Skip to main content
Log in

Optical and electrical properties of biocompatible and novel (CS–GO) polymer nanocomposites

  • Published:
Optical and Quantum Electronics Aims and scope Submit manuscript

Abstract

The objective of this paper is to give information about the optical and electrical characteristics measured of the CS–GO PNCs (chitosan-graphene oxide polymer nanocomposites), which is novel, biodegradable and biocompatible in nature. These nanocomposites have been synthesized by simple solution mixing technique trailed by ultrasonication treatment. The variation of GO nano-filler has shown a direct impact on the optical and electrical properties of the nanocomposite. According to the observations, optical absorption edge has a slightly shift towards the longer wavelength; while the optical band gap of the nanocomposite is constantly reduced on increasing the wt% of GO. In optical properties, the dielectric constant, dissipation factor and electrical conductivity have been found to increase with increasing wt% of GO in the PNC. Further, a shift in the relaxation frequency, at which dipole get relaxed indicating the interaction between the graphene and chitosan, has also been observed for different GO wt%. The conductivity of nanocomposites were increased to almost 10 times on increasing 2 wt% of GO. Taking into account the outcomes accomplished, the use of CS–GO PNC is reasonable for forthcoming advancement of optical sensors, and might be demonstrated as an expected possibility for the electrical or optoelectronic devices working at high frequencies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  • Abdelaziz, M.: Cerium (III) doping effects on optical and thermal properties of PVA films. Phys. B 406, 1300–1307 (2011)

    Article  ADS  Google Scholar 

  • Ajayan, P.M., Schadle, L.S., Giannaris, C., Rubio, A.: Single-walled carbon naotube-polymer composites: strength and weakness. Adv. Mater. 12, 750–753 (2000)

    Article  Google Scholar 

  • Al-Naamani, L., Dobretsov, S., Dutta, J.: Chitosan-zinc oxide nanoparticle composite coating for active food packaging applications. Innov. Food Sci. Emerg. Technol. 38, 231–237 (2010)

    Article  Google Scholar 

  • Alvi, P.A., Hashmi, S.Z., Dalela, S., Rahman, F.: Mathematical simulation of graphene with modified c–c bond length and transfer energy. J. Nano-Electron. Phys. 3(3), 42–50 (2011)

    Google Scholar 

  • Aziz, S.B., Hamsan, M.H., Kadir, M.F.Z., Woo, H.J.: Design of polymer blends based on chitosan: POZ with improved dielectric constant for application in polymer electrolytes and flexible electronics. Adv. Polym. Technol. 2020, 1–10 (2020)

  • Bao, H., Pan, Y., Ping, Y., Sahoo, N.G., Wu, T., Li, L., Gan, L.H.: Chitosan-functionalized graphene oxide as a nanocarrier for drug and gene delivery. Small 7, 1569–1578 (2011)

    Article  Google Scholar 

  • Benucci, I., Liburdi, K., Cacciotti, I., Lombardelli, C., Zappino, M., Nanni, F., Esti, M.: Chitosan/clay nanocomposite films as supports for enzyme immobilization: an innovative green approach for winemaking applications. Food Hydrocolloids 74, 124–131 (2018)

    Article  Google Scholar 

  • Dangi, S.B., Khichar, K.K., Kumar, U., Hashmi, S. Z., Choudhary, B. L Kumar, S., Alvi, P.A.: Investigation of optical properties of PVA-GO nanocomposites. In: AIP Conference Proceedings, vol. 2220, p. 020082

  • Dharupaneedi, S.P., Anjanapura, R.V., Han, J.M., Aminabhavi, T.M.: Functionalized graphene sheets embedded in chitosan nanocomposite membranes for ethanol and isopropanol dehydration via pervaporation. Ind. Eng. Chem. Res. 53, 14474–14484 (2014)

    Article  Google Scholar 

  • Dong, X., Wei, C., Liang, J., Liu, T., Kong, D., Lv, F.: Thermosensitive hydrogel loaded with chitosan-carbon nanotubes for near infrared light triggered drug delivery. Colloids Surf. B 154, 253–262 (2017)

