Abstract
The current research aims to develop an optically active, thermally luminescent, and radiation-shielding glass resources. For that, we have planned to develop a glasses of the chemical composition Ba(25-x)La15Si60Nix (where, ‘x’ = 0, 0.2, 0.4, 0.6, 0.8 & 1.0 mol%). There after the developed glasses are planned for structure, physical, mechanical, radiation shielding, optical and thermoluminescence characterization. The XRD & SEM studies reveal the glassy behavior. The EDS analysis signifies the chemical constitutes with atomic weight %. The physical properties such as density (~ 2.625 gm/cm3), molar volume (~ 48.48 cm3 mol−1) and refractive index (1.649) of glasses are evaluated. The DTA studies of glasses reveal the GTT (~ 429.5 °C) and thermal stabilities (1.593) evolutions are purely function of Ni2+ ions. Using ultrasonic velocities of the test glasses, the glasses' micro-hardness (~ 2.82 GPa) was evaluated. Radiation shielding properties such as RPE (~ 36.55%) and MAC (~ 16.556) reveal the shielding behavior is purely a function of Ni2+ ions. Using the optical absorption spectra, the bandgap (~ 1.21 eV) of the glasses evaluated. These values also purely function of Ni2+ ions. Using the photoluminescence spectra the luminescence analysis of glasses studied. The variations in values of emission cross section (~ 1.21 × 109, cm2) and Chromacity colour co-ordinates also suggesting emission range of glasses is purely function of Ni2+ ions. The TL properties are studied at 0 and 50 kGy gamma irradiation dose range. The frequency factor (~ 3.062 × 1021, S−1) and A.E. (~ 1.798 eV) of glasses were evaluated. This reveals that the TL behavior of glasses is a purely function of Ni2+ ions. Overall, the NSBL glasses prepared are mechanical hard, TL effective, optical and radiation shielding resources.
Similar content being viewed by others
References
Abdel-Wahab, E.A., Shaaban, K.S., Yousef, E.S.: Enhancement of optical and mechanical properties of sodium silicate glasses using zirconia. Opt. Quant. Electron. 52, 458 (2020). https://doi.org/10.1007/s11082-020-02575-3
Alekseeva, I., Dymshits, O., Tsenter, M., Zhilin, A.: Influence of various alkali and divalent metal oxides on phase transformations in NiO-doped glasses of the Li2O–Al2O3–SiO2–TiO2 system. J. Non-Cryst. Solids 357, 2209–2214 (2011). https://doi.org/10.1016/j.jnoncrysol.2010.12.065
Al-Ghamdi, H., Alsaif, N.A.M., El-Hamalawy, A.A., Ahmed, E.M., Sadeq, M.S., Rammah, Y.S.: B2O3–P2O5–CaO bioactive glasses: Synthesis, physical properties, optical basicity, electronegativity and radiation attenuation competence. Radiat. Phys. Chem. 214, 111278 (2024). https://doi.org/10.1016/j.radphyschem.2023.111278
Al-Hadeethi, Y., Sayyed, M.I., Kaewkhao, J., Raffah, B.M., Almalki, R., Rajaramakrishna, R., Hussein, M.A.: Physical, optical properties and radiation shielding studies of xLa2O3-(100–x)B2O3 glass system. Ceram. Int. 46(4), 5380–5386 (2020). https://doi.org/10.1016/j.ceramint.2019.10.293
