–213, 369–372 (2002).

    Google Scholar 

  3. A. Rodriquez-Pulido, I. M. Ross, and W. M. Rainforth, “Processing and structural characterisation of 3Y-TZP ceramics resistant to hydrothermal ageing,” Key Eng. Mat., 206–213, 1053–1056 (2002).

    Google Scholar 

  4. S. N. Lakiza, L. M. Lopato, and A. V. Shevchenko, “Interactions in the Al2O3-ZrO2-Y2O3 system,” Poroshk. Metall., Nos. 9–10, 46–51 (1994).

  5. R. S. Roth, “Classification of perovskite and other ABO3-type compounds,” J. Res. Nat. Bur. Stand., 58, No. 2, 75–88 (1957).

    CAS  Google Scholar 

  6. F. Bertaut and F. Forrat, “Etude des combinaisons des oxydes des térres rares avec l’alumine et la galline,” C. R. Acad. Sci., Paris, 243, No. 17, 1219–1222 (1956).

    CAS  Google Scholar 

  7. F. H. Aldred and A. E. S. White, “Some equipment for ceramic research,” Trans. Brit. Ceram. Soc., 58, No. 4, 199–223 (1959).

    CAS  Google Scholar 

  8. S. G. Tresvyatskii, V. I. Kushakovskii, and V. S. Belevantsev, “A study of the Al2O3-Sm2O3 and Al2O3-Gd2O3 systems,” Atom. Energiya, 9, No. 3, 219–220 (1960).

    Google Scholar 

  9. P. P. Budnikov, V. I. Kushakovskii, and V. S. Belevantsev, “A study of the Gd2O3-Al2O3 and Sm2O3-Al2O3 systems,” Dokl. AN SSSR, 165, No. 5, 1076–1077 (1965).

    Google Scholar 

  10. I. A. Bondar’ and N. A. Toropov, “Phase equilibria in the system ytterbium oxide — alumina and comparison with equilibria in other Ln2O3 — Al2O3 systems,” Izv. AN SSSR, Ser. Khimiya, No. 2, 212–218 (1966).

  11. D. Goldberg, “Contribution a l’étude des systemes formes par l’alumine avec quelques oxydes de metaux trivalents et tetravalents, en particulier, l’oxyde de titane,” Rev. Int. Hautes Temp. Refract., 5, No. 3, 181–194 (1968).

    CAS  Google Scholar 

  12. M. Mizuno, T. Yamada, and T. Nogushi, “Phase diagram of the system Al2O3-Sm2O3 at high temperatures,” J. Ceram. Soc. Jap., 85, No. 8, 372–379 (1977).

    Google Scholar 

  13. P. Wu and A. D. Pelton, “Coupled thermodynamic-phase diagram assessment of the rare earth oxide-aluminum oxide binary systems,” J. Alloys Comp., No. 179, 259 (1992).

    Google Scholar 

  14. H. Yamane, K. Ogawara, M. Omori, and T. Hirai, “Phase transition of rare-earth aluminates (RE4Al2O9) and rare earth gallates,” J. Amer. Ceram. Soc., 78, No. 9, 2385–2390 (1995).

    Article  CAS  Google Scholar 

  15. Y. Peres and M. Jorba, “ZrO2-rare earth oxide systems,” Ann. Chim., 7, No. 7–8, 479–511 (1962).

    Google Scholar 

  16. A. Rouanet and M. Foex, “Etude a haute temperature des systems formes par la zircone avec les sesquioxydes de samarium et de gadolinium,” C. R. Acad. Sci. Paris, Ser. C, 267, 873–876 (1968).

    CAS  Google Scholar 

  17. A. Rouanet, “Contribution a l’étude des systemes zircone-oxydes des lanthanides au voisinage de la fusion,” Rev. Int. Hautes Temp. Refract., 8, No. 2, 161–180 (1977).

    Google Scholar 

  18. S. M. Lakiza, V. P. Red’ko, and L. M. Lopato, “Phase diagram of the Al2O3-ZrO2-Nd2O3 system. I. Isothermal sections of the phase diagram at 1250 and 1650°C,” Poroshk. Metall., Nos. 7–8, 77–86 (2003).

  19. S. M. Lakiza and L. M. Lopato, “Stable and metastable phase relations in the system Alumina-Zirconia-Yttria,” J. Amer. Ceram. Soc., 80, No. 4, 893–902 (1997).

    CAS  Google Scholar 

  20. S. M. Lakiza and L. M. Lopato, “Interactions in the Al2O3-ZrO2-La2O3 system at 1250 and 1650°C,” Poroshk. Metall., Nos. 7–8, 99–103 (2000).

  21. L. M. Lopato, A. V. Shevchenko, and A. E. Kushchevskii, “Researches on systems containing highly refractory oxides,” Poroshk. Metall., No. 1, 88–92 (1972).

    Google Scholar 

  22. O. Fabzichnaya and F. Aldinger, “Assessment of thermodynamic parameters in the system ZrO2-Y2O3-Al2O3,” Z. Metallkunde, 95, No. 1, 27–39 (2004).

    Google Scholar 

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Authors and Affiliations

  1. Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, Kiev

    S. M. Lakiza, V. P. Red’ko & L. M. Lopato

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  1. S. M. Lakiza
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  2. V. P. Red’ko
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  3. L. M. Lopato
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Translated from Poroshkovaya Metallurgiya, Nos. 11–12(446), pp. 40–48, November–December, 2005.

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Lakiza, S.M., Red’ko, V.P. & Lopato, L.M. Phase diagram of the Al2O3-ZrO2-Sm2O3 system. I. Triangulation and isothermal sections at 1250 and 1650°C. Powder Metall Met Ceram 44, 548–556 (2005). https://doi.org/10.1007/s11106-006-0024-y

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  • DOI: https://doi.org/10.1007/s11106-006-0024-y

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