Skip to main content
SpringerLink
Log in

The Behavior of Al0.5CoCrFeNiCuPt0.3 High-Entropy Alloy During High-Temperature Oxidation

  • Original Paper
  • Published:
High Temperature Corrosion of Materials Aims and scope Submit manuscript

Abstract

The quest for high-entropy alloys (HEAs) with superior resistance against oxidation at elevated temperatures is one of the urgent problems in materials society, since HEAs are candidates for coating machinery parts operating in aggressive conditions (such as turbine blades, turbojet and jet engines, etc.). In this study, the effect of minor platinum alloying on the microstructure, phase composition and high-temperature oxidation resistance of Al0.5CoCrFeNiCuPt0.3 HEA was studied. It was demonstrated that platinum does not precipitate as an intermetallic phases; rather, it dissolves in the solid solution phases. High-temperature oxidation tests were carried out in a muffle furnace at 900 °C and 1000 °C for 50 h in air. It was found out that platinum alloying significantly increases oxidation resistance of Al0.5CoCrFeNiCuPt0.3 HEA at elevated temperatures with specific weight change of 0.139 mg/cm2 and 0.238 mg/cm2 after 50 h of isothermal exposure to 900 °C and 1000 °C, respectively. A dense oxide layer, mainly composed of Al2O3, without defects and pores protected the surface of the alloy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. B. Cantor, I. T. H. Chang, P. Knight, and A. J. B. Vincent, Materials Science and Engineering: A 375–377, 213 (2004). https://doi.org/10.1016/j.msea.2003.10.257.

    Article  CAS  Google Scholar 

  2. J. W. Yeh, S. K. Chen, S. J. Lin, J. Y. Gan, T. S. Chin, T. T. Shun, C. H. Tsau, and S. Y. Chang, Advanced Engineering Materials 6, 299 (2004). https://doi.org/10.1002/adem.200300567.

    Article  CAS  Google Scholar 

  3. E. P. George, D. Raabe, and R. O. Ritchie, Nature Reviews Materials 4, 515 (2019). https://doi.org/10.1038/s41578-019-0121-4.

    Article  CAS  Google Scholar 

  4. Z. Li, K. G. Pradeep, Y. Deng, D. Raabe, and C. C. Tasan, Nature 534, 227 (2016). https://doi.org/10.1038/nature17981.

    Article  CAS  PubMed  Google Scholar 

  5. E. P. George, W. A. Curtin, and C. C. Tasan, Acta Materialia 188, 435 (2020). https://doi.org/10.1016/j.actamat.2019.12.015.

    Article  CAS  Google Scholar 

  6. A. K. Kasar, K. Scalaro, and P. L. Menezes, Materials 14, 5814 (2021). https://doi.org/10.3390/ma14195814.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  7. O. Samoilova, N. Shaburova, A. Ostovari Moghaddam, and E. Trofimov, Materials Letters 328, 133190 (2022). https://doi.org/10.1016/j.matlet.2022.133190.

    Article  CAS  Google Scholar 

  8. S. Veselkov, O. Samoilova, N. Shaburova, and E. Trofimov, Materials 14, 2595 (2021). https://doi.org/10.3390/ma14102595.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  9. P. Kumar, T.-N. Lam, P. K. Tripathi, S. S. Singh, P. K. Liaw, and E.-W. Huang, APL Materials 10, 120701 (2022). https://doi.org/10.1063/5.0116605.

    Article  CAS  Google Scholar 

  10. T. M. Butler and M. L. Weaver, Journal of Alloys and Compounds 674, 229 (2016). https://doi.org/10.1016/j.jallcom.2016.02.257.

    Article  CAS  Google Scholar 

  11. A. Mohanty, J. K. Sampreeth, O. Bembalge, J. Y. Hascoet, S. Marya, R. J. Immanuel, and S. K. Panigrahi, Surface and Coatings Technology 380, 125028 (2019). https://doi.org/10.1016/j.surfcoat.2019.125028.

