Abstract
PVA/PVP blended polymers loaded with nano Zn0.75-xCd0.25VxS (x = 0, 0.05. 0.1, 0.15) were synthesized by thermolysis and casting methods. Phase identification and crystal structure analysis of the nanopowders fillers were performed using Rietveld method. The X-ray diffraction and Fourier transform infrared analysis revealed the homogeneous distribution of the embedded nano-powder throughout the PVA/PVP matrix. The optical bandgaps of all loaded blends with the nano materials were decreased. All films demonstrated a normal dispersion character. The effect of vanadium amount in Zn0.75-xCd0.25VxS/PVA/PVP on different dispersion parameters was investigated in detail. The effect of nano filler on the fluorescence intensity and the emitted colors of different blends was explored. The studied samples may be useful in optoelectronics applications.
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Al-Baradi, A.M., Altowairqi, F.A., Atta, A.A., Badawi, A., Algarni, S.A., Almalki, A.S.A., Hassanien, A.M., Alodhayb, A., Kamal, A.M., El-Nahass, M.M.: Structural and optical characteristic features of RF sputtered CdS/ZnO thin films. Chin. Phys. B 29(8), 080702 (2020)
Badawi, A.: Engineering the optical properties of PVA/PVP polymeric blend in situ using tin sulfide for optoelectronics. Appl. Phys. A 126, 1–12 (2020)
Badawi, A., Alharthi, S.S., Althobaiti, M.G., Alharbi, A.N.: The effect of iron oxide content on the structural and optical parameters of polyvinyl alcohol/graphene nanocomposite films. J. Vinyl Addit. Technol. 28(1), 235–246 (2022)
El Hotaby, W., Sherif, H.H.A., Hemdan, B.A., Khalil, W.A., Khalil, S.K.H.: Assessment of in situ-prepared polyvinylpyrrolidone-silver nanocomposite for antimicrobial applications. Acta Phys. Pol. 131(6), 1554–1560 (2017)
Elashmawi, S., Abdelghany, A.M., Hakeem, N.A.: Quantum confinement effect of CdS nanoparticles dispersed within PVP/PVA nanocomposites. J. Mater. Sci. Mater. Electron. 24, 2956–2961 (2013)
El-naggar, A.M., Mohamed, M.B., Aldhafiri, A.M., Heiba, Z.K.: Effect of vacancies and vanadium doping on the structural and magnetic properties of nano LiFe2.5O4. J. Mater. Res. Technol. 9(6), 16435–16444 (2020)
El-naggar, A.M., Heiba, Z.K., Mohamed, M.B., Kamal, A.M., Lakshminarayana, G., Shar, M.A.: Structural, linear and nonlinear optical properties of poly (vinyl alcohol)(PVA)/polyethylene glycol (PEG)/SnS2: Y nanocomposite films. Optik 258, 168941(1–14) (2022)
El-naggar, A.M., Heiba, Z.K., Mohamed, M.B., Kamal, A.M., Osman, M.M., Albassam, A.A., Lakshminarayana, G.: Improvement of the optical characteristics of PVA/PVP blend with different concentrations of SnS2/Fe. J. Vinyl Addit. Technol. 28(1), 82–93 (2022)
Fan, L., Wang, M., Zhang, Z., Qin, G., Hu, X., Chen, Q.: Preparation and characterization of pva alkaline solid polymer electrolyte with addition of bamboo charcoal. Materials (Basel, Switzerland) 11(5), 679(1–14) (2018)
Farah, A.M., Thema, F.T., Dikio, E.D.: Electrochemical detection of hydrogen peroxide based on graphene oxide/prussian blue modified glassy carbon electrode. Int. J. Electrochem. Sci. 7, 5069–5083 (2012)