Amorós, J.L., Blasco, E., Moreno, A., Marín, N., Feliu, C.: Sinter-crystallisation kinetics of a SiO2–Al2O3–CaO–MgO–SrO glass-ceramic glaze. J. Non-Cryst. Solids 532, 119900 (2020). https://doi.org/10.1016/j.jnoncrysol.2020.119900
Dan, H.K., Ty, N.M., Tap, T.D., Vinh, H.X., Vinh, L.T., Jiao, Q., Zhou, D., Qiu, J.: Effects of Al3+/La3+ ratio on the DSC/DTA and luminescence properties of Bi-doped lanthanum aluminosilicate glasses. Infrared Phys. Technol. 103, 103072 (2019). https://doi.org/10.1016/j.infrared.2019.103072
Deepa, A.V., Vinothkumar, P., Sathya Moorthy, K., et al.: Optical, electrical, mechanical properties of Pr3+ and Yb3+ doped phosphate glasses. Opt. Quant. Electron. 52, 483 (2020). https://doi.org/10.1007/s11082-020-02606-z
Fesharaki, M.J., Jalali, M.R., Karimi, L., et al.: Studies on the photoluminescence and thermoluminescence properties of CaZrO:xEu phosphor for dosimetric applications. Opt. Quant. Electron. 54, 406 (2022). https://doi.org/10.1007/s11082-022-03820-7
Ficheux, M., Burov, E., Aquilanti, G., Trcera, N., Montouillout, V., Cormier, L.: Structural evolution of high zirconia aluminosilicate glasses. J. Non-Cryst. Solids 539, 120050 (2020). https://doi.org/10.1016/j.jnoncrysol.2020.120050
Grabtchikov, A.S., Khodasevich, I.A., Golubev, N.V., Ignat’eva, E.S., Mashinsky, V.M., Kozlova, E.O., Malashkevich, G.E., Sigaev, V.N.: Optical amplification in Ni2+-doped gallium germanosilicate glass-ceramics. Opt. Commun. 491, 126955 (2021). https://doi.org/10.1016/j.optcom.2021.126955
Ibrahim, M.S.S., Hamed, M.K.G., El-Okr, M.M., et al.: Highly sensitive photonic crystal gamma ray dosimeter. Opt. Quant. Electron. 53, 348 (2021). https://doi.org/10.1007/s11082-021-02968-y
Iftekhar, S., Grins, J., Edén, M.: Composition–property relationships of the La2O3–Al2O3–SiO2 glass system. J. Non-Cryst. Solids 356(20), 1043–1048 (2010). https://doi.org/10.1016/j.jnoncrysol.2010.01.017
Intawin, P., Panyata, S., Kraipok, A., Tunkasiri, T., Eitssayeam, S., Pengpat, K.: Effects of TiO2 content and thermal parameters on crystallization kinetics and mechanical properties of phosphate based glass system. Thermochim. Acta (2020). https://doi.org/10.1016/j.tca.2020.178699
Isokawa, Y., Nakauchi, D., Okada, Go., Kawaguchi, N., Yanagida, T.: Radiation induced luminescence properties of Ce-doped Y2O3-Al2O3-SiO2 glass prepared using floating zone furnace. J. Alloy. Compd. 782, 859–864 (2019). https://doi.org/10.1016/j.jallcom.2018.12.245
Issa, S.A.M., Ali, A.M., Susoy, G., Tekin, H.O., Saddeek, Y.B., Elsaman, R., Somaily, H.H., Algarni, H.: Mechanical, physical and gamma ray shielding properties of xPbO-(50–x)MoO3–50V2O5 (25 ≤ x ≤ 45 mol %) glass system. Ceram. Int. 46(12), 20251–20263 (2020). https://doi.org/10.1016/j.ceramint.2020.05.107
Kamil, S.M., Abul-Magd, A.A., El-Gammal, W., Saudi, H.A.: Enhanced optical and structural features of Ni2+/La3+ hybrid borate glasses. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 267(2), 120569 (2022). https://doi.org/10.1016/j.saa.2021.120569
