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Synthesis of low cost transparent polymer/plants extracts composites films: structural, dielectric and optical characteristics for flexible antibacterial and radiation shielding applications

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Abstract

In this work, fabrication of polyvinyl alcohol (PVA)/plants extracts (Laurus nobilis, Calyptus, Bember) biodegradable composites bio-films for antibacterial, gamma ray shielding and UV-shielding has been investigated with few cost, elevated corrosion resistance, lightweight, good antibacterial activity and good absorption for high photon energy compared of other films. The FTIR, optical and A.C electrical characterizations of PVA/plant extracts composites were studied. The results of dielectric characterization indicated to improve the dielectric parameters (ε′, ε″ and σA.C) with rise in plants extracts ratios. The results of optical characterization for biodegradable composites give that the absorption, extinction coefficient, absorption coefficient, dielectric constants, refractive index, optical conductivity of polymer rise while transmission and energy gap reduced with rising of plants extracts ratios. The absorbance increases about 69.2% at λ = 220 nm while the energy gap reduces about 47.6% with adding of 20 vol% of the plants extracts. The antibacterial testing for PVA/plant extracts composites indicated to the good antibacterial performance of composites samples. Also, the composites tested for gamma ray attenuation which showed the PVA/plant extracts composites have good attenuation for gamma ray. Finally, results showed that PVA/plants extracts composites can be used for antibacterial, gamma ray attenuation and UV-shielding applications with good flexibility and excellent efficiency.

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References

  • Abbas, M., Arshad, M., Rafique, M.K., Altalhi, A.A., Saleh, D.I., Ayub, M.A., Sharif, S., Riaz, M., Alshawwa, S.Z., Masood, N., Nazir, A., Iqbal, M.: Chitosan-polyvinyl alcohol membranes with improved antibacterial properties contained Calotropis procera extract as a robust wound healing agent. Arab. J. Chem. 15, 103766 (2022). https://doi.org/10.1016/j.arabjc.2022.103766

    Article  Google Scholar 

  • Abdelrazek, E.M., Abdelghany, A.M., Aldhabi, A.A.: Influence of manganese chloride filler on optical and structural properties of PVA/PVP films. Mater. Sci. Indian J. 10(1), 1–11 (2013)

    Google Scholar 

  • Abduljalil, H., Hashim, A., Jewad, A.: The Effect of addition titanium dioxide on electrical properties of poly-methyl methacrylate. Eur. J. Sci. Res. 63(2), 231–235 (2011)

    Google Scholar 

  • Abral, H., Ikhsan, M., Rahmadiawan, D., Handayani, D., Sandrawati, N., Sugiarti, E., Muslimin, A.N.: Anti-UV, antibacterial, strong, and high thermal resistant polyvinyl alcohol/Uncaria gambir extract biocomposite film. J. Mater. Res. Technol. 17, 2193–2202 (2022). https://doi.org/10.1016/j.jmrt.2022.01.120

    Article  Google Scholar 

  • Agarwal, S., Saraswat, Y.K., Saraswat, V.K.: Study of optical constants of ZnO dispersed PC/PMMA blend nanocomposites. Open Phys. J. 3, 63–72 (2016). https://doi.org/10.2174/1874843001603010063

    Article  ADS  Google Scholar 

  • Ahmed, H., Hashim, A., Abduljalil, H.M.: Analysis of structural, electrical and electronic properties of (polymer nanocomposites/silicon carbide) for antibacterial application, Egypt. J. Chem. 62(4), 1167–1176 (2019). https://doi.org/10.21608/EJCHEM.2019.6241.1522

    Article  Google Scholar 

  • Al-Aaraji, N.A.H., Hashim, A., Hadi, A., et al.: Effect of silicon carbide nanoparticles addition on structural and dielectric characteristics of PVA/CuO nanostructures for electronics devices. SILICON 14, 4699–4705 (2022). https://doi.org/10.1007/s12633-021-01265-3

    Article  Google Scholar 

  • Aruan, N.M., Sriyanti, I., Edikresnha, D., Suciati, T., Munir, M.M., Khairurrijal.: Polyvinyl alcohol/soursop leaves extract composite nanofibers synthesized using electrospinning technique and their potential as antibacterial wound dressing. Procedia Eng. 170, 31–35 (2017). https://doi.org/10.1016/j.proeng.2017.03.006