    Article  Google Scholar 

  • Fan, H., Wang, L., Zhao, K., Li, N., Shi, Z., Ge, Z., Jin, Z.: Fabrication, mechanical properties, and biocompatibility of graphene-reinforced chitosan composites. Biomacromol 11, 2345–2351 (2010)

    Article  Google Scholar 

  • Fazil, S., Bangesh, M., Rehman, W., Liaqat, K., Saeed, S., Sajid, M., Waseem, M., Shakeel, M., Bibi, I., Guo, C.-Y.: Mechanical, thermal, and dielectric properties of functionalized graphene oxide/polyimide nanocomposite films. Nanomater. Nanotechnol. 9, 1–8 (2019)

    Article  Google Scholar 

  • Figueroa, T., Aguayo, C., Fernández, K.: Design and characterization of chitosan-graphene oxide nanocomposites for the delivery of proanthocyanidins Int. J. Nanomed. 15, 1229–1238 (2020)

    Article  Google Scholar 

  • Hamsan, M.H., Shujahadeen, B.A., Azha, M.A.S., Azli, A.A., Shukur, M.F., Yusof, Y.M., Muzakir, S.K., Manan, N.S.A., Kadir, M.F.Z.: Solid-state double layer capacitors and protonic cell fabricated with dextran from Leuconostoc mesenteroides based green polymer electrolyte Mater. Chem. Phys. 241, 122290 (2020)

    Google Scholar 

  • Han, D., Yan, L., Chen, W., Li, W.: Preparation of chitosan/grapheneoxide composite film with enhanced mechanical strenght in the wet state. Carbohydr. Polym. 83, 653–658 (2011)

    Article  Google Scholar 

  • Justin, R., Chen, B.: Strong and conductive chitosan–reduced graphene oxide nanocomposites for transdermal drug delivery. J. Mater. Chem. B 2, 3759–3770 (2014)

    Article  Google Scholar 

  • Khakhal, H.R., Kumar, S., Dolia, S.N., Dalela, B., Vats, V.S., Hashmi, S.Z., Alvi, P.A., Kumar, S., Dalela, S.: Oxygen vacancies and F+ centre tailored room temperature ferromagnetic properties of CeO2 nanoparticles with Pr doping concentrations and annealing in hydrogen environment. J. Alloys Compd. 844, 156079 (2020)

    Article  Google Scholar 

  • Khichar, K.K., Dangi, S.B., Dhayal, V., Kumar, U., Hashmi, S.Z., Sadhu, V., Choudahry, B.L., Kumar, S., Kaya, S., Kuznetsov, A.E., Dalela, S., Gupta, S.K., Alvi, P.A.: Structural, optical, and surface morphological studies of ethyl cellulose/grapheme oxide nanocomposites. Polym. Compos. 41, 2792–2802 (2020)

    Article  Google Scholar 

  • Kim, D.S., Dhand, V., Rhee, K.Y., Park, S.-J.: Study on the effect of silanization and improvement in the tensile behavior of graphene-chitosan-composite. Polymers 7, 527–551 (2015)

    Article  Google Scholar 

  • Kosowska, K., Domalik-Pyzik, P., Krok-Borkowicz, M., Chłopek, J.: Synthesis and characterization of chitosan/reduced graphene oxide hybrid composites. Materials 12, 2077 (2019)

    Article  ADS  Google Scholar 

  • Kumar, M.N.V.R.: A review of chitin and chitosan applications. React. Funct. Polym. 46(1), 1–27 (2000)

    Article  Google Scholar 

  • Kumar, U., Upadhyay, S.: Structural, microstructure, optical, and dielectric properties of Sr1.99M0.01SnO4 (M: La, Nd, Eu) Ruddlesden–Popper oxide. J. Mater. Sci.: Mater. Electron. 31, 5721–5730 (2020)

