Abstract
The solution cast (SC) prepared polymer nanocomposite (PNC) films, based on poly(vinylidene fluoride) (PVDF) and poly(methyl methacrylate) (PMMA) blend host matrix with varying amounts of barium titanate (BaTiO3) as nanofiller, were thermally treated through standardized hot pressed (HP) procedure at 160 °C under the pressure of 2 tons. The optical characterization including absorbance, reflectance, and percentage transmittance for UV–vis radiations of 200–800 nm, direct and indirect energy band gaps, Urbach energy, refractive index, extinction coefficient, optical range dielectric permittivity and optical conductivity as well as non-linear optical parameters of these solution cast-hot pressed (SC-HP) PNC films are performed and confirmed their dependency on the nanofiller concentrations. These SC-HP processed PNC films showed reduced UV–vis absorbance, direct energy band gap, and the degree of crystallinity of the PVDF crystalline phase whereas the crystallite melting temperature significantly enhanced in comparison to the same composition SC prepared PNC films. The dielectric permittivity and electrical conductivity values, at 27 °C, for these thermally treated PNC films are improved appreciably over the broadband radio frequency range of 1 MHz to 1 GHz. The technologically favoured changes in various optical and dielectric parameters establish the appropriateness of the thermal treatment process for envisaging applications of these PNCs in advances of high-performance flexible-type optoelectronic and radio electronic devices.
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References
Abdel Maksoud, M.I.A., Fahim, R.A., Kassem, S.M., Awed, A.S.: Gamma irradiation-induced changes in structural, linear/nonlinear optical, and optoelectrical properties of PVB/BiVO4 nanocomposite for organic electronic devices. Opt. Quant. Electron. 55, 1165 (2023)
Abdelrazek, E.M., Abdelghany, A.M., Badr, S.I., Morsi, M.A.: Structural, optical, morphological and thermal properties of PEO/PVP blend containing different concentrations of biosynthesized Au nanoparticles. J. Mater. Res. Tech. 7, 419–431 (2018)
AlAbdulaal, T.H., Yahia, I.S.: Optical linearity and nonlinearity, structural morphology of TiO2-doped PMMA/FTO polymeric nanocomposite films: laser power attenuation. Optik 227, 166036 (2021)
Al-Muntaser, A., Abo-Dief, H.M., Tarabiah, A.E., Alzahrani, E., Alsalmah, H.A., Alharbi, Z.M., Pashameah, R.A., Saeed, A.: Incorporated TiO2 nanoparticles into PVC/PMMA polymer blend for enhancing the optical and electrical/dielectric properties: hybrid nanocomposite films for flexible optoelectronic devices. Polym. Eng. Sci. 63, 3684–3697 (2023)
Alshammari, A.H., Alshammari, M., Ibrahim, M., Alshammari, K., Taha, T.A.M.: Processing polymer film nanocomposites of polyvinyl chloride–polyvinylpyrrolidone and MoO3 for optoelectronic applications. Opt. Laser Technol. 168, 109833 (2024)
Anandalli, M.H., Bhajantri, R.F., Maidur, S.R., Shastri, L.A., Sasirekha, V.: Dominant role of organic dye on Mn: ZnS/PMMA polymer nanocomposites: structural, thermal, linear, and nonlinear optical properties for optoelectronic and photonic applications. Mater. Today Commun. 35, 105918 (2023)
Baibarac, M., Nila, A., Smaranda, I., Stroe, M., Stingescu, L., Cristea, M., Cercel, R.C., Lorinczi, A., Ganea, P., Mercioniu, I., Ciobanu, R., Schreiner, C., Garcia, R.G., Bartha, C.: Optical, structural, and dielectric properties of composites based on thermoplastic polymers of the polyolefin and polyurethane type and BaTiO3 nanoparticles. Materials 14, 753 (2021)
