Skip to main content
Log in

Synthesis and study the concentration effect on the photocatalytic activity of titania nanoparticles as anti-bactria using reactive magnetron sputtering technique

  • Published:
Optical and Quantum Electronics Aims and scope Submit manuscript

Abstract

In this work, the dc reactive magnetron sputtering technique was used to prepare and deposit nanostructured titanium dioxide (TiO2) thin films on glass substrates. Titanium dioxide thin films of mixed phase (anatase+rutile) and single phase (anatase) were prepared using different gas mixing ratios, and for both of the two phases, they were diagnosed via x-ray diffraction (XRD). It was found that the contents of rutile in mixed phase dependent on the deposition time increased from the ratio of 40 to 46% and 50% as the deposition time increased from 3 h to 3.30 and 4 h. The photocatalytic activity of the mixed and single phase TiO2 was measured by kill the bacteria Escherichia coli (E.Coli) under exposure to UV-radiation. It was proven that the photocatalytic activity in the mixed phase (TiO2) gave better results weight fraction is 40% as an antibacterial activity. Based on the obtained results anti-bacterial activity of dioxide titanium nanoparticles was dependent on the concentration and phase of TiO2 and weight fraction of mixed-phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  • Al-Maliki, F.J., Hammadi, O.A., Al-Oubidy, E.A.: Optimization of rutile/anatase ratio in titanium dioxide nanostructures prepared by DC magnetron sputtering technique. Ir Jrnal of Science 60(Special issue), 91–98 (2019)

    Google Scholar 

  • Baiju, K.V., Shukla, S., Sandhya, K.S.: James, photocatalytic activity of Sol-Gel-Derived nanocrystalline Titania. J Phys Chem C 111(21), 7612–7622 (2007)

    Article  Google Scholar 

  • Balachandran, K., Venckatesh, R., Sivaraj, R.: Synthesis of nano TiO2-SiO2 composite using sol-gel method: effect on size, surface morphology and thermal stability. Int. J. Eng. Sci. Technol. 2(8), 3695–3700 (2010)

    Google Scholar 

  • Berridge, M.V., Tan, A.S., Coy, K.D.M., Wang, R.: The biochemical and cellular basis of cell proliferation assays that use tetrazolium salts. Biochemica 4, 14–19 (1996)

    Google Scholar 

  • Dunne, W.M.: Bacterial adhesion: seen any goodbiofilms lately. ClinMicrobiol Rev 15, 155–166 (2002)

    Google Scholar 

  • Fasciani, C., Lanterna, A.E., Giorgi, J.B., Scaiano, J.C.: Visible light production of hydrogen by ablated graphene: water splitting or carbon gasification. J. Am. Chem. Soc. 139, 11024–11029 (2017)

    Article  Google Scholar 

  • Habibi, M.H., Talebian, N.: The effect of annealing on photocatalytic properties of nanostructured titanium dioxide thin films. Dyes Pigments 73(1), 103–110 (2007)

    Article  Google Scholar 

  • Haghighi, F., Roudbar Mohammadi, S., Mohammadi, P., Hosseinkhani, S., Shidpour, R.: Antifungal activity of TiO2 nanoparticles and EDTA on Candida albicansBiofilms. Infect Epidemiol Med 1(1), 33–38 (2013)

    Google Scholar 

  • Hammadi, O.A.: Production of nanopowders from physical vapor deposited films on nonmetallic substrates by conjunctional freezing-assisted ultrasonic extraction method. Proc. IMechE, Part N, J Nanomat Nanoeng Nanosys 232(4), 135–140 (2018)

    Google Scholar 

  • Hammadi, O.A., Khalaf, M.K., Kadhim, F.J., Chiad, B.T.: Operation characteristics of a closed-field unbalanced dual-magnetrons plasma sputtering system. J. Phys. 41(1), 24–33 (2014)

    Google Scholar 

  • Hu, A., Zhang, X., Luong, D., Oakes, K.D., Servos, M.R., Liang, R., Kurdi, S., Peng, P., Zhou, Y.: Adsorption and photocatalytic degradation kinetics of pharmaceuticals by TiO2 nanowires during water treatment. Waste Biomass Valoriz. 3, 443–449 (2012)

    Article  Google Scholar 

  • Hurum, D.C., Agrios, A.G., Gray, K.A., Rajh, T., Thurnauer, C.: Explaining the enhanced photocatalytic activity of degussa P25 mixed-phase TiO2 using EPR. J. Phys. Chem. B 107, 4545 (2003)

    Article  Google Scholar 

  • Hurum, D.C., Gray, K.A., Rajh, T., Thurnauer, M.C.: Recombination pathways in the Degussa P25 formulation of TiO2: Surface versus lattice mechanisms. J PhysChem B 109, 977–980 (2005)

