Abstract
Isothermal oxidation tests were performed on Ti6242S (Ti—6% Al—2% Sn—4% Zr—2% Mo, 0.08% Si), Ti6246 (Ti—6% Al—2% Sn—4% Zr—6% Mo, 0.05% Si), TiXT (Ti—0.45% Si) alloys and pure titanium in laboratory air at 560 °C, 600 °C and 650 °C for 1000 h to compare their oxidation behaviors. This study aims to highlight the role of molybdenum and silicon in the oxidation resistance of titanium alloys. The results show that 6 wt.% of Mo in Ti6246 alloys does not substantially change the oxidation behavior compared to Ti6242S alloy containing only 2 wt.% of Mo. Meanwhile, the presence of 0.45 wt.% Si seems to be clearly beneficial for the oxidation resistance, reducing the parabolic rate constant by a factor larger than 2 as compared to pure titanium.
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References
R. Gaddam, B. Sefer, R. Pederson, and M.-L. Antti, Mater. Charact. 99, 2015 (166).
R. Gaddam, B. Sefer, R. Pederson, and M. L. Antti, Sci. Eng. 48, 2013 (1).
K. S. McReynolds and S. Tamirisakandala, Metall. Mater. Trans. A 42, 2011 (1732).
R. N. Shenoy, J. Unnam, and R. K. Clark, Oxid. Met. 26, 1986 (105).
C. E. Shamblen and T. K. Redden, in The Science, Technology, and Application of Titanium, eds. R. I. Jaffee and N. E. Promisel (Pergamon Press, Oxford, 1968), p. 199.
M. Berthaud, Etude du comportement de l’alliage de titane Ti6242S à haute température sous atmosphères complexes : applications aéronautiques, Ph.D. Thésis Université de Bourgogne Franche-Comté (2018).
M. Berthaud, I. Popa, R. Chassagnon, O. Heintz, J. Lavková, and S. Chevalier, Corr. Sci. 164, 2020 (108049).
C. Dupressoire, A. Rouaix-Vande Put, P. Emile, C. Archambeau-Mirguet, R. Peraldi, and D. Monceau, Oxid. Met. 87, 2017 (343).
I. Gurappa, J. Alloy Compd. 389, 2005 (190).
C. Leyens, M. Peters, and W. A. Kaysser, Mater. Sci. Forum 251–254, 1997 (769).
C. Leyens, M. Peters, and W. A. Kaysser, Mater. Sci. Technol. 213 (1996)
W. Jia, W. Zeng, X. Zhang, Y. Zhou, J. Liu, and Q. Wang, J. Mater. Sci. 46, 2011 (1351).
B. Champin, L. Graff, M. Armand, G. Béranger, and C. Coddet, J. Common Met. 69, 1980 (163).
A. M. Chaze, C. Coddet, and G. Béranger, J Less-Common Met. 83, 1982 (49).
C. Julius, J. Phase Equilib. Diffus. 27, 2006 (255).
A.M. Chaze and C. Coddet, Oxid. Met. 27 (1987)
K. Maeda, S. Suzuki, K. Ueda, T. Kitashima, S. K. Bhattacharya, R. Sahara, and T. Narushima, J. Alloys Compd. 776, 2019 (519).
Y. Shida and H. Anada, Mater. Trans. JIM 35, 1994 (623).
K. Per, High Temperature Corrosion, (Elsevier Applied Science Publishers, Essex, 1988).
H. L. Du, P. K. Datta, D. B. Lewis, and J. S. Burnell-Gray, Corros. Sci. 36, 1994 (631).
C.J. Rosa, Oxid. Met. 17, 1982 (359–369).
D. Vojtech, B. Bartova, and T. Kubatík, Mater. Sci. Eng. A 361, 2003 (50).
H. Habazaki, K. Shimizu, S. Nagata, P. Skeldon, G. E. Thompson, and G. C. Wood, Corros. Sci. 44, 2002 (1047).
A. M. Chaze and C. Coddet, J. Less-Common Met. 124, 1986 (73).
A. Kanjer, L. Lavisse, V. Optasanu, P. Berger, C. Gorny, P. Peyre, F. Herbst, O. Heintz, N. Geoffroy, T. Montesin, and M. C. Marco de Lucas, Coat. Technol. 326, 2017 (146).
C. Coddet and A. M. Chaze, J Less Common Met. 124, 1986 (73).
F. Torrent, L. Lavisse, P. Berger, G. Pillon, C. Lopes, F. Vaz, and M. C. Marco de Lucas, Coat. Technol. 255, 2014 (146).
J. Unnam, R. N. Shenoy, and R. K. Clark, Oxid. Met. 26, 1986 (231).
C. J. Rosa, J. Metallurg. Trans. 1, 1970 (2517).
K. N. Strafford and J. M. Towell, Oxid. Met. 10, 1976 (41).
M. Göbel, V. A. C. Haanappel, and M. F. Stroosnijder, Oxid. Met. 55, 2001 (137).
H. Conrad, Prog. Mater. Sci. 26, 1981 (123).
Z. Liu and G. Welsch, Metallurg. Trans. A 19, 1998 (527).
C. Leyens and M. Peters (eds.), Titanium and Titanium Alloys: Fundamentals and Applications, 1st ed (Wiley, New York, 2003),.
N. Vaché and D. Monceau, Oxid. Met. 93, 2020 (215).
A. Casadebaigt, D. Monceau, and J. Hugues, High Temperature Oxidation of Ti–6Al–4V Alloy Fabricated by Additive Manufacturing. Influence on Mechanical Properties, MATEC Web of Conferences 321, 2020 (03006).
N. Vaché, Y. Cadoret, B. Dod, and D. Monceau, Corros. Sci. 178, 2021 (109041).
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The authors thank ANR French National Research Agency for financial funding of ALTITUDE project and TIMET Savoie for providing the materials.
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Vincent, B., Optasanu, V., Herbst, F. et al. Comparison Between the Oxidation Behaviors of Ti6242S, Ti6246, TiXT Alloys, and Pure Titanium. Oxid Met 96, 283–294 (2021). https://doi.org/10.1007/s11085-021-10051-w
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DOI: https://doi.org/10.1007/s11085-021-10051-w