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Effect of Annealing Atmosphere and Heating Rate on the Internal Oxidized Zone and Forsterite Film During Annealing

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Abstract

The use of Hi-B steel in the manufacture of transformer cores can save raw materials and greatly reduce the volume and energy consumption of the transformer. A film of forsterite on the steel surface provides a certain degree of insulation and forms by the reaction between the internal oxidized zone (IOZ) and the MgO coating during the high-temperature annealing. Therefore, the IOZ morphology is the key to affect the film morphology. This paper studies the effect of annealing atmosphere and heating rate on the morphology evolution of IOZ during the first heating stage of high-temperature annealing. The main factors affecting IOZ morphology are discussed in the context of the influence of its morphology evolution on the film morphology. The results show the change trend of IOZ thickness on the steel with MgO coating is completely different from that without MgO coating. The IOZ thickness in the steel with or without MgO coating jointly affects the forsterite film thickness.

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The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.

References

  1. G. Yang, A. Gx, B. Xg, et al., Effect of Cr on secondary recrystallization behaviors in high permeability grain oriented silicon steel manufactured by low-temperature slab reheating. Journal of Magnetism and Magnetic Materials 476, 2019 (428–436).

    Article  Google Scholar 

  2. He C X, Yang F Y, Meng L, et al. Effect of annealing atmospheres on secondary recrystallization in thin-gauge grain-oriented silicon steel: Microstructures and textures. Journal of magnetism and magnetic materials, 2017, 439(oct.):397–402.

  3. C. C. Silveira, M. A. D. Cunha, and V. T. L. Buono, The influence of internal oxidation during decarburization of a grain oriented silicon steel on the morphology of the glass film formed at high temperature annealing. Journal of Magnetism & Magnetic Materials 358–359, 2014 (65–69).

    Article  Google Scholar 

  4. M. A. Cunha and G. M. M. Cesar, Forsterite film formation and grain growth in 3% Si steel. IEEE Transactions on Magnetics 30, (6), 1994 (4890–4892).

    Article  CAS  Google Scholar 

  5. Cui F E, Yang P, Mao W M. Behaviors of different inhibitors during secondary recrystallization of a grain-orientated silicon steel. International Journal of Minerals, Metallurgy, and Materials, 2011, l8 (6): 314–319.

  6. Y. Guo, L. W. Pan, F. Q. Dai, et al., Effect of oxidized zone morphology on forsterite film morphology of a Fe-3%Si steel during high temperature annealing. Oxidation of Metals 2021. https://doi.org/10.1007/s11085-021-10066-3.

    Article  Google Scholar 

  7. M. G. M. M. Cesar, D. C. L. Vasconcelos, and W. L. Vasconcelos, Microstructural characterization of magnesias derived from different sources and their influence on the structure of ceramic films formed on a 3% silicon steel surface. Journal of Materials Science 37, (11), 2002 (2323–2329).

    Article  CAS  Google Scholar 

  8. S. Jung, M. S. Kwon, J. Park, et al., A TEM study of oxide layers formed during decarburization annealing of electrical steel. ISIJ International 51, 2011 (1163–1168).

    Article  CAS  Google Scholar 

  9. M. G. M. M. Cesar and M. J. Mantel, Effect of the temperature and dew point of the decarburization process on the oxide subscale of a 3% silicon steel. Journal of Magnetism and Magnetic Materials 254–255, 2003 (337–339).

    Article  Google Scholar 

  10. Y. Guo, F. Q. Dai, X. C. Zeng, et al., Numerical simulation of decarburization kinetics for Fe-3%Si steel during annealing. ISIJ International 59, 2019 (326–335).

    Article  CAS  Google Scholar 

  11. Incropera F P, DeWitt D P, Bergman T L, et al. Fundamentals of heat and mass transfer, 6th. Published by John Wiley & Sons, Inc. New York. 2007, P254.

  12. J. R. Welty, C. E. Wicks, R. E. Wilson, et al., Fundamentals of Momentum, Heat, and Mass Transfer, 4th, (Published by John Wiley & Sons, Inc., New York, 2005), pp. P319-320.

    Google Scholar 

Download references

Acknowledgements

Project Q20211106 supported by Hubei Provincial Department of Education, China.

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Correspondence to Luwei Pan or Fangqin Dai.

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Guo, Y., Zeng, X., Pan, L. et al. Effect of Annealing Atmosphere and Heating Rate on the Internal Oxidized Zone and Forsterite Film During Annealing. Oxid Met 97, 477–492 (2022). https://doi.org/10.1007/s11085-022-10100-y

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  • DOI: https://doi.org/10.1007/s11085-022-10100-y

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