Abstract
Protective NiCoCrAlYTa coatings are used on gas turbine single crystal superalloy blades to provide environmental resistance. They can be deposited by several processes. In this study, isothermal oxidation behaviour of NiCoCrAlYTa coatings produced by HVOF spraying and Tribomet™ process and deposited on single crystal nickel-based superalloy CMSX-4 were compared between 950 and 1,150 °C for several exposure durations. Microstructure and chemical composition of both coatings were examined before and after oxidation testing and quite similar observations were made for both coating processes. The combination of phase and chemical analyses allowed the establishment of an occurrence diagram of phases for both coating processes, according to temperature and duration of exposure. The obtained diagrams seemed similar for both processes. Finally both processes appeared to be equivalent for the protection of CMSX-4 superalloy in isothermal oxidation conditions.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11085-013-9422-y/MediaObjects/11085_2013_9422_Fig1_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11085-013-9422-y/MediaObjects/11085_2013_9422_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11085-013-9422-y/MediaObjects/11085_2013_9422_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11085-013-9422-y/MediaObjects/11085_2013_9422_Fig4_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11085-013-9422-y/MediaObjects/11085_2013_9422_Fig5_HTML.jpg)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11085-013-9422-y/MediaObjects/11085_2013_9422_Fig6_HTML.gif)
Similar content being viewed by others
References
R. C. Reed, The Superalloys—Fundamentals and Applications, (Cambridge University Press, Cambridge, 2006).
P. Caron and T. Khan, Aerospace Science and Technology 3, 513 (1999).
D. S. Rickerby and M. R. Winstone, Materials and Manufacturing Processes 7, (4), 495 (1992).
J. T. DeMasi-Marcin and D. K. Gupta, Surface and Coatings Technology 68–69, 1 (1994).
Mevrel, and R. Morbioli, in Proceeding First International Congress (High-Techn-Materials and Finishing, Berlin, 1989).
A. Boudot, Propriétés des revêtements de protection haute température pour pales de turbine haute pression, PhD Thesis, Institut National Polytechnique de Toulouse (1997).
T. A. Taylor and D. F. Bettridge, Surface and Coatings Technology 86/87, 9 (1996).
A. Raffaitin, F. Crabos, E. Andrieu and D. Monceau, Surface and Coatings Technology 201, 3829 (2006).
F. J. Belzunce, V. Higuera and S. Poveda, Materials Science and Engineering A297, 162 (2001).
M. J. Pomeroy, Materials and Design 26, 223 (2005).
A. Vande Put, D. Oquab, E. Péré, A. Raffaitin and D. Monceau, Oxidation of Metals 75, 247 (2011).
W. Brandl, D. Toma, J. Krüger, H. J. Grabke and G. Matthaüs, Surface and Coatings Technology 94–95, 1997 (21).
L. Russo, and M. Dorfman, in Proceedings of ITSC’95 (Kobe, Japan, 1995).
D. Toma, W. Brandl and U. Köster, Surface and Coatings Technology 120–121, 8 (1999).
K. Harris, G. L. Erickson, S. L. Sikkenga, W. D. Brentnall, J. M. Aurrecoechea, and K. G. Kubarych, in Superalloys 1992, eds. S. D. Antolovich et al., (TMS, Warrendale, 1992), p. 297.
T. Taylor and J. Foster, Surface and Coatings Technology 201, (7), 3819 (2006).
J. Koutsky, Journal of Materials Processing Technology 157, 557 (2004).
A. Taylor and R. W. Floyd, Journal of the Institute of Metals 81, 451 (1952–1953).
R. Mévrel, Materials Science and Engineering A 120, 13 (1989).
P. Fox and G. J. Tatlock, Materials Science and Technology A 5, 816 (1989).
A. Raffaitin, Influence du cyclage thermique sur les comportements en oxidation/corrosion et en fluage de systèmes MCrAlY/superalliage à base de nickel, PhD Thesis, Institut National Polytechnique de Toulouse, ENSIACET/CIRIMAT, France (2007).
F. D. Hull, Metal Progress 96, (5), 139 (1969).
E. Hourcastagné, Qualification du revêtement NiCoCrAlYTa appliqué par HVOF, Internal Technical Note No. AA073676 (Turbomeca, 2012).
Acknowledgments
This work is supported by Turbomeca-SAFRAN group. The authors wish to acknowledge Dr Aurélie Rouaix-Vande Put from Institut Carnot-CIRIMAT, France, for her help with preliminary work and stimulating discussions, and Florian Kerguen and Geoffrey Bégué-Duthu for performing preliminary works.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Goti, R., Bétaille-Francoual, M., Hourcastagné, E. et al. Isothermal Oxidation Behaviour of NiCoCrAlYTa Coatings Produced by HVOF Spraying and Tribomet™ Process. Oxid Met 81, 105–113 (2014). https://doi.org/10.1007/s11085-013-9422-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11085-013-9422-y