Bouharras, F.E., Raihane, M., Ameduri, B.: Recent progress on core-shell structured BaTiO3@polymer/fluorinated polymers nanocomposites for high energy storage: synthesis, dielectric properties and applications. Prog. Mater. Sci. 113, 100670 (2020)
Charan, C.P., Sengwa, R.J.: Effect of hot pressing on the optical thermal and dielectric properties of solution cast prepared nanocomposite films based on a poly(vinylidene fluoride-co-hexafluoropropylene) and poly(ethylene oxide) blend matrix with dispersed zinc oxide nanoparticles. J. Macromol. Sci. Part B (2024). https://doi.org/10.1080/00222348.2024.2320507
Charan, C.P., Sengwa, R.J., Saraswat, M.: Synergistic effect of polymer blend compositions on the structural, thermal, optical, and broadband dielectric properties of P(VDF-HFP)/PEO/ZnO polymer nanocomposites. Chem. Phys. Impact 8, 100410 (2024)
Choudhary, S., Sengwa, R.J.: ZnO nanoparticles dispersed PVA–PVP blend matrix based high performance flexible nanodielectrics for multifunctional microelectronic devices. Curr. Appl. Phys. 18, 1041–1058 (2018)
Craciun, F., Cordero, F., Mercadelli, E., Ilic, N., Galassi, C., Baldisserri, C., Bobic, J., Stagnaro, P., Canu, G., Buscaglia, M.T., Dzunuzovic, A., Petrovic, M.V.: Flexible composite films with enhanced piezoelectric properties for energy harvesting and wireless ultrasound-powered technology. Compos. Part B Eng. 263, 110835 (2023)
Dhatarwal, P., Sengwa, R.J.: Investigation on the optical properties of (PVP/PVA)/Al2O3 nanocomposite films for green disposable optoelectronic. Physica B Condens. Matter 613, 412989 (2021)
Dhatarwal, P., Sengwa, R.J.: Crystalline phases thermal behaviour, optical energy band gap, and broadband radio wave frequency dielectric properties of PEO/PVDF blend films. Macromol. Res. 30, 460–469 (2022)
Dhatarwal, P., Sengwa, R.J., Choudhary, S.: Multifunctional (PVP/PEO)/SnO2 nanocomposites of tunable optical and dielectric properties. Optik 221, 165368 (2020)
Drakopoulos, S.X., Yang, J., Vryonis, O., Williams, L., Psarras, G.C., Mele, E.: Flexible polymer-based nanodielectrics reinforced with electrospun composite nanofibers for capacitive energy storage. ACS Appl. Polym. Mater. 4, 8203–8215 (2022)
El-naggar, A.M., Heiba, Z.K., Kamal, A.M., Mohamed, M.B.: Structural, dielectric, linear and nonlinear optical parameters of Zn0.9Cu0.1S filled PVA/CMC/PEG blends. Opt. Quant. Electron. 55, 790 (2023)
El-naggar, A.M., Heiba, Z.K., Kamal, A.M., Mohammed, M.B.: Structural, optical, and dielectric properties of PVC/ZnMn2O4/PbS polymers with and without MWCNTs. Opt. Quant. Electron. 56, 13 (2024)
Farrage, N.M., Teleb, N.H., Abd El-Ghany, W.A.: Investigation of the structural and optical properties of Sb2S3/PVA/PVP nanocomposites blended sheets for optoelectronic applications. Opt. Quant. Electron. 56, 488 (2024)
Gaßdorf, F., Fan, Z., Schwaderer, J., Beuermann, S., Wilhelm, R., Weber, A.P., Fischlschweiger, M.: Macromolecular architecture-dependent polymorphous crystallization behavior of PVDF in the PVDF/γ-BL system via thermally induced phase separation. Macromol. Rapid Commun. 44, 2300177 (2023)
Kacem, E., Althobaiti, H.A., Al-Ejji, M., Bader, N., Abed, A., Rajeh, A.: Structural, optical, and thermal studies of Poly(vinylidene fluoride-co-hexafluoropropylene) and Polyvinylpyrrolidone composite doped Ag/ZnO mixed nanoparticles for flexible optoelectronic devices. Opt. Mater. 146, 114560 (2023)