  • Kumar, U., Kumar, A., Yadav, D., Upadhyay, S.: Synthesis and characterization of Ruddlesden-Popper system (Ba1−xSrx)2SnO4. Mater. Charact. 162, 110198 (2020)

    Article  Google Scholar 

  • Kumara, S., Sharma, M., Aljawfi, R.N., Chae, K.H., Kumar, R., Dalela, S., Alshoaibi, A., Ahmed, F., Alvi, P.A.: Tailoring the structural, electronic structure and optical properties of Fe: SnO2 nanoparticles. J. Electron Spectrosc. Relat. Phenomena 240, 146934 (2020)

    Article  Google Scholar 

  • Kumari, K., Aljawfi, R.N., Chawla, A.K., Kumar, R., Alvi, P.A., Alshoaibi, A., Vij, A., Ahmed, F., Abu-Samak, M., Kumar, S.: Engineering the optical properties of Cu doped CeO2 NCs for application in white LED. Ceram. Int. 46, 7482–7488 (2020)

    Article  Google Scholar 

  • Lee, C., Wei, X., Kysar, J.W., Hone, J.: Measurement of the elastic properties and intrinsic strength of monolayer grapheme. Science 321(5887), 385–388 (2008)

    Article  ADS  Google Scholar 

  • Lerf, A., Heyong, H., Forster, M., Klinowski, J.: Structure of graphite oxide revisited. J. Phys. Chem. B 102, 4477–4482 (1998)

    Article  Google Scholar 

  • Li, T., Gao, B., Tong, Z., et al.: Chitosan and graphene oxide nanocomposites as coatings for controlled-release fertilizer. Water Air Soil Pollut. 230, 146 (2019)

    Article  ADS  Google Scholar 

  • Lomeda, J.R., Doyle, C.D., Kosynkin, D.V., Hwang, W.-F., Tour, J.M.: Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets. J. Am. Chem. Soc. 103, 16201–16206 (2008)

    Article  Google Scholar 

  • Meng, F., Zheng, S., Li, H., Liang, Q., Liu, T.: Formation of ordered nanostructures in epoxy thermosets: a mechanism of reaction-induced microphase separation. Macromolecules 39, 5072–5080 (2006)

    Article  ADS  Google Scholar 

  • Muhammad, F.F., Aziz, S.B., Hussein, S.A.: Effect of the dopant salt on the optical parameters of PVA: NaNO3 solid polymer electrolyte. J. Mater. Sci.: Mater. Electron. 26, 521–529 (2015)

    Google Scholar 

  • Nogales, A., Ezquerra, T.A., Rueda, D.R., Martinez, F., Retuert, J.: Influence of water on the dielectric behaviour of chitosan film. Colloid Polym. Sci. 275(5), 419–425 (1997)

    Article  Google Scholar 

  • Patsidis, A.C., Psarras, G.C.: Applications of Dielectric, Polymers and Multicomponent Polymeric Systems: Thermal, Thermo-Mechanical and Dielectric Analysis, vol. 245. CRC Press, Boca Raton (2020)

    Google Scholar 

  • Qi, X., Pu, K.Y., Zhou, X., Li, H., Liu, B., Boey, F., Huang, W., Zhang, H.: Conjugated-polyelectrolyte functionalized reduced graphene oxide with excellent solubility and stability in polar solvents. Small 6, 663–669 (2010)

    Article  Google Scholar 

  • Reddy, K.R., Lee, K.P., Gopalan, A.I., Kim, M.S., Showkat, A.M., Nho, Y.: Synthesis of metal (Fe or Pd)/alloy (Fe–Pd)-nanoparticles-embedded multiwall carbon nanotube/sulfonated polyaniline composites by γ irradiation. J. Polym. Sci., Part A: Polym. Chem. 44(10), 3355–3364 (2006)

    Article  ADS  Google Scholar 

  • Reddy, K.R., Sin, B.C., Yoo, C.H., Sohn, D., Lee, Y.: Coating of multiwalled carbon nanotubes with polymer nanospheres through microemulsion polymerization. J. Colloid Interface Sci. 340(2), 160–165 (2009)