    Article  Google Scholar 

  • Aydin, G., Zorlu, E.B.: Characterisation and antibacterial properties of novel biodegradable films based on alginate and roselle (Hibiscus sabdariffa L.) extract. Waste Biomass Valoriz. 13, 2991–3002 (2022). https://doi.org/10.1007/s12649-022-01710-3

    Article  Google Scholar 

  • Bodea, I.M., Cătunescu, G.M., Pop, C.R., Fit, N.I., David, A.P., Dudescu, M.C., Stănilă, A., Rotar, A.M., Beteg, F.I.: Antimicrobial properties of bacterial cellulose films enriched with bioactive herbal extracts obtained by microwave-assisted extraction. Polymers 14, 1435 (2022). https://doi.org/10.3390/polym14071435

    Article  Google Scholar 

  • El-sayd, E.A., Ibrahiem, A.A., Ahmed, R.M.: Effect of cobalt chloride on the optical properties of PVA/PEG blend. Arab J. Nucl. Sci. Appl. 52(1), 22–32 (2019)

    Google Scholar 

  • Habbeb, M.A., Hashim, A., AbidAli, A.-R.K.: The dielectric properties for (PMMA-LiF) composites. Eur. J. Sci. Res. 61(3), 367–371 (2011)

    Google Scholar 

  • Hashim, A.: Synthesis of SiO2/CoFe2O4 nanoparticles doped CMC: exploring the morphology and optical characteristics for photodegradation of organic dyes. J. Inorg. Organomet. Polym. 31, 2483–2491 (2021). https://doi.org/10.1007/s10904-020-01846-6

    Article  Google Scholar 

  • Hashim, A., Habeeb, M.A.: Synthesis and characterization of polymer blend-CoFe2O4 nanoparticles as a humidity sensors for different temperatures. Trans. Electr. Electron. Mater. 20, 107–112 (2019). https://doi.org/10.1007/s42341-018-0081-1

    Article  Google Scholar 

  • Hashim, A., Hadi, Q.: Novel of (niobium carbide/polymer blend) nanocomposites: fabrication and characterization for pressure sensor. Sens. Lett. 15, 1–3 (2017a). https://doi.org/10.1166/sl.2017.3892

    Article  Google Scholar 

  • Hashim, A., Hadi, A.: A novel piezoelectric materials prepared from (carboxymethyl cellulose-starch) blend-metal oxide nanocomposites. Sens. Lett. 15, 1019–1022 (2017b). https://doi.org/10.1166/sl.2017.3910

    Article  Google Scholar 

  • Hashim, A., Jassim, A.: Novel of biodegradable polymers-inorganic nanoparticles: structural, optical and electrical properties as humidity sensors and gamma radiation shielding for biological applications. J. Bionanosci. 12, 170–176 (2018). https://doi.org/10.1166/jbns.2018.1518

    Article  Google Scholar 

  • Hashim, A., Habeeb, M.A., Hadi, A.: Synthesis of novel polyvinyl alcohol–starch-copper oxide nanocomposites for humidity sensors applications with different temperatures. Sens. Lett. 15(9), 758–761 (2017). https://doi.org/10.1166/sl.2017.3876

    Article  Google Scholar 

  • Hashim, A., Habeeb, M.A., Khalaf, A., Hadi, A.: Fabrication of (PVA-PAA) blend-extracts of plants bio-composites and studying their structural, electrical and optical properties for humidity sensors applications. Sens. Lett. 15, 589–596 (2017). https://doi.org/10.1166/sl.2017.3856

    Article  Google Scholar 

  • Henaish, A.M.A., Abouhaswa, A.S.: Effect ofWO3 nanoparticle doping on the physical properties of PVC polymer. Bull. Mater. Sci. 43, 149 (2020). https://doi.org/10.1007/s12034-020-2109-5

    Article  Google Scholar 

  • Indolia, A.P., Gaur, M.S.: Optical properties of solution grown PVDF-ZnO nanocomposite thin films. J. Polym. Res 20(43), 1–8 (2013)

    Google Scholar 

  • Jasim, F.A., Lafta, F., Hashim, A., Ali, M., Hadi, A.G.: Characterization of palm fronds-polystyrene composites. J. Eng. Appl. Sci. 8(5), 140–142 (2013)