Kubin, M., Makreski, P., Zanoni, M., Gasperini, L., Selleri, G., Fabiani, D., Gualandi, C., Bužarovska, A.: Effects of nano-sized BaTiO3 on microstructural, thermal, mechanical and piezoelectric behavior of electrospun PVDF/BaTiO3 nanocomposite mats. Polym. Test. 126, 108158 (2023)
Kumar, N., Sengwa, R.J.: Broadband dielectric behaviour and structural characterization of PVDF/PMMA/OMMT polymer nanocomposites for promising performance nanodielectrics in flexible technology advances. Phy. Scr. 98, 085915 (2023a)
Kumar, N., Sengwa, R.J.: Broadband dielectric dispersion (20 Hz − 1 GHz) and relaxation, crystalline structure, and thermal characterization of PVDF/PMMA blend films. Polym. Bull. 80, 12021–12046 (2023b)
Kumar, N., Sengwa, R.J.: Optical characterization of PVDF/PMMA/OMMT hybrid polymer nanocomposite films for futuristic optoelectronic devices. Optik 287, 171163 (2023c)
Kumar, N., Sengwa, R.J., Dhatarwal, P., Saraswat, M.: Effectively polymer composition controllable optical properties of PVDF/PMMA blend films for advances in flexible devices technologies. Indian J. Eng. Mater. Sci. 29, 169–180 (2022)
Liu, Y., Liu, Q., Liu, Z., Wu, M., Lou, X., Gao, J., Zhong, L.: Influence of local phase separation on dielectric properties of PVDF/PMMA blends during thermal aging. IEEE Trans. Dielectr. Electr. Insul. 30, 2199–2204 (2023)
Martins, P., Lopes, A.C., Lanceros-Mendez, S.: Electroactive phases of poly(vinylidene fluoride): determination, processing and applications. Prog. Polym. Sci. 39, 683–706 (2014)
Mohammed, M.I.: Optical properties of ZnO nanoparticles dispersed in PMMA/PVDF blend. J. Mol. Struct. 1169, 9–17 (2018)
Morsi, M.A., Abdelrazek, E.M., Tarabiah, A.E., Salim, E.: Preparation and tuning the optical and electrical properties of polyethylene oxide/polyvinyl alcohol/poly(3,4-thylenedioxythiophene): Polystyrene sulfonate/CuO-based quaternary nanocomposites for futuristic energy storage devices. J. Energy Storage 80, 110239 (2024)
Nasrallah, D.A., El-Metwally, E.G., Ismail, A.M.: Structural, thermal, and dielectric properties of porous PVDF/Li4Ti5O12 nanocomposite membranes for high-power lithium-polymer batteries. Polym. Adv. Technol. 32, 1214–1229 (2021)
Nor, N.A.M., Jaafar, J., Ismail, A.F., Mohamed, M.A., Rahman, M.A., Othman, M.H.D., Lau, W.J., Yusof, N.: Preparation and performance of PVDF-based nanocomposite membrane consisting of TiO2 nanofibers for organic pollutant decomposition in wastewater under UV irradiation. Desalination 391, 89–97 (2016)
Panaitescu, D.M., Popa, M.S., Ciuprina, F., Enache, L., Frone, A.N., Nicolae, C.A., Gabor, A.R., Trusca, R., Raditoiu, V., Trica, B., Ghiurea, M.: Role of polyaniline coating on nanosilica particles in polyvinylidene fluoride nanocomposites for energy storage. Surf. Interf. 36, 102546 (2023)
Petrovic, M.V., Cordero, F., Mercadelli, E., Brunengo, E., Ilic, N., Galassi, C., Despotovic, Z., Bobic, J., Dzunuzovic, A., Stagnaro, P., Canu, G., Craciun, F.: Flexible lead-free NBT-BT/PVDF composite films by hot pressing for low-energy harvesting and storage. J. Alloys Compd. 884, 161071 (2021)
Plesník, L., Barabaszová, K.Č, Holešová, S., Peikertová, P., Martynková, G.S., Nakonieczny, D.S.: Nanocomposite PVDF membrane for battery separator prepared via hot pressing. Batteries 9, 398 (2023)
Rajeevan, S., John, S., Georage, S.C.: Polyvinylidene fluoride: a multifunctional polymer in supercapacitor applications. J. Power Sour. 504, 230037 (2021)
