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Experimental and theoretical comparative analysis of pure WO3 and La doped WO3 for degradation of MB

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Abstract

This study reports the simple synthesis of pure and La-doped (1, 2, 3, 4 and 5%) WO3 nanoparticles (NPs) for the degradation of MB dye. The UV–Vis, XRD, FTIR, SEM and PL techniques have been utilized for the evaluation of prepared samples. The photo catalytic activity of these synthesized samples has been observed for the degradation of methylene blue (MB) in the presence of visible light via photo catalysts (WO3, La-WO3) NPs. Additionally, the suppression of the band gap from 2.81 to 2.23 eV along photo generated electron–hole pair has been demonstrated by UV visible and PL spectroscopy respectively. The crystalline size of 4% La-WO3, reduced from 30 to 11 nm as compared to pure WO3. FTIR spectroscopy analysis reveals the synthesized material is composed of tungsten and oxygen. However, in the presence of visible light, the optimal 4% La-doped WO3 NPs’ are capable of degrade methylene blue (MB) to 94% within 180 min. To test the stability of the optimized catalyst, reusability and trapping tests have been conducted. The correlation between the theoretical model and the experiments has also been performed using the COMSOL Multiphysics module 5.3a.

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Acknowledgements

The researchers wish to extend their sincere gratitude to the Deanship of Scientific Research at the Islamic University of Madinah for the support provided to the Post-Publishing Program.

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Deanship of Scientific Research at the Islamic University of Madinah.

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  1. Ayesha Younas, Tahir Iqbal Abdullah Almohammedi and Sumera Afsheen have contributed equally.

Authors and Affiliations

  1. Department of Physics, Faculty of Science, University of Gujrat, Hafiz Hayat Campus, Gujrat, 50700, Pakistan

    Ayesha Younas & Tahir Iqbal

  2. Department of Physics, Faculty of Science, Islamic University of Madinah, Madinah, 42351, Saudi Arabia

    Abdullah Almohammedi

  3. Department of Zoology, Faculty of Science, University of Gujrat, Hafiz Hayat Campus, Gujrat, 50700, Pakistan

    Sumera Afsheen

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  1. Ayesha Younas
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  2. Tahir Iqbal
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  3. Abdullah Almohammedi
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  4. Sumera Afsheen
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Contributions

AY: writing—original draft, data curation, methodology, validation, project administration. TI, SA and AA: conceptualization, supervision.

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Correspondence to Ayesha Younas, Tahir Iqbal or Abdullah Almohammedi.

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Younas, A., Iqbal, T., Almohammedi, A. et al. Experimental and theoretical comparative analysis of pure WO3 and La doped WO3 for degradation of MB. Opt Quant Electron 55, 1172 (2023). https://doi.org/10.1007/s11082-023-05446-9

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