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Synergistic Effect of B and Y Micro-alloying on Oxide-Layer Formation on the Super-austenitic S31254 Stainless Steel

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High Temperature Corrosion of Materials Aims and scope Submit manuscript

Abstract

Aiming to address the Mo volatilization problem of super-austenitic stainless steel at high temperature, the S31254 steel containing B and rare earth element Y with high oxidation resistance was designed. It was observed that a synergy of B + Y can promote the formation of the dense Cr2O3 layer at 1050 and 1100 °C, making MoO3 layer formation difficult. While the oxide layers of the 0B sample from top to bottom were divided into four layers: Fe-rich oxide layer, MoO3 layer, Cr–Mn–Ni spinel oxide layer, and Cr2O3 layer (loose and porous), thus the undense Cr2O3 layer in the 0B sample can hardly inhibit MoO3 volatilization, especially at 1100 °C. In addition, the synergistic effect of B and Y on the diffusion of Cr to the surface was calculated using first-principles calculations. The results demonstrated that both the addition of B and Y can enhance Cr diffusion to the surface, while Y can specifically promote the combination of Cr and O. Consequently, the combined presence of B and Y exhibits a more favorable synergy for improving the density of the Cr2O3 layer, effectively inhibiting MoO3 formation and volatilization, thereby enhancing the oxidation resistance of S31254.

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Acknowledgements

This work was supported by the Natural Science Foundation of Shanxi Province (Grant No. 202203021221085); the Research project of Shanxi Institute of Zhejiang University new materials and chemical industry (Grant No. 2022SZ-TD007) and the National Natural Science Foundation of China (Grant Nos. U1860204 and 51871159).

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Authors and Affiliations

  1. College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, 030024, China

    Wenjun Wang, Junyu Ren, Jinyao Ma, Caili Zhang, Zheng Li, Yuping Li, Nan Dong & Peide Han

  2. Instrumental Analysis Center, Taiyuan University of Technology, Taiyuan, 030024, China

    Jinyao Ma & Caili Zhang

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  1. Wenjun Wang
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  2. Junyu Ren
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  3. Jinyao Ma
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  5. Zheng Li
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  6. Yuping Li
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  7. Nan Dong
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  8. Peide Han
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Contributions

W.W. wrote the manuscript, designed the experimental route of the investigation and revised the results obtained. J. R. conducted calculations and revised the manuscript. J. M. and C. Z. conducted the characterization work with experimental techniques and analyzed the results. Z. L. fabricated the alloy and analyzed the results. N. D. helped in conception and design of study. Y. L. and P. H. helped in revising the manuscript critically for important intellectual con tent.

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Correspondence to Yuping Li or Nan Dong.

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Wang, W., Ren, J., Ma, J. et al. Synergistic Effect of B and Y Micro-alloying on Oxide-Layer Formation on the Super-austenitic S31254 Stainless Steel. High Temperature Corrosion of mater. (2024). https://doi.org/10.1007/s11085-024-10236-z

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  • DOI: https://doi.org/10.1007/s11085-024-10236-z

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