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Evaluation of Short-Term Oxidation Mechanism of Laser Cladded Ni–Cr–C Coating on Titanium Aluminide Substrate

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Abstract

In the present investigation, a NiCr–Cr3C2 powder mixture was deposited on titanium aluminide substrate by laser cladding. The kinetics and mechanism of oxidation of the substrate and coating were studied at 800–1100 °C using XRD, SEM, ToF–SIMS and XPS characterization techniques. The results demonstrated that the Ni–Cr–C coating had improved oxidation resistance, as compared to the substrate. The oxidized surface of the coating was covered with Cr2O3 and NiCr2O4 phases at the early stages of the oxidation. The formation of NiCr2O4 could be attributed to the reaction of NiO (an oxidation product of the NiCr phase) and Cr2O3 (an oxidation product of the chromium carbide phase) during oxidation. Increasing the oxidation time at 900 °C led to the partial formation of CrO3 as a result of the oxidation of Cr2O3. It was also found that the parabolic rate constant ratio of \(\left( {K_{{\text{p}}}^{{{\text{substrate}}}} /K_{{\text{p}}}^{{{\text{coating}}}} } \right)\) increased with the temperature, which showed, comparatively, the better oxidation resistance of the coating at higher temperatures.

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Acknowledgements

The authors would like to thank Biointerfaces Institute at McMaster University for conducting the XPS measurements. The authors also gratefully thank WATLAB, at the University of Waterloo, for conducting the SIMS experiments. In addition, we appreciate the members of Multi-Scale Additive Manufacturing (MSAM) group, especially Prof. Mihaela Vlasea, Dr. Ali Keshavarzkermani and Dr. Reza Esmaeilizadeh, for all their supports.

Funding

No funding was received to assist with the preparation of this paper.

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Authors and Affiliations

  1. Materials Engineering Group, Golpayegan College of Engineering, Isfahan University of Technology, Golpayegan, 87717-67498, Iran

    S. E. Aghili & R. Amini Najafabadi

  2. Department of Materials Engineering, Isfahan University of Technology, Isfahan, 84156-83111, Iran

    M. Shamanian

  3. Faculty of Chemical and Materials Engineering, Shahrood University of Technology, Shahrood, 3619995161, Iran

    H. Ashrafi

  4. Multi-Scale Additive Manufacturing Lab, Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, ON, N2L 3G1, Canada

    E. Marzbanrad, Y. Mahmoodkhani & E. Toyserkani

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  1. S. E. Aghili
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Contributions

SEA was contributed to conceptualization, data curation, investigation, methodology, formal analysis, writing—original draft. MS was contributed to conceptualization, methodology, formal analysis, writing—review and editing, supervision. RAN was contributed to investigation, writing—review and editing. HA was contributed to investigation, writing—review and editing. EM was contributed to formal analysis, investigation, writing—review and editing. YM was contributed to writing—review and editing. ET was contributed to conceptualization, methodology, formal analysis, writing—review and editing, supervision.

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Correspondence to S. E. Aghili.

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Aghili, S.E., Shamanian, M., Amini Najafabadi, R. et al. Evaluation of Short-Term Oxidation Mechanism of Laser Cladded Ni–Cr–C Coating on Titanium Aluminide Substrate. High Temperature Corrosion of mater. 99, 311–329 (2023). https://doi.org/10.1007/s11085-023-10154-6

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  • DOI: https://doi.org/10.1007/s11085-023-10154-6

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