Abstract
The possibility of synthesizing BN powder with a different content of ternary compound in the system B - N - C is studied. It is shown that the regime for powder preparation and their composition determine the phase content of sintered specimens. The ternary compound in the system B - N - C is thermally unstable and at a sintering temperature of 1900 °C is converted into BN and B4C phases.
Similar content being viewed by others
REFERENCES
M. Hubacek and T. Sato, “Preparation and properties of a compound in the B-N-C system,” J. Sol. State Chem., 114, No.1, 258–264 (1995).
Yu. G. Andreev and T. Lundstrom, “High-temperature synthesis and investigation of hexagonal carbonitride,” J. All. Comp., 210, No.1–2, 311–317 (1994).
C. Popov, K. Saito, K. Yamamoto, et al., “Synthesis of nitrogen-rich B-N-C materials from melamine and booron trichloride,” J. Mater. Sci., 33, 1281–1286 (1998).
Y. Kenjiro, “Shock synthesis of a graphitic boron-carbon-nitrogen system,” J. Amer. Ceram. Soc., 81, No.7, 1941–1944 (1998).
B. Yao, W. Chen, L. Lin, et al., “Amorphous B-N-C semiconductor,” J. Appl. Phys., 84, 1412–1415 (1998).
T. S. Bartnistkaya and A. F. Alekseev, “Study of preparing boron nitride from boric acid and carbamide,” in: Study of Nitrides [in Russian], Nauk. Dumka, Kiev (1975).
G. V. Samsonov, O. P. Kulik, and V. S. Polishchuk, Preparation and Analysis Methods for Nitrides [in Russian], Nauk. Dumka, Kiev (1978).
V. I. Chukalin, N. V. Chukanov, S. V. Gurov, et al., “Structural features of adsorption IR-spectra for ultrafine boron nitride,” Poroshk. Metall., No. 1, 85–91 (1988).
N. A. Sanchez, C. Rincon, G. Zambrano, and P. Prieto, “Characterization of plasma during the gwoth of CN x films by RF magnetron sputtering,” Phys. Stat. Sol., 220, No.1, 697–701 (2000).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, J. Willey and Sons Inc., New York; London (1996).
H. Stein, T. Aselage, and D. Emin, “Infrared absorption in boron carbides: dependence on isotopes and carbon concentration,” AIP Conf. Proc. “Boron-rich solids,” D. Emin, T. L. Aselage, A. C. Switendick, and B. C. L. Beckel (eds.), Amer. Inst. of Phys., New York (1990).
F. Galenner, G. Lugovsky, and I. Micchelsen, “Vibrational spectra of pure vitreous B2O3,” Phys. Rev., 22B, No.8, 3983–3990 (1980).
T. S. Bartnistkaya, M. V. Vlasova, V. I. Lyashenko, et al., “Formation of very fine boron nitride with carbothermal reduction in the presence of lithium compounds,” Poroshk. Metall., No. 1, 64–73 (1993).
Author information
Authors and Affiliations
Additional information
__________
Translated from Poroshkovaya Metallurgiya, Nos. 9–10(445), pp. 3–8, September–October, 2005.
Rights and permissions
About this article
Cite this article
Grigor'ev, O.N., Lyashenko, V.I., Timofeeva, I.I. et al. Study of the Synthesis of the Ternary Compound B - N - C. Powder Metall Met Ceram 44, 415–419 (2005). https://doi.org/10.1007/s11106-006-0001-5
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11106-006-0001-5