Skip to main content
Log in

Study of the Synthesis of the Ternary Compound B - N - C

  • Theory, Production Technology, and Properties of Powders and Fibers
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

Abstract

The possibility of synthesizing BN powder with a different content of ternary compound in the system B - N - C is studied. It is shown that the regime for powder preparation and their composition determine the phase content of sintered specimens. The ternary compound in the system B - N - C is thermally unstable and at a sintering temperature of 1900 °C is converted into BN and B4C phases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. M. Hubacek and T. Sato, “Preparation and properties of a compound in the B-N-C system,” J. Sol. State Chem., 114, No.1, 258–264 (1995).

    CAS  Google Scholar 

  2. Yu. G. Andreev and T. Lundstrom, “High-temperature synthesis and investigation of hexagonal carbonitride,” J. All. Comp., 210, No.1–2, 311–317 (1994).

    CAS  Google Scholar 

  3. C. Popov, K. Saito, K. Yamamoto, et al., “Synthesis of nitrogen-rich B-N-C materials from melamine and booron trichloride,” J. Mater. Sci., 33, 1281–1286 (1998).

    Article  CAS  Google Scholar 

  4. Y. Kenjiro, “Shock synthesis of a graphitic boron-carbon-nitrogen system,” J. Amer. Ceram. Soc., 81, No.7, 1941–1944 (1998).

    Google Scholar 

  5. B. Yao, W. Chen, L. Lin, et al., “Amorphous B-N-C semiconductor,” J. Appl. Phys., 84, 1412–1415 (1998).

    CAS  Google Scholar 

  6. T. S. Bartnistkaya and A. F. Alekseev, “Study of preparing boron nitride from boric acid and carbamide,” in: Study of Nitrides [in Russian], Nauk. Dumka, Kiev (1975).

    Google Scholar 

  7. G. V. Samsonov, O. P. Kulik, and V. S. Polishchuk, Preparation and Analysis Methods for Nitrides [in Russian], Nauk. Dumka, Kiev (1978).

    Google Scholar 

  8. V. I. Chukalin, N. V. Chukanov, S. V. Gurov, et al., “Structural features of adsorption IR-spectra for ultrafine boron nitride,” Poroshk. Metall., No. 1, 85–91 (1988).

    Google Scholar 

  9. N. A. Sanchez, C. Rincon, G. Zambrano, and P. Prieto, “Characterization of plasma during the gwoth of CN x films by RF magnetron sputtering,” Phys. Stat. Sol., 220, No.1, 697–701 (2000).

    Google Scholar 

  10. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, J. Willey and Sons Inc., New York; London (1996).

    Google Scholar 

  11. H. Stein, T. Aselage, and D. Emin, “Infrared absorption in boron carbides: dependence on isotopes and carbon concentration,” AIP Conf. Proc. “Boron-rich solids,” D. Emin, T. L. Aselage, A. C. Switendick, and B. C. L. Beckel (eds.), Amer. Inst. of Phys., New York (1990).

    Google Scholar 

  12. F. Galenner, G. Lugovsky, and I. Micchelsen, “Vibrational spectra of pure vitreous B2O3,” Phys. Rev., 22B, No.8, 3983–3990 (1980).

    Google Scholar 

  13. T. S. Bartnistkaya, M. V. Vlasova, V. I. Lyashenko, et al., “Formation of very fine boron nitride with carbothermal reduction in the presence of lithium compounds,” Poroshk. Metall., No. 1, 64–73 (1993).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

__________

Translated from Poroshkovaya Metallurgiya, Nos. 9–10(445), pp. 3–8, September–October, 2005.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Grigor'ev, O.N., Lyashenko, V.I., Timofeeva, I.I. et al. Study of the Synthesis of the Ternary Compound B - N - C. Powder Metall Met Ceram 44, 415–419 (2005). https://doi.org/10.1007/s11106-006-0001-5

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-006-0001-5

Keywords

Navigation