Gupta, S., Pramanik, A.K., Kailath, A., Mishra, T., Guha, A., Nayar, S., Sinha, A.: Composition dependent structural modulations in transparent poly(vinyl alcohol) hydrogels. Colloids Surf. B 74, 186–190 (2009)
Hashim, A.: Enhanced structural, optical, and electronic properties of In2O3 and Cr2O3 nanoparticles doped polymer blend for flexible electronics and potential applications. J. Inorg. Organomet. Polym. 30, 3894–3906 (2020)
Heiba, Z.K., Mohamed, M.B.: Structural, optical and magnetic properties of ZnS Co-doped with Cd and Fe. J. Inorg. Organomet. Polym. 30, 879–888 (2019)
Heiba, Z.K., Mohamed, M.B., Imam, N.G.: Hybrid luminescent CdS@ZnS nanocomposites. Ceram. Int. 41(10), 12930–12938 (2015)
Heiba, Z.K., Mohamed, M.B., Imam, N.G., Mostafa, N.Y.: Optical and electrical properties of quantum composite of polyvinyl alcohol matrix with CdSe quantum dots. Colloid Polym. Sci. 294(2), 357–365 (2016)
Heiba, Z.K., Mohamed, M.B., Plaisier, J.R., El-naggar, A.M., Albassam, A.A.: Influence of (Mn or Co)-doping on structural, magnetic and electronic properties of nano Zn0.75Cd0.25S. Chin. J. Phys. 67, 414–427 (2020)
Heiba, Z.K., Ghannam, M.M., Sanad, M.M.S., Albassam, A.A., Mohamed, M.B.: Structural, optical, and dielectric properties of nano-ZnMn2−xVxO4. J. Mater. Sci. Mater. Electron. 31(11), 8946–8962 (2020)
Heiba, Z.K., Mohamed, M.B., Badawi, A.: Effect of vanadium doping on the structural and optical characteristics of nano ZnCdS. Phys. Scr. 97(5), 055802 (2022)
Heiba, Z.K., Mohamed, M.B., Farag, N.M., Badawi, A.: Controlling the structural, linear and nonlinear optical and photoluminescent characteristics of NiCo2O4 via alloying with MnS. Appl. Phys. A 128(4), 1–12 (2022b)
Heiba, Z.K., El-naggar, A.M., Mohamed, M.B., Altowairqi, Y., Kamal, A.M., Abd-Elkader, O.H.: Modifying the optical properties of 0.7 PVA/0.3 PEG blend through doping with CdS/TM (TM: Fe, Mg, Mn). Opt. Mater. 123, 111938 (2022)
Heiba, Z.K., Mohamed, M.B., Badawi, A.: Structure and optical properties of nano-ZnMn2O4/CuS solid solution heterostructure. J. Sol-Gel Sci. Technol. 101(3), 637–648 (2022d)
Imam, N.G., Mohamed, M.B.: Environmentally friendly Zn0.75Cd0.25S/PVA heterosystem nanocomposite: UV-stimulated emission and absorption spectra. J. Mol. Struct. 1105, 80–86 (2016)
Kumar, G.N.H., Rao, J.L., Gopal, N.O., Narasimulu, K.V., Chakradhar, R.P.S., Rajulu, A.V.: Spectroscopic investigations of Mn2+ ions doped polyvinylalcohol films. Polymer 45, 5407–5415 (2004)
Kumar, K.K., Ravi, M., Pavani, Y., Bhavani, S., Sharma, A.K., Rao, V.V.R.N.: Investigations on the effect of complexation of NaF salt with polymer blend (PEO/PVP) electrolytes on ionic conductivity and optical energy band gaps. Phys. B 406, 1706–1712 (2011)
Li, X.G., Kresse, I., Springer, J., Nissen, J., Yang, Y.L.: Morphology and gas permselectivity of blend membranes of polyvinylpyridine with ethylcellulose. Polymer 42, 6859–6869 (2001)
Lutterotti, L.: Total pattern fitting for the combined size-strain-stress-texture determination in thin film diffraction. Nucl. Instrum. Methods Phys. Res. B. 268, 334–340 (2010)
Maheshwari, S.U., Govindan, K., Raja, M., Raja, A., Pravin, M.B.S., Vasanth Kumar, S.: Preliminary studies of PVA/PVP blends incorporated with HAp and β-TCP bone ceramic as template for hard tissue engineering. Biomed. Mater. Eng. 28, 401–415 (2017)