    Article  CAS  Google Scholar 

  12. C. Jang, D. Lee, and D. Kim, International Journal of Pressure Vessels and Piping 85, 368 (2008). https://doi.org/10.1016/j.ijpvp.2007.11.010.

    Article  CAS  Google Scholar 

  13. Moghaddam A. Ostovari, N. A. Shaburova, M. V. Sudarikov, S. N. Veselkov, O. V. Samoilova, and E. A. Trofimov, Vacuum 192, 110412 (2021). https://doi.org/10.1016/j.vacuum.2021.110412.

    Article  CAS  Google Scholar 

  14. L. Chen, Z. Zhou, Z. Tan, D. He, K. Bobzin, L. Zhao, M. Öte, and T. Königstein, Journal of Alloys and Compunds 764, 845 (2018). https://doi.org/10.1016/j.jallcom.2018.06.036.

    Article  CAS  Google Scholar 

  15. N. A. Shaburova, Moghaddam A. Ostovari, S. N. Veselkov, M. V. Sudarikov, O. V. Samoilova, and E. A. Trofimov, Physical Mesomechanics 24, 653 (2021). https://doi.org/10.1134/S1029959921060035.

    Article  Google Scholar 

  16. J. J. Yang, C. M. Kuo, P. T. Lin, H. C. Liu, C. Y. Huang, H. W. Yen, and C. W. Tsai, Journal of Alloys and Compounds 825, 153983 (2020). https://doi.org/10.1016/j.jallcom.2020.153983.

    Article  CAS  Google Scholar 

  17. J. Lu, Y. Chen, H. Zhang, N. Ni, L. Li, L. He, R. Mu, X. Zhao, and F. Guo, Corrosion Science 166, 108426 (2020). https://doi.org/10.1016/j.corsci.2019.108426.

    Article  CAS  Google Scholar 

  18. J. Dąbrowa, G. Cieślak, M. Stygar, K. Mroczka, K. Berent, T. Kulik, and M. Danielewski, Intermetallics 84, 52 (2017). https://doi.org/10.1016/j.intermet.2016.12.015.

    Article  CAS  Google Scholar 

  19. W. Li, L. B. Fu, Y. D. Liu, W. L. Zhang, T. G. Wang, S. M. Jiang, J. Gong, and C. Sun, Corrosion Science 176, 108892 (2020). https://doi.org/10.1016/j.corsci.2020.108892.

    Article  CAS  Google Scholar 

  20. T. Baskaran, N. Esakkiraja, C. Samartha, P. Kumar, V. Jayaram, and A. Paul, Surface and Coatings Technology 426, 127766 (2021). https://doi.org/10.1016/j.surfcoat.2021.127766.

    Article  CAS  Google Scholar 

  21. M. Bai, Y. Chen, and P. Xiao, Coatings 11, 441 (2021). https://doi.org/10.3390/coatings11040441.

    Article  CAS  Google Scholar 

  22. Z. M. Zhou, H. Peng, L. Zheng, H. B. Guo, and S. K. Gong, Rare Metals 40, 2568 (2021). https://doi.org/10.1007/s12598-017-0980-z.

    Article  CAS  Google Scholar 

  23. O. Samoilova, S. Pratskova, I. Suleymanova, N. Shaburova, Moghaddam A. Ostovari, and E. Trofimov, Metals 13, 1709 (2023). https://doi.org/10.3390/met13101709.

    Article  CAS  Google Scholar 

  24. T. Abe, B. Sundman, and H. Onodera, Journal of phase equilibria and diffusion 27, 5 (2006). https://doi.org/10.1361/105497196X92736.

    Article  CAS  Google Scholar 

  25. H. M. Daoud, A. M. Manzoni, and R. Völkl, Advanced Engineering Materials 17, 1134 (2015). https://doi.org/10.1002/adem.201500179.