    Google Scholar 

  • Hussain, A.A., Wahab, H.S.: Synthesis and spectroscopic characterization of anatase TiO2 nanoparticles. Int. J. Nanotech. Nanosci. 2, 1–6 (2014)

    Google Scholar 

  • Jin, Y., Li, G., Zhang, Y., Zhang, Y., Zhang, L.: Photoluminescence of anatase TiO2 Thin films are achieved bythe addition of ZnFe2O4. J. Phys. Condens. Matter. 13, L913–L918 (2001)

    Article  ADS  Google Scholar 

  • Kadhim, F.J., Al-Oubidy, E.A.: Effect of gas mixing ratio on energy band gap of mixed-phase titanium dioxide nanostructures prepared by reactive magnetron sputtering technique. J. Phys 14(4), 19–23 (2018)

    Google Scholar 

  • Kaneko, M., Okura I.: In Photocatalysis: Science and Technology (Kodansha, 2002), p. 157

  • Karabay, I., Aydın Yüksel, S., Ongül, F., Öztürk, S., Asli, M.: Structural and optical characterization of TiO2thin films prepared by sol-gel process. Acta Phys. Pol. A 121(1), 265–267 (2012)

    Article  ADS  Google Scholar 

  • Kathiravan, A., Renganathan, R.: Photosensitization of colloidal TiO2 nanoparticles with phycocyanin pigment. J. Colloid Interface Sci. 335, 196–202 (2009)

    Article  ADS  Google Scholar 

  • Mi, W.B., Jiang, E.Y., Bai, H.L.: Structure, magnetic and optical properties of poly-crystalline Co-doped TiO2 films. J. Magn. Magn. Mater. 321(16), 2472–2476 (2009)

    Article  ADS  Google Scholar 

  • Riazian, M.: Electrical properties, and enhancement of photocatalytic activity of TiO2 nanorods doped with SiO2. S Afr J Chem 70, 189–199 (2017)

    Article  Google Scholar 

  • Stoller, M., Mescia, M., Valencia Peroni, C., Chianese, A.: Production of nanoparticles of titanium dioxide by using a spinning disc reactor. Chem Eng Trans 11, 71–76 (2007)

    Google Scholar 

  • Vijayalakshmi, R., Rajendran, V.: Synthesis and characterization of nano-TiO2 via different methods. Arch. Appl. Sci. Res. 4(2), 1183–1190 (2012)

    Google Scholar 

  • Wang, Y.W., Huang, Y., Ho, W.K., Zhang, L.Z., Zou, Z.G., Lee, S.C.: Biomolecule controlled hydrothermal synthesis of C-N-S-tridoped TiO2 nanocrystalline photocatalysts for NO removal under simulated solar light irradiation. J. Hazard. Mater. 169, 77–87 (2009)

    Article  Google Scholar 

  • Wei, J., Zhao, L., Peng, S., Shi, J., Liu, Z., Wen, W.: Wettability of urea-doped TiO2 nanoparticles and their high electrorheological effects. J. Sol-Gel Sci. Technol. 47, 311–315 (2008)

    Article  Google Scholar 

  • Yang, Y., Zhang, Q., Zhang, B., Mi, W.B., Chen, L., Li, L., Zhao, C., Diallo, E.M., Zhang, X.X.: The influence of metal interlayers on the structural and optical properties of nanocrystalline TiO2 films. Appl. Surf. Sci. 258(10), 4532–4537 (2012)

    Article  ADS  Google Scholar 

  • Zachariah, A., Baiju, K.V., Shukla, S., Deepa, K.S., James, J., Warrier, K.G.K.: Synergistic Effect in photocatalysis As observed for mixed-phase nanocrystalline titania processed via sol-gel solvent mixing and calcination. J. Phys. Chem. C 112, 11345–11356 (2008a)

    Article  Google Scholar 

  • Zachariah, A., Baiju, K.V., Shukla, S., Deepa, K.S., James, J., Warrier, K.G.K.: Synergistic effect in photocatalysis as observed for mixed-phase nanocrystalline titania processed via sol-gel solvent mixing and calcination. J. Phys. Chem. C112, 11345–11356 (2008)

    Google Scholar 

  • Zhao, Y., Li, C., Liu, X., Gu, F., Jiang, H., Shao, W., Zhang, L., He, Y.: Synthesis and optical properties of TiO2 nanoparticles. Mater Lett 61, 79–83 (2007)

    Article  Google Scholar 

Download references

Funding

The authors have not disclosed any funding.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Firas J. Al-Maliki.

Ethics declarations

Conflict of interest

The authors declare that they do not have any conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Al-Maliki, F.J., Al-Rubaiy, M.A. Synthesis and study the concentration effect on the photocatalytic activity of titania nanoparticles as anti-bactria using reactive magnetron sputtering technique. Opt Quant Electron 54, 377 (2022). https://doi.org/10.1007/s11082-022-03756-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11082-022-03756-y

Keywords

Navigation