    Article  ADS  Google Scholar 

  • Sahu, J., Soni, S., Kumar, S., Dalela, B., Alvi, P.A., Sharma, S.S., Phase, D.M., Gupta, M., Kumar, S., Dalela, S.: Defects and oxygen vacancies tailored structural, optical and electronic structure properties of Co-doped ZnO nanoparticle samples probed using soft X-ray absorption spectroscopy. Vacuum 179, 109538 (2020)

    Article  ADS  Google Scholar 

  • Salavagione, H.J., Martinez, G., Ellis, G.: Recent advances in the covalent modification of graphene with polymers. Macromol. Rapid Commun. 32, 1771–1789 (2011)

    Article  Google Scholar 

  • Shao, L., Chang, X., Zhang, Y., Huang, Y., Yao, Y., Guo, Z.: Graphene oxide cross-linked chitosan nanocomposite membrane. Appl. Surf. Sci. 280, 989–992 (2013)

    Article  ADS  Google Scholar 

  • Smith, A.T., LaChance, A.M., Zeng, S., Liu, B., Sun, L.: Synthesis, properties, and applications of graphene oxide/reduced graphene oxide and their nanocomposites. Nano Mater. Sci. 1(1), 31–47 (2019)

    Article  Google Scholar 

  • Soni, S., Vats, V.S., Kumar, S., Dalela, B., Mishra, M., Meena, R.S., Gupta, G., Alvi, P.A., Dalela, S.: Structural, optical and magnetic properties of Fe-doped CeO2 samples probed using X-ray photoelectron spectroscopy. J. Mater. Sci. Electron. Mater. 29(12), 10141 (2018)

    Article  Google Scholar 

  • Szunerits, S., Boukherroub, R.: Antibacterial activity of graphene-based materials. J. Mater. Chem. B 4, 6892–6912 (2016)

    Article  Google Scholar 

  • Tavakoli, M., Bakhtiari, S.S.E., Karbasi, S.: Incorporation of chitosan/graphene oxide nanocomposite into the PMMA bone cement: physical, mechanical and biological evaluation. Int. J. Biol. Macromol. 149, 783–793 (2020)

    Article  Google Scholar 

  • Valencia Zapata, M.E., Mina Hernandez, J.H., Grande Tovar, C.D., Valencia Llano, C.H., Diaz Escobar, J.A., Vázquez-Lasa, B., San Román, J., Rojo, L.: Novel bioactive and antibacterial acrylic bone cement nanocomposites modified with graphene oxide and chitosan. Int. J. Mol. Sci. 20, 2938 (2019)

    Article  Google Scholar 

  • Wei, H., Wang, H., Li, A., Cui, D., Zhao, Z., Chu, L., Wei, X., et al.: Multifunctions of polymer nanocomposites: environmental remediation, electromagnetic interference shielding, and sensing applications. ChemNanoMat 6(2), 174–184 (2020)

    Article  Google Scholar 

  • Wrońska, N., Anouar, A., El Achaby, M., Zawadzka, K., Kędzierska, M., Miłowska, K., Katir, N., et al.: Chitosan-functionalized graphene nanocomposite films: interfacial interplay and biological activity. Materials 13(4), 998 (2020)

    Article  ADS  Google Scholar 

Download references

Acknowledgements

Authors are indebted to DST, Govt. of India for providing the experimental facilities through the CURIE project given to the Banasthali Vidyapith. One of the authors (P. A. Alvi) is heartily acknowledges to UGC-DAE Kolkata center via supportive project (File No: UGC-DAE-CSR-KC/CRS/19/RC14/0992/1027).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. A. Alvi.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dhayal, V., Hashmi, S.Z., Kumar, U. et al. Optical and electrical properties of biocompatible and novel (CS–GO) polymer nanocomposites. Opt Quant Electron 53, 53 (2021). https://doi.org/10.1007/s11082-020-02723-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11082-020-02723-9

Keywords

Navigation