Rajeh, A., Althobaiti, H.A., Almehmadi, S.J., Alsalmah, H.A., Masmali, N.A., Al-Sulami, A.I., Al-Ejji, M.: Alteration in the structural, optical, thermal, electrical, and dielectric properties of PMMA/PVDF blend by incorporation of Ni/ZnO nanohybrid for optoelectronic and energy storage devices. J. Inorg. Organomet. Polym. 34, 1221–1231 (2024). https://doi.org/10.1007/s10904-023-02880-w
Rajesh, K., Crasta, V., Kumar, N.B.R., Shetty, G., Rekha, P.D.: Structural, optical, mechanical and dielectric properties of titanium dioxide doped PVA/PVP nanocomposite. J. Polym. Res. 26, 99 (2019)
Ravulapalli, S., Padal, K.T.B., Kumar, B.R.: Structural and optical properties of PVP/PEO blends doped with CNTs. Emergent Mater. 6, 1923–1933 (2023)
Sagar, R., Gaur, M.S., Kozlov, V.V., Godaev, B.S., Rogachev, A.A.: Effect of BaZrO3 and BaTiO3 nanofillers on dielectric and thermal properties of poly(vinyl chloride)/polyvinylidene fluoride nanohybrid. J. Therm. Anal. Calorim. 148, 6071–6083 (2023a)
Sagar, R., Gaur, M.S., Iľkovič, S.: Effect of 105 MeV gold ion irradiation on dielectric properties of PVC/PVDF@BaZrO3 nanohybrid thin film. Rad. Effects Defects Solids (2023b). https://doi.org/10.1080/10420150.2023.2294032
Sengwa, R.J.: Thermal and dielectric properties of PVDF/PEO/SiO2 nanodielectrics for flexible radioelectronic device technologies. Hybrid Adv. 2, 100028 (2023)
Sengwa, R.J., Charan, C.P.: ZnO nanofiller concentrations modified P(VDF-HFP)/PEO polymer matrix-based nanocomposites of enhanced optical and dielectric properties for emerging optoelectronic and energy storage devices. Surf. Interfaces 46, 103945 (2024)
Sengwa, R.J., Dhatarwal, P.: Nanofiller concentration-dependent appreciably tailorable and multifunctional properties of (PVP/PVA)/SnO2 nanocomposites for advanced flexible device technologies. J. Mater. Sci. Mater. Electron. 32, 9661–9674 (2021)
Sengwa, R.J., Dhatarwal, P.: Toward multifunctionality of PEO/PMMA/MMT hybrid polymer nanocomposites: Promising morphological, nanostructural, thermal, broadband dielectric, and optical properties. J. Phys. Chem. Solids 166, 110708 (2022)
Sengwa, R.J., Kumar, N.: Composition controllable multifunctionality of PVDF/PMMA/BaTiO3/OMMT based ternary and quaternary hybrid polymer nanocomposites. Chem. Phys. Impact 7, 100281 (2023)
Sengwa, R.J., Choudhary, S., Dhatarwal, P.: Nonlinear optical and dielectric properties of TiO2 nanoparticles incorporated PEO/PVP blend matrix based multifunctional polymer nanocomposites. J. Mater. Sci. Mater. Electron. 30, 12275–12294 (2019)
Sengwa, R.J., Kumar, N., Saraswat, M.: Morphological, structural, optical, broadband frequency range dielectric and electrical properties of PVDF/PMMA/BaTiO3 nanocomposites for futuristic microelectronic and optoelectronic technologies. Mater. Today Commun. 35, 105625 (2023)
Soliman, T.S., Vshivkov, S.A., Elkalashy, Sh.I.: Structural linear and nonlinear optical properties of Ni nanoparticles – polyvinyl alcohol nanocomposites films for optoelectronic applications. Opt. Mater. 107, 110037 (2020)
Soliman, T.S., Hessien, M.M., Elkalashy, Sh.I.: Structural, thermal, and optical properties of polyvinyl alcohol films doped with La2ZnOx nanoparticles. J. Non-Cryst. Solids 580, 121405 (2022)
Taha, T.A.: Optical properties of PVC/Al2O3 nanocomposite films. Polym. Bull. 76, 903–918 (2019)
Thakur, Y.S., Acharya, A.D., Sharma, S.: Bhawna, Reinforcement of V2O5 nanoparticle in polyaniline to improve the optical and UV- shielding properties. Results Opt. 11, 100400 (2023)
Wang, Y., Yao, M., Ma, R., Yuan, Q., Yang, D., Cui, B., Ma, C., Liu, M., Hu, D.: Design strategy of barium titanate/polyvinylidene fluoride-based nanocomposite films for high energy storage. J. Mater. Chem. A 8, 884–917 (2020)
