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Modification of nickel micropatterns for sensor-active applications from deep eutectic solvents

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Abstract

In this work, we proposed a rapid single-stage laser-induced fabrication of bimetallic micropatterns on the oxide glass surface using deep eutectic solvents (DESs) consisting of choline chloride, citric acid along with nickel, copper and cobalt acetates as metallization solutions. The resulting bimetallic micropatterns were tested as working electrodes for non-enzymatic determination of dopamine. The linear range for dopamine detection was found to be 1–500 µM, with sensitivity of 340.4 µA mM− 1 and 615.2 µA mM− 1 and detection limit of 0.36 µM and 0.51 µM for Ni-Cu and Ni-Co sensor, respectively. For the first time, bimetallic Ni-Cu and Ni-Co structures have been obtained from DESs for high-performance dopamine detection with great potential for further application in non-enzymatic sensing and biosensing.

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Acknowledgements

The authors would like to thank the SPbSU Nanotechnology Interdisciplinary Centre, Centre for Physical Methods of Surface Investigation, Centre for Optical and Laser Materials Research and Centre for X-ray Diffraction Studies.

Funding

I.I.T., E.M.K., A.S.L. and M.S.P. acknowledge Russian Science Foundation (grant 20-79-10075).

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Authors and Affiliations

  1. Saint Petersburg State University, 7/9 Universitetskaya nab, 199034, St. Petersburg, Russia

    Aleksandra S. Levshakova, Evgeniia M. Khairullina, Maxim S. Panov, Ruzanna Ninayan, Andrey S. Mereshchenko, Andrey Shishov & Ilya I. Tumkin

  2. St. Petersburg State Chemical Pharmaceutical University, Professor Popov str., 14, lit, 197022, Saint Petersburg, Russia

    Maxim S. Panov

Authors
  1. Aleksandra S. Levshakova
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  2. Evgeniia M. Khairullina
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  3. Maxim S. Panov
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  4. Ruzanna Ninayan
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  5. Andrey S. Mereshchenko
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  6. Andrey Shishov
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  7. Ilya I. Tumkin
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Contributions

Conceptualization, I.I.T. and A.S.L.; methodology, I.I.T., E.M.K. and A.Yu.S.; formal analysis, E.M.K. and M.S.P.; investigation, A.S.L., E.M.K., R.N. and A.S.M.; data curation, E.M.K. and A.S.M.; writing—original draft preparation, A.S.L., R.N. and I.I.T.; writing—review and editing, I.I.T., E.M.K., A.Yu.S., and M.S.P.; visualization, E.M.K. and A.S.L.; supervision, I.I.T.; project administration, I.I.T.; funding acquisition, I.I.T. All authors have read and agreed to the published version of the manuscript.

Corresponding author

Correspondence to Ilya I. Tumkin.

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This article is part of the Topical Collection on Fundamentals of Laser Assisted Micro- & Nanotechnologies, Guest edited by Vadim Veiko, Tigran Vartanyan, Andrey Belikov and Eugene Avrutin.

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Levshakova, A.S., Khairullina, E.M., Panov, M.S. et al. Modification of nickel micropatterns for sensor-active applications from deep eutectic solvents. Opt Quant Electron 55, 267 (2023). https://doi.org/10.1007/s11082-022-04403-2

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