    Article  CAS  Google Scholar 

  26. C. M. Lin and H. L. Tsai, Intermetallics 19, 288 (2011). https://doi.org/10.1016/j.intermet.2010.10.008.

    Article  CAS  Google Scholar 

  27. R. A. Swalin, Thermodynamics of Solids, 2nd ed, (Wiley, New York, 1972), p. 400.

    Google Scholar 

  28. A. Takeuchi and A. Inoue, Materials Transactions 46, 2817 (2005). https://doi.org/10.2320/matertrans.46.2817.

    Article  CAS  Google Scholar 

  29. W. R. Wang, W. L. Wang, and J. W. Yeh, Journal of Alloys and Compound 589, 143 (2014). https://doi.org/10.1016/j.jallcom.2013.11.084.

    Article  CAS  Google Scholar 

  30. M. Ogura, T. Fukushima, R. Zeller, and P. H. Dederichs, Journal of Alloys and Compound 715, 454 (2017). https://doi.org/10.1016/j.jallcom.2017.04.318.

    Article  CAS  Google Scholar 

  31. Y. Y. Liu, Z. Chen, Y. Z. Chen, J. C. Shi, Z. Y. Wang, S. Wang, and F. Liu, Vacuum 169, 108837 (2019). https://doi.org/10.1016/j.vacuum.2019.108837.

    Article  CAS  Google Scholar 

  32. S. Abbaszadeh, A. Pakseresht, H. Omidvar, and A. Shafiei, Surfaces and Interfaces 21, 100724 (2020). https://doi.org/10.1016/j.surfin.2020.100724.

    Article  CAS  Google Scholar 

  33. C. C. Tung, J. W. Yeh, T. Shun, S. K. Chen, Y. S. Huang, and H. C. Chen, Materials Letters 61, 1 (2007). https://doi.org/10.1016/j.matlet.2006.03.140.

    Article  CAS  Google Scholar 

  34. J. Zhu, S. Lu, Y. Jin, L. Xu, X. Xu, C. Yin, and Y. Jia, Oxidation of Metals 94, 265 (2020). https://doi.org/10.1007/s11085-020-09991-6.

    Article  CAS  Google Scholar 

  35. D. Lussana, D. Baldissin, M. Massazza, and M. Baricco, Oxidation of Metals 81, 515 (2014). https://doi.org/10.1007/s11085-013-9465-0.

    Article  CAS  Google Scholar 

  36. A. Anupam, A. S. M. Ang, K. Guruvidyathri, M. Abbas, D. Sivaprahasam, P. Munroe, C. C. Berndt, B. S. Murty, and R. S. Kottada, Corrosion Science 184, 109381 (2021). https://doi.org/10.1016/j.corsci.2021.109381.

    Article  CAS  Google Scholar 

  37. M. J. Pavel and M. L. Weaver, High Temperature Corrosion of Materials (2024). https://doi.org/10.1007/s11085-024-10225-2.

    Article  Google Scholar 

Download references

Acknowledgements

The study was supported by the Russian Science Foundation, project No. 23-23-00107, https://rscf.ru/en/project/23-23-00107/.

Author information

Authors and Affiliations

  1. South Ural State University, 76 Lenin Av, Chelyabinsk, Russia, 454080

    Olga Samoilova, Ilsiya Suleymanova, Nataliya Shaburova, Ahmad Ostovari Moghaddam & Evgeny Trofimov

Authors
  1. Olga Samoilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ilsiya Suleymanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Nataliya Shaburova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ahmad Ostovari Moghaddam
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Evgeny Trofimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Olga Samoilova involved in conceptualization, investigation, validation, writing - original draft, writing - review and editing; Ilsiya Suleymanova involved in investigation, writing - original draft; Nataliya Shaburova involved in Iinvestigation, validation; Ahmad Ostovari Moghaddam involved in validation, writing - review and editing; Evgeny Trofimov involved in conceptualization, writing - review and editing.

Corresponding author

Correspondence to Ahmad Ostovari Moghaddam.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Samoilova, O., Suleymanova, I., Shaburova, N. et al. The Behavior of Al0.5CoCrFeNiCuPt0.3 High-Entropy Alloy During High-Temperature Oxidation. High Temperature Corrosion of mater. (2024). https://doi.org/10.1007/s11085-024-10248-9

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11085-024-10248-9

Keywords

Search

Navigation