Abstract
Influence of the solvent environments, pumping pulse energies and concentrations on the spectral properties of 1,2,3,8-tetrahydro-1,2,3,3,5-pentamethyl-7H-pyrrolo[3,2-g]quinolin-7-one (LD-423) have been investigated. The photophysical characteristics such as absorption, fluorescence spectra, Stokes’ shift, fluorescence quantum yield, absorption, emission cross sections, extinction coefficient and amplified spontaneous emission (ASE) were measured. Here, LD-423 showed two ASE in a certain organic solution under pulsed laser excitation (Nd: YAG λex = 355 nm). One of these peaks corresponds to the fluorescence, while the other peak is an anomalous peak which does not have a corresponding fluorescence peak. This abnormal ASE peak can be ascribed to the fact that the excited molecules are connected in the excited state and the solvent acts as a link between them.
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Al-Shamiri, H.A.S., Badr, Y., Kana, M.T.A.: Optical, photo-physical properties and photostability of laser dyes impregnated in sol–gel matrix. In: Electronics, Communications and Photonics Conference (SIECPC), 2011 Saudi International. IEEE (2011)
Deepa, H., et al.: Solvatochromic shift studies in LD-425 and LD-423: estimation of ground and excited state dipole moments. J. Mol. Liq. 181, 82–88 (2013)
del Valle, J.C., Kasha, M., Catalán, J.: Spectroscopy of amplified spontaneous emission laser spikes in phenyloxazoles. Prototype classes. J. Phys. Chem. A 101(18), 3260–3272 (1997)
Ibnaouf, K.: Dual ASE from the monomeric and excimeric states of a conjugated-polymer (PDHF) in solution. Opt. Laser Technol. 54, 309–314 (2013)
Ibnaouf, K.: Effects of the solvent environments on the ASE from coumarin 503. Opt. Int. J. Light Electron Opt. 126(24), 5057–5060 (2015)
Ibnaouf, K., et al.: Dual ASE spectra from” Superexciplex” TICT states of dye molecules. Laser Phys. Lawrence 15(11), 1536–1542 (2005)
Ibnaouf, K., et al.: Amplified spontaneous emission spectra from the superexciplex of coumarin 138. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 97, 1145–1151 (2012)
Masilamani, V., Aldwayyan, A.: Evidence of superexciplex in dye molecules. Jpn. J. Appl. Phys. 41(9R), 5801–5804 (2002)
Masilamani, V., et al.: Laser properties of a conjugate polymer (MEH-PPV) in the liquid-excimeric state. Laser Phys. 17(12), 1367–1373 (2007)
Mataga, N., Tsuno, S.: Hydrogen bonding effect on the fluorescence of some nitrogen heterocycles. I. Bull. Chem. Soc. Jpn. 30(4), 368–374 (1957)
Moulton, P.F.: Spectroscopic and laser characteristics of Ti: Al2O3. JOSA B. 3(1), 125–133 (1986)
Sastikumar, D., Masilamani, V.: Influence of solvents on amplified spontaneous emission characteristics of 7-diethylamino-4-methylcoumarin. In: Proceedings of the Indian Academy of Sciences-Chemical Sciences. Springer (1997)
Sastikumar, D., Masilamani, V.: Dual amplified spontaneous emission from 7-ethylamino-6-methyl-4-trifluoromethyl coumarin (coumarin 307). Indian J. Pure Appl. Phys. 34(10), 827–829 (1996)
Senthilkumar, S., Nath, S., Pal, H.: Photophysical properties of coumarin-30 dye in aprotic and protic solvents of varying polarities. Photochem. Photobiol. 80(1), 104–111 (2004)
Somasundaram, G., Ramalingam, A.: Gain studies of Coumarin 1 dye-doped polymer laser. J. Lumin. 90(1), 1–5 (2000)
Zhang, D., et al.: Low threshold amplified spontaneous emission based on coumarin 151 encapsulated in mesoporous SBA-15. Appl. Phys. Lett. (2006). https://doi.org/10.1063/1.2402908
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Ibnaouf, K.H., Alhathlool, R. Influence of solvents on the amplified spontaneous emission characteristics of LD-423. Opt Quant Electron 50, 289 (2018). https://doi.org/10.1007/s11082-018-1551-8
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DOI: https://doi.org/10.1007/s11082-018-1551-8