Abstract
In this paper, the optical properties of carbon films embedded by Ni nanoparticles under four deposition processing using mosaic targets made of graphite and nickel with Ni surface areas from 1.78 to 4.64% with a special emphasis on the absorption edge were investigated. Resulting films with Ni surface areas 1.78, 3.21, 3.92 and 4.64% have approximately Ni atomic ratio of about 59.7, 86.5, 90 and 92.9 wt%, respectively. The optical reflectance and transmittance spectra in the wavelength range 300–2500 nm were used to compute the absorption coefficient. The optical dispersion parameters were calculated according to Wemple and Didomenico single oscillator model (WDD). The variation of complex optical conductivity σ with energy of films exhibit values for optical gaps from about 0.8 to 4 eV which correspod to the fundamental indirect and direct gap which are about 0.3 to 3.7 eV. It can be seen that at Ni surface areas 3.92% the films have minimum indirect optical band gap about 0.2 eV. Due to high Ni content of films at 4.64%, they have maximum disordered. It can be seen that these optical properties were in consistent with room temperature electrical resistivity of films.
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Abbas, M.M., Shehab, A.Ab-M, Al-Samuraee, A.-K., Hassan, N.-A.: Effect of deposition time on the optical characteristics of chemically deposited nanostructure PbS thin films. Energy Procedia 6, 241–250 (2011)
Abdel-Aziz, M.M., Yahia, I.S., Wahab, L.A., Fadel, M., Afifi, M.A.: Determination and analysis of dispersive optical constant of TiO2 and Ti2O3 thin films. Appl. Surf. Sci. 252, 8163–8170 (2006)
Abrasonis, G., Krause, M., Mu¨cklich, A., Sedlackova, K., Radno´czi, G., Kreissig, U., Kolitsch, A., Moller, W.: Growth regimes and metal enhanced 6-fold ring clustering of carbon in carbon–nickel composite thin films. Carbon 45, 2995–3006 (2007)
Banerjee, P.P.: A simple derivation of the Fresnel diffraction formula. Proc. IEEE 73, 1859–1860 (1985)
Cavas, M., Yakuphanoglu, F., Amanullah, F.M.: Photoluminescence and optical properties of nanostructure Ni doped ZnO thin films prepared by sol–gel spin coating technique. J. Alloy. Compd. 509, 7900–7908 (2011)
Dalouji, V.: Effect of deposition time on surface plasmon resonance and Maxwell–Garnett absorption in RF-magnetron sputtered carbon-nickel films. Mater. Sci. Pol. 34, 337–343 (2016)
Dalouji, V., Elahi, S., Ahmadmarvili, A.: Electric susceptibility and energy loss functions of carbon-nickel composite films at different deposition times. Silicon (2016a). doi:10.1007/s12633-016-9409-9
Dalouji, V., Mohammad Elahi, S., Valedbagi, S.: Multiphonon hopping conduction in carbon–nickel composite films at different deposition time. Rare Met. (2016b). doi:10.1007/s12598-015-0686-z
Dalouji, V., Elahi, S.M., Naderi, S.: Surface plasmon resonance and electrical properties of RF: magnetron sputtered carbon–nickel composite films at different annealing temperatures. Rare Met. 35, 863–869 (2016c)
Dalouji, V., Elahi, S.M., Ghaderi, A., Solaymani, S.: Influence of annealing temperature on berthelot-type hopping conduction mechanism in carbon-nickel composite films. Chin. Phys. Lett. 33, 057203 (2016d)
Dalouji, V., Asareh, N., Hashemizadeh, S.A., Solaymani, S.: Carbon films embedded by nickel nanoparticles: The effect of deposition time on Berthelot-type hopping conduction parameters. Eur. Phys. J. Plus 131, 442 (2016e)
Dalouji, V., Elahi, S.M., Ghaderi, A., Solaymani, S.: Porosity evaluation and the power spectral densities analyses of carbon–nickel composite films annealed at different temperatures. Chin. Phys. Lett. 33, 086601 (2016f)
EL-Farahaty, K.A., Seisa, E.A., El-Sheikh, S.G.: Influence of wavelength and temperature on the optical and some structural properties of polyester and polyamide surgical suture fibers. Optical Materials 32, 928–935 (2010)
Gomez-Escoto, R., Ghafari, M., Hahn, H.: Reversible metal–semiconductor transition effects in heterogeneous superlattices. Rev. Mex. Fis. S 53, 240–244 (2007)
Habibi, M.H., Talebian, N.: The effect of annealing on structural, optical and electrical properties of nanostructured tin doped indium oxide thin films. Acta Chim. Slov. 52, 53–59 (2005)
Imran, M.M.A., Lafi, O.A., Abu-Samak, M.: Effect of thermal annealing on some electrical properties and optical band gap of vacuum evaporated Se65Ga30In5 thin films. Vacuum 86, 1589–1594 (2012)