Katyayan, S., Agrawal, S.: Optical behavior and TL kinetics of Eu3+ and Tb3+ doped zirconate thermoluminescent phosphors. Opt. Quant. Electron. 51, 277 (2019). https://doi.org/10.1007/s11082-019-1993-7
Konar, B., Kim, D.-G., Jung, I.-H.: Critical thermodynamic optimization of the Li2O-Al2O3-SiO2 system and its application for the thermodynamic analysis of the glass-ceramics. J. Eur. Ceram. Soc. 38(11), 3881–3904 (2018). https://doi.org/10.1016/j.jeurceramsoc.2018.04.031
Martinet, C., Heili, M., Martinez, V., Kermouche, G., Molnar, G., Shcheblanov, N., Barthel, E., Tanguy, A.: Highlighting the impact of shear strain on the SiO2 glass structure: from experiments to atomistic simulations. J. Non-Cryst. Solids 533, 119898 (2020). https://doi.org/10.1016/j.jnoncrysol.2020.119898
Padmanabham, A., Gandhi, Y., Satyanarayana, T., Veeraiah, N.: Spectroscopic and dielectric properties of crystallized PbO–Sb2O3–As2O3:NiO glass system. J. Alloy. Compd. 488(1), 400–408 (2009). https://doi.org/10.1016/j.jallcom.2009.08.148
Plotnichenko, V.G., Sokolov, V.O., Snopatin, G.E., Churbanov, M.F.: Optical absorption and structure of impurity Ni2+ center in tungstate–tellurite glass. J. Non-Cryst. Solids 357(3), 1070–1073 (2011). https://doi.org/10.1016/j.jnoncrysol.2010.10.026
Prasad, V., Suresh, B., Kostrzewa, M., Gandhi, Y., Ingram, A., Siva-Sesha-Reddy, A., Ravi-Kumar, V., Veeraiah, N.: Dielectric dispersion, dipolar relaxation and AC conduction phenomena of NiO doped lead bismuth silicate glass system. J. Non-Cryst. Solids 500, 460–467 (2018). https://doi.org/10.1016/j.jnoncrysol.2018.09.002
Rajesham, S., Chandra Sekhar, K., Shareefuddin, M., et al.: Synthesis, physical, optical and structural studies of B2O3-CdO-Al2O3-PbF2 glasses modified with MoO3 ions. Opt. Quant. Electron. 54, 470 (2022). https://doi.org/10.1007/s11082-022-03874-7
Sekhar, V., Pavić, L., Moguš-Milanković, A., Kumar, V.R., Reddy, A.S.S., Raju, G.N., Veeraiah, N.: Dielectric dispersion and impedance spectroscopy of NiO doped Li2SO4–MgO–P2O5 glass system. J. Alloy. Compd. 824, 153907 (2020). https://doi.org/10.1016/j.jallcom.2020.153907
Srikumar, T., Brik, M.G., Srinivasa-Rao, Ch., Venkatramaiah, N., Gandhi, Y., Veeraiah, N.: Emission features of Ho3+ ion in Nb2O5, Ta2O5 and Al2O3 mixed Li2O–ZrO2–SiO2 glasses. Physica B 406(19), 3592–3598 (2011). https://doi.org/10.1016/j.physb.2011.06.046
Suresh, B., Srinivasa-Reddy, M., Siva-Sesha-Reddy, A., Gandhi, Y., Ravi-Kumar, V., Veeraiah, N.: Spectroscopic features of Ni2+ ion in PbO–Bi2O3–SiO2 glass system. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 141, 263–271 (2015). https://doi.org/10.1016/j.saa.2015.01.058
Tamrakar, R.K., Upadhyay, K.: Thermoluminescence behaviour of GdAlO3:Yb3+under gamma exposure. Opt. Quant. Electron. 50, 271 (2018). https://doi.org/10.1007/s11082-018-1542-9
Thieme, C., Rüssel, C.: High thermal expansion of crystallized glasses in the system BaO–ZnO–NiO–SiO2. Ceram. Int. 41(10), 13310–13319 (2015). https://doi.org/10.1016/j.ceramint.2015.07.114
Thulasiramudu, A., Buddhudu, S.: Optical characterization of Mn2+, Ni2+ and Co2+ ions doped zinc lead borate glasses. J. Quant. Spectrosc. Radiat. Transfer 102(2), 212–227 (2006)