    Google Scholar 

  • Jothibas, M., Manoharan, C., Johnson Jeyakumar, S., Praveen, P.: Study on structural and optical behaviors of In2O3 nanocrystals as potential candidate for optoelectronic devices. J. Mater. Sci. Mater. Electron. 26, 9600–9606 (2015). https://doi.org/10.1007/s10854-015-3623-x

    Article  Google Scholar 

  • Kamath, S.M.K., H. Kumar, H.G., Chandramani, R., Radhakrishna, M.C.: PVP influence on PVA crystallinity and optical band gap. Arch. Phys. Res. 6(2), 18–21 (2015)

    Google Scholar 

  • Mahfoudh, N., Karoui, K., Ben-Rhaiem, A.: Optical studies and dielectric response of [DMA]2MCl4 (M ¼ Zn and Co) and [DMA]2ZnBr 4. RSC Adv. 11, 24526–24535 (2021). https://doi.org/10.1039/d1ra03652a

    Article  ADS  Google Scholar 

  • Meng, Du., Cao, X.-Z., Xia, R., Zhou, Z.-P., Jin, S.-X., Wang, B.-Y.: Magnetic field aligned orderly arrangement of Fe3O4 nanoparticles in CS/PVA/Fe3O4 membranes. Chin. Phys. B 27(2), 027805 (2018)

    Article  ADS  Google Scholar 

  • Nasr, G.M., Abd-El-Haleem, A.S., Klingner, A., Alnozahy, A.M., Mourad, M.H.: The DC electrical properties of polyvinyl alcohol/multi-walled carbon nanotube composites. J. Multidiscip. Eng. Sci. Technol. 2(5), 884–889 (2015)

    Google Scholar 

  • Nayak, D., Choudhary, R.B.: Augmented optical and electrical properties of PMMA-ZnS nanocomposites as emissive layer for OLED applications. Opt. Mater. 91, 470–481 (2019). https://doi.org/10.1016/j.optmat.2019.03.040

    Article  ADS  Google Scholar 

  • Rahman, L., Goswami, J., Choudhury, D.: Assessment of physical and thermal behaviour of chitosan-based biocomposites reinforced with leaf and stem extract of Tectona grandis. Polym. Polym. Compos. 30, 1–12 (2022). https://doi.org/10.1177/09673911221076305

    Article  Google Scholar 

  • Shanshool, H.M., Yahaya, M., Yunus, W.M.M., Abdullah, I.Y.: Investigation of energy band gap in polymer/ZnO nanocomposites. J. Mater. Sci. Mater. Electron. (2016). https://doi.org/10.1007/s10854-016-5046-8

    Article  Google Scholar 

  • Siddaiah, T., Ojha, P., Kumar, N.O.G.V.R., Ramu, C.: Structural, optical and thermal characterizations of PVA/MAA:EA polyblend films. Mater. Res. 21(5), e20170987 (2018)

    Article  Google Scholar 

  • Tyagi, C., Devi, A.: Alteration of structural, optical and electrical properties of CdSe incorporated polyvinyl pyrrolidone nanocomposite for memory devices. J. Adv. Dielectr. 8(3), 1850020 (2018). https://doi.org/10.1142/S2010135X18500200

    Article  ADS  Google Scholar 

  • Varada Rajulu, KCh., Mohanty, B.N.: Dielectric and conductivity properties of some wood composites. Int. J. Eng. Technol. 8, 51–60 (2016)

    Google Scholar 

  • Waly, A.L., Abdelghany, A.M., Tarabiah, A.E.: Study the structure of selenium modified polyethylene oxide/polyvinyl alcohol (PEO/PVA) polymer blend. J. Market. Res. 14, 2962–2969 (2021). https://doi.org/10.1016/j.jmrt.2021.08.078

    Article  Google Scholar 

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Acknowledgment to University of Babylon.

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ZSH, NAAl-I, AH wrote the main manuscript text, prepared figures and reviewed the manuscript.

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Correspondence to Ahmed Hashim.

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Hamad, Z.S., Al-Isawi, N.A. & Hashim, A. Synthesis of low cost transparent polymer/plants extracts composites films: structural, dielectric and optical characteristics for flexible antibacterial and radiation shielding applications. Opt Quant Electron 55, 751 (2023). https://doi.org/10.1007/s11082-023-05052-9

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