Wang, S., Luo, Z., Liang, J., Hu, J., Jiang, N., He, J., Li, Q.: Polymer nanocomposite dielectrics: understanding the matrix/particle interface. ACS Nano 16, 13612–13656 (2022)
Wang, L., Yang, C., Wang, X., Shen, J., Sun, W., Wang, J., Yang, G., Cheng, Y., Wang, Z.: Advances in polymers and composite dielectrics for thermal transport and high-temperature applications. Compos. Part A Appl. Sci. Manuf. 164, 107320 (2023)
Wemple, S.H., DiDomenico, M., Jr.: Bahavior of the electronic dielectric constant in covalent and ionic materials. Phys. Rev. B 3, 1338 (1971)
Wu, X., Chen, X., Zhang, Q.M., Tan, D.Q.: Advanced dielectric polymers for energy storage. Energy Stor. Mater. 44, 29–47 (2022)
Xie, Y., Fan, X., Li, X., Zhang, Y., Zhang, Z., Huang, X.: Perspective on interface engineering for capacitive energy storage polymer nanodielectrics. Phys. Chem. Chem. Phys. 24, 19624–19633 (2022)
You, L., Liu, B., Hua, H., Jiang, H., Yin, C., Wen, F.: Energy storage performance of polymer-based dielectric composites with two-dimensional fillers. Nanomaterials 13, 2842 (2023)
Zeng, S., Li, X., Li, M., Zheng, J., Shiju, E., Yang, W., Zhao, B., Guo, X., Zhang, R.: Flexible PVDF/CNTs/Ni@CNTs composite films possessing excellent electromagnetic interference shielding and mechanical properties under heat treatment. Carbon 155, 34–43 (2019)
Zhang, Y., He, X., Cong, X., Wang, Q., Yi, H., Li, S., Zhang, C., Zhang, T., Wang, X., Chi, Q.: Enhanced energy storage performance of polyethersulfone-based dielectric composite via regulating heat treatment and filling phase. J. Alloys Compd. 960, 170539 (2023a)
Zhang, C., Tong, X., Liu, Z., Zhang, Y., Zhang, T., Tang, C., Liu, X., Chi, Q.: Enhancement of energy storage performance of PMMA/PVDF composites by changing the crystalline phase through heat treatment. Polymers 15, 2486 (2023b)
Zhou, W., Li, T., Yuan, M., Li, B., Zhong, S., Li, Z., Liu, X., Zhou, J., Wang, Y., Cai, H., Dang, Z.M.: Decoupling of inter-particle polarization and intra-particle polarization in core-shell structured nanocomposites towards improved dielectric performance. Energy Stor. Mater. 42, 1–11 (2021)
Zhou, L., Zhao, S., Xie, P., Miao, X., Liu, S., Sun, N., Guo, M., Xu, Z., Zhong, T., Shen, Y.: Research progress and prospect of polymer dielectrics. Appl. Phys. Rev. 10, 031310 (2023)
Zyoud, S.H., AlAbdulaal, T.H., Almoadi, A., Alqahtani, M.S., Harraz, F.A., Al-Assiri, M.S., Yhia, I.S., Zahran, H.Y., Mohammed, M.I., Abdel-wahab, MSh.: Linear/nonlinear optical characteristics of ZnO-doped PVA/PVP polymeric films for electronic and optical limiting applications. Crystals 13, 608 (2023)
Acknowledgements
The University Grants Commission, New Delhi, is gratefully acknowledged for the experimental grant through SAP DRS-II Project (No. F.530/12/DRS-II/2016(SAP-I)).
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Authorship contributions R.J. Sengwa: Conceptualization, Supervision, Methodology, Data curation, Project administration, Resources, Writing—original draft, Writing—review & editing Naresh Kumar: Conceptualization, Methodology, Data curation, Writing—original draft.
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Sengwa, R.J., Kumar, N. Optical properties and broadband radio frequencies dielectric performance of solution cast-hot pressed PVDF/PMMA/BaTiO3 nanocomposite films. Opt Quant Electron 56, 889 (2024). https://doi.org/10.1007/s11082-024-06716-w
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DOI: https://doi.org/10.1007/s11082-024-06716-w