Abstract
We have studied the magnetic and structural properties of the solid solutions M 2+x Cu 2+1−x Fe 3+2 O4, where M = Mg, Ni, Co, Zn, Mn, Me +0.5x Cu 2+1−x Fe 3+2+0.5x O4, were Me = Li, Cu, and (Mn3O4)x(CuFe2O4)1−x. We have developed a new method for detecting a tetragonal phase and have used this method to determine the range of existence for solutions with a tetragonal structure. We explain the dependence of these ranges on the nature of M and Me.
Similar content being viewed by others
REFERENCES
M. A. Zinovik and V. N. Ivanova, “Ferrite material with a rectangular hysteresis loop,” Inventor's Certificate 425224 USSR, Otkrytiya. Izobreteniya, No. 15 (1974).
M. A. Zinovik, A. A. Shchepetkin, and G. I. Chufarov, “Ferrite material with a rectangular hysteresis loop,” Inventor's Certificate 427401 USSR, Otkrytiya. Izobreteniya, No. 17 (1974).
M. A. Zinovik, “Ferrite material,” Inventor's Certificate 1633466 USSR, Otkrytiya. Izobreteniya, No. 9 (1991).
M. A. Zinovik, Yu. D. Tret'yakov, and V. E. Pokrovskii, “Ferrite material,” Inventor's Certificate 989593 USSR, Otkrytiya. Izobreteniya, No. 2 (1983).
V. G. Glotov and M. A. Zinovik, “Ferrite material,” Inventor's Certificate 1633465 USSR, Otkrytiya. Izobreteniya, No. 9 (1991).
N. Baffier and M. Huber, J. Phys. Chem. Solid, 33, 737 (1972).
M. A. Zinovik, A. A. Shchepetkin, and G. I. Chufarov, “Phase ratios in synthesis and air-cooling of spinel solid solutions in the system Mn3O4-CuFe2O4,” Zhurn. Neorg. Khim., 16, No.2, 532–533 (1971).
L. I. Rabkin, S. A. Sosokin, and B. Sh. Epshtein, Ferrites [in Russian], Energiya, Leningrad (1968).
M. A. Zinovik, E. P. Naiden, and S. M. Zhilyakov, “Synthesis, atomic structure, and magnetic properties of solid solutions in the system Li0.5Fe2.5O4-Cu0.5Fe2.5O4,” Izv. Vuzov. Fizika, No. 10, 114–117 (1975).
I. K. Pukhov, A. G. Davidovich, and M. A. Zinovik, “Measurement of the Curie point for ferrites,” Zavod. Lab., 40, No.4, 409–411 (1974).
M. A. Zinovik, “Solid solutions with a spinel structure in the system Cu-Li-Fe-O,” Izv. Akad. Nauk SSSR, Neorg. Mater., 33, No.6, 761–764 (1997).
H. A. Jahn and E. Teller, Proc. Roy. Soc., London, A 161, 220–224 (1937).
E. Verwey and M. V. Van Bruggen, Z. Kristallog., 92, 136–139 (1935).
J. B. Goodenough, Magnetism and the Chemical Bond [Russian translation from English], Metallurgiya, Moscow (1968).
P. Wojtowicz, J. Phys. Rev., 116, 32–36 (1959).
A. B. Antonov, Synthesis and Crystal Chemistry Characteristics of Spinel Solid Solutions in the Systems Cu-Mn-O, Cu-Mn-Cr-O, PhD Thesis [in Russian], Sverdlovsk (1990).
A. Bergstein and L. Cervinka, Chekh. Fiz. Zhurn., 11, 584–588 (1961).
H. Ohnishi and T. Teranishi, J. Phys. Soc. Japan, 16, 35–39 (1961).
H. J. Hook and M. L. Keith, Am. Mineral, 43, 69–73 (1958).
K. S. Irani, A. P. Sinha, and A. B. Biswas, J. Phys. Chem. Sol., 23, 711–717 (1962).
Yu. P. Vorob'ev, A. N. Men', and V. B. Fetisov, Calculations and Prediction of Properties for Oxides [in Russian], Nauka, Moscow (1983).
S. Mijahara, J. Phys. Soc. Japan, 17, 181–185 (1962).
G. Blasse, Phys. Chem. Sol., 27, 383–388 (1966).
B. N. Naik and A. P. B. Sinha, Ind. J. Pure and Appl. Phys., 7, 170–175 (1969).
K. S. Irani, A. P. B. Sinha, and A. B. Biswas, J. Phys. Chem. Sol., 23, 711–717 (1962).
Yu. D. Tret'yakov, N. N. Oleinikov, and V. A. Granik, Physicochemical Principles of Ferrite Heat Treatment [in Russian], Mosk. Gos. Univ., Moscow (1973).
G. N. Il'inova, Crystal Chemistry of Some Solid Solutions with a Spinel Structure, PhD Thesis [in Russian], Sverdlovsk (1971).
L. A. Reznitskii, Results of Science and Technology. Chemical Thermodynamics and Equilibria [in Russian], VINITI, Moscow (1978), Vol. 4, p. 115.
A. P. Bobov, Crystal Chemical Transformations and Thermodynamic Analysis of Dissociation Processes in Spinel Solid Solutions of Hausmanite with Manganese Aluminate, Chromite, and Orthotitanium,” PhD Thesis [in Russian], Sverdlovsk (1982).
C. Delorme, Bull. Soc. Franc. Minerallog., 81, 91–96 (1958).
M. A. Zinovik, A. A. Shchepetkin, and G. I. Chufarov, “Interpretation of the properties of spinel solid solutions in the system Cu-Mn-Fe-O,” Izv. Akad. Nauk SSSR, Neorg. Mater., 8, No.12, 2173–2176 (1972).
Author information
Authors and Affiliations
Additional information
__________
Translated from Poroshkovaya Metallurgiya, Nos. 9–10(445), pp. 84–93, September–October, 2005.
Rights and permissions
About this article
Cite this article
Zinovik, E.V., Zinovik, M.A. Structure and Properties of Ferrites Based on CuFe2O4 . Powder Metall Met Ceram 44, 481–488 (2005). https://doi.org/10.1007/s11106-006-0013-1
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11106-006-0013-1