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Growth Kinetics and Isothermal Oxidation Behavior of Aluminide Pack Coatings on a Multiphase Mo–Si–B Alloy

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Abstract

Refractory metal alloys, such as Mo–Si–B systems, can extend high-temperature capability more than commercial Ni-based superalloys, but Mo–Si–B alloys require surface coatings to improve their poor oxidation resistance. In this study, aluminide coating layers were created on Mo–3Si–1B (wt%) alloys by pack cementation with NH4Cl, Al and Al2O3 powder. The aluminide coating layers consisted of MoAl4, Mo3Al8, and precipitates. The growth kinetics of the coating layers were estimated by identifying diffusion behaviors. The aluminide coating layer growth constant (k0) was estimated as ~ 741.3 μm/h0.5, and the activation energy (Q) for the growth of the diffusion coating layer was evaluated as ~ 44.2 kJ/mol for the examined coating temperatures of 800, 900 and 1000 °C. The thicknesses of the coating layers calculated by an estimated kinetic equation were compared with the experimental results. The coating layer successfully protected the Mo–Si–B substrate during isothermal oxidation at 1400 °C under an air atmosphere. The growth kinetics of the coated layer and oxidation behaviors were discussed in terms of microstructural analyses.

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Acknowledgements

Financial support from ADD (Agency for Defense Development) in the Republic of Korea is gratefully acknowledged (Contract No. UD170006GD). Additionally, JSP appreciates financial support from the Basic Science Research Program through the National Research Foundation of Republic of Korea (NRF) funded by the Ministry of Education, Science and Technology (Contract No. 2016R1D1A1A0991905).

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Hanbat National University, Daejeon, 34158, Republic of Korea

    Kwangsu Choi, Wonchul Yang & Joon Sik Park

  2. Department of Materials Science and Engineering, Chungnam National University, Daejeon, 34134, Republic of Korea

    Kyeong-Ho Baik

  3. Agency for Defense Development, Daejeon, 34186, Republic of Korea

    Youngmoo Kim & Seong Lee

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  1. Kwangsu Choi
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  2. Wonchul Yang
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  3. Kyeong-Ho Baik
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  4. Youngmoo Kim
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  5. Seong Lee
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  6. Joon Sik Park
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Correspondence to Joon Sik Park.

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Choi, K., Yang, W., Baik, KH. et al. Growth Kinetics and Isothermal Oxidation Behavior of Aluminide Pack Coatings on a Multiphase Mo–Si–B Alloy. Oxid Met 92, 423–437 (2019). https://doi.org/10.1007/s11085-019-09930-0

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  • DOI: https://doi.org/10.1007/s11085-019-09930-0

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