Vladislavova, L., Thieme, C., Zscheckel, T., Höche, T., Rüssel, C.: Crystallization of Ba1- xSrxZn2Si2O7 from the BaO/SrO/ZnO/SiO2 glass system: effect of platinum and Sb2O3 on nucleation. J. Alloy. Compd. 793, 705–714 (2019). https://doi.org/10.1016/j.jallcom.2019.04.034
Wang, S.-F., Hsu, Y.-F., Hsieh, Y.-C.: Effects of La2O3, Nd2O3, NiO and CoO additions on the characteristics of SiO2–Al2O3–Y2O3–ZnO glass seals for intermediate temperature solid oxide fuel cells. Int. J. Hydrogen Energy 40(8), 3338–3347 (2015). https://doi.org/10.1016/j.ijhydene.2015.01.045
White, K.I., Beales, K.J., Midwinter, J.E., et al.: Radiation effects on absorption losses in some optical glasses. Opto-Electronics 6, 313–315 (1974). https://doi.org/10.1007/BF01423381
Xie, J., Zhang, M., Guo, R., Shi, Y., Liu, X., Pan, X., Chen, K., Deng, W.: Investigation of optical and thermal properties in Er3+-doped Ga2O3- La2O3-Ta2O5 glasses fabricated by container less solidification. J. Alloy. Compd. 872, 159651 (2021). https://doi.org/10.1016/j.jallcom.2021.159651
Zakaly, H.M.H., Alsaif, N.A.M., Shams, M.S., et al.: Synthesis, physical, optical characteristics, neutron/γ-rays shielding capacity of newly arsenic glasses: experimental, theoretical, and simulation investigations. Opt. Quant. Electron. 55, 365 (2023). https://doi.org/10.1007/s11082-023-04610-5
Zamyatin, O.A., Churbanov, M.F., Plotnichenko, V.G., Zamyatina, E.V.: Optical properties of the MoO3–TeO2 glasses doped with Ni2+–ions. J. Non-Cryst. Solids 480, 74–80 (2018). https://doi.org/10.1016/j.jnoncrysol.2017.08.016
Zhang, Q.Y., Zhang, W.J., Wang, W.C., Jiang, Z.H.: Calculation of physical properties of glass via the phase diagram approach. J. Non-Cryst. Solids 457, 36–43 (2017). https://doi.org/10.1016/j.jnoncrysol.2016.11.005
Zhao, E.-L., Zhao, S.-X., Xia, Wu., Li, J.-W., Lü-Qiang, Yu., Nan, C.-W., Cao, G.: Electrochemical performance of Li2O-V2O5-SiO2-B2O3 glass as cathode material for lithium ion batteries. J. Materiom. 5(4), 663–669 (2019). https://doi.org/10.1016/j.jmat.2019.05.002
Zhu, H., Renli, Fu., Agathopoulos, S., Fang, J., Li, G., He, Q.: Crystallization behaviour and properties of BaO-CaO-Al2O3-SiO2 glasses and glass-ceramics for LTCC applications. Ceram. Int. 44(9), 10147–10153 (2018). https://doi.org/10.1016/j.ceramint.2018.03.003
Acknowledgements
The authors thank Dr. K. Abhijit Rao (CEO, Sree Educational Group of Institutions) for continuous moral support during the overall completion of the investigation.
Author information
Authors and Affiliations
Contributions
RKG—methodology, results, analysis, report correction and communication.
Corresponding author
Ethics declarations
Conflict of interest
None.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Guntu, R.K. Photoluminescence and TL defect center analysis of radiation shielding Ba(25-x)La15Si60Nix glasses. Opt Quant Electron 56, 255 (2024). https://doi.org/10.1007/s11082-023-05847-w
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11082-023-05847-w