Manikandan, A., Vijaya, J.J., Kennedy, L.J., Bououdina, M.: Structural, optical and magnetic properties of Zn1−xCuxFe2O4 nanoparticles prepared by microwave combustion method. J. Mol. Struct. 1035, 332–340 (2013)
Manna, L., Banchero, M., Sola, D., Ferri, A., Ronchetti, S., Sicardi, S.: Impregnation of PVP microparticles with ketoprofen in the presence of supercritical CO2. J. Supercrit. Fluids 42, 378–384 (2007)
Rajesh, K., Crasta, V., Kumar, N.B.R., Shetty, G., Rekha, P.D.: Structural, optical, mechanical and dielectric properties of titanium dioxide doped PVA/PVP nanocomposite. J. Polym. Res. 26, 99 (2019)
Rajeswari, N., Selvasekarapandian, S., Sanjeeviraja, C., Kawamura, J., Bahadur, S.A.: A study on polymer blend electrolyte based on PVA/PVP with proton salt. Polym. Bull. 71, 1061–1080 (2014)
Ramesan, M.T., Varghese, M., Jayakrishnan, P., Periyat, P.: Silver-doped zinc oxide as a nanofiller for development of Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) blend nanocomposites. Adv. Polym. Technol. 37(1), 137–143 (2018)
Reddy, C.V.S., Han, X., Zhu, Q.-Y., Mai, L.-Q., Chen, W.: Dielectric spectroscopy studies on (PVP+ PVA) polyblend film. Microelect. Eng. 83(2), 281–285 (2006)
Ricciardi, R., Auriemma, F., Rosa, C.D., Laupretre, F.: Investigation of the crystallinity of freeze/thaw poly(vinyl alcohol) hydrogels by different techniques. Macromolecules 37(5), 9510–9516 (2004)
Rodríguez-Carvajal, J.: Recent advances in magnetic structure determination by neutron powder diffraction. Phys. B (Amsterdam Neth) 192, 55–69 (1993)
Tanaka, K.: Optical properties and photoinduced changes in amorphous As S films. Thin Solid Films 66, 271–279 (1980)
Tauc, J.: Optical properties and electronic structure of amorphous Ge and Si. Materials Res. Bulletin 3, 37–46 (1968)
Tichý, L., Ticha, H., Nagels, P., Callaerts, R., Mertens, R., Vlcek, M.: Optical properties of amorphous As–Se and Ge–As–Se thin films. Mater. Lett. 39, 122–128 (1999)
Wemple, S.H., Domenico, D.: Behavior of the electronic dielectric constant in covalent and ionic materials. Phys. Rev. B 3, 1338–1351 (1971)
Xia, Q., Zhao, X.J., Chen, S.J., Ma, W.Z., Zhang, J., Wang, X.L.: Effect of solution-blended poly(styrene-co-acrylonitrile) copolymer on crystallization of poly(vinylidene fluoride. Express Polym. Lett. 4(5), 284–291 (2010)
Yang, M., Wang, Y., Ren, Y., Liu, E., Fan, J., Hu, X.: Zn/Cd ratio-dependent synthetic conditions in ternary ZnCdS quantum dots. J. Alloys Compd. 752, 260–266 (2018)
Acknowledgements
This work is supported by Researchers Supporting Project number (RSP-2021/72), King Saud University, Riyadh, Saudi Arabia.
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This funding was provided by King Saud University, Riyadh, Saudi Arabia..
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Heiba, Z.K., El-naggar, A.M., Mohamed, M.B. et al. Modifications of the structural and optical properties of PVA/PVP loaded with Zn0.75-xCd0.25VxS nano powders. Opt Quant Electron 54, 452 (2022). https://doi.org/10.1007/s11082-022-03827-0
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DOI: https://doi.org/10.1007/s11082-022-03827-0