Jayawardena, K.D.G.I., Tan, Y.Y., Fryar, J., Shiozawa, H., Silva, S.R.P., Henley, S.J., Fuge, G.M., Truscott, B.S., Ashfold, M.N.R.: Highly conductive nanoclustered carbon: nickel films grown by pulsed laser deposition. Carbon 49, 3781–3788 (2011)
Jeong, H.Y., Kim, Y.I., Lee, J.Y., Choi, S.Y.: A low-temperature-grown TiO2-based device for the flexible stacked RRAM application. Nanotechnology 21, 115203 (2010)
Kovács, G.J., Veres, M., Koós, M., Radnóczi, G.: Raman spectroscopic study of magnetron sputtered carbon–nickel and carbon nitride–nickel composite films: the effect of nickel on the atomic structure of the C/CN x matrix. Thin Solid Films 516, 7910–7915 (2008)
Lewin, E., Buchholt, K., Lu, J., Hultman, L., Spetz, A.L., Jansson, U.: Carbide and nanocomposite thin films in the Ti–Pt–C system. Thin Solid Films 518, 5104–5109 (2010)
Mahdavi, S.: Nano-TiO2 modified with natural and chemical compounds as efficient adsorbents for the removal of Cd+2, Cu+2, and Ni+2 from water. Clean Technol. Environ. Policy 18, 81–94 (2016)
Mahdavi, S., Akhzari, D.: The removal of phosphate from aqueous solutions using two nano-structures: copper oxide and carbon tubes. Clean Technol. Environ. Policy 18, 817–827 (2016)
Mahdavi, S., Amini, N., Merrikhpour, H., Akhzari, D.: Characterization of bare and modified nano-zirconium oxide (ZrO2) and their applications as adsorbents for the removal of bivalent heavy metals. Korean J. Chem. Eng. (2016). doi:10.1007/s11814-016-0259-3
Majeed Khan, M.A., Kumar, S., Ahamed, M., Alrokayan, S.A., Alsalhi, M.S., Alhoshan, M., Aldwayyan, A.S.: Structural and spectroscopic studies of thin film of silver nanoparticles. Appl. Surf. Sci. 257, 10607–10612 (2011)
Metin, H., Esen, R.: Kimyasal depolama yöntemi teknigiyle büyütülen cds filimlerinde fotoiletkenlik çalismalari/photoconductivity studies on cds films grown by chemcal bath deposition technque. Erciyes University Fen Bilimeri Enstitusu Dergisi 19(1–2), 96–102 (2003)
Mobius, A., Adkins, C.J.: Metal–insulator transition in amorphous alloys. Solid State Mater. Sci. 4, 303–323 (1999)
Moholkar, A.V., Agawane, G.L., Sim, K.-U., Kwon, Y.-B., Rajpure, K.Y., Kim, J.H.: Influence of deposition temperature on morphological, optical, electrical and opto-electrical properties of highly textured nanocrystalline spray deposited CdO: Ga thin films. Appl. Surf. Sci. 257, 93–101 (2010)
Montiel-González, Z., Rodil, S.E., Muhl, S., Mendoza-Galván, A., Rodríguez-Fernández, L.: Amorphous carbon gold nanocomposite thin films: structural and spectro-ellipsometric analysis. Thin Solid Films 519, 5924–5932 (2011)
Mott, N.F., Davis, E.A.: Electronic processe in non-crystalline materials. Clarendon Press, Oxford (1979)
Ohno, T., Tagawa, S., Itoh, H., Suzuki, H., Matsuda, T.: Size effect of TiO 2–SiO 2 nano-hybrid particle. Mater. Chem. Phys. 113, 119–123 (2009)
Pandey, B., Hussain, S.: Effect of nickel incorporation on the optical properties of diamond-like carbon (DLC) matrix. J. Phys. Chem. Solids 72, 1111–1116 (2011)
Reshak, A.H., Ebothe, J., Wojciechowski, A., Kuznik, W., Popeda, A.: Optically stimulated non-linear optics effects in semiconducting nano-crystallites. Physica E 42, 1769–1771 (2010)
Sakr, G.B., Yahia, I.S., Fadel, M., Fouad, S.S., Romcevic, N.: Optical spectroscopy, optical conductivity, dielectric properties and new methods for determining the gap states of CuSe thin films. J. Alloy. Compd. 507, 557–562 (2010)
Sbaï-Benchikh, N., Zeinert, A., Cailliérez, H., Donnet, C.: Optical properties of nickel-incorporated amorphous carbon film deposited by femtosecond pulsed laser ablation. Diam. Relat. Mater. 18, 1085–1090 (2009)
Sedlac kova, K., Grasin, R.O., Ujvari, T., Bertoti, I., Radnoczi, G.: Carbon-metal (Ni or Ti) nanocomposite thin films for functional applications. Solid State Sci. 11, 1815–1818 (2009)
Sedláckova, K., Czigány, Z., Ujvári, T., Bertoti, I., Grasin, R., Kovács, G.J., Radnóczi, G.: The effect of the carbon matrix on the mechanical properties of nanocomposite films containing nickel nanoparticles. Nanotechnology 18, 445604 (2007)
Stach, S., Garczyk, Ż., Ţălu, Ş., Solaymani, S., Ghaderi, A., Moradian, R., Nezafat Negin, B., Elahi, S.M., Gholamali, H.: Stereometric parameters of the Cu/Fe NPs thin films. J. Phys. Chem. C 119(31), 17887–17898 (2015)
Ţălu, Ş., Bramowicz, M., Kulesza, S., Ghaderi, A., Dalouji, V., Solaymani, S., Fathikenari, M., Ghoranneviss, M.: Fractal features and surface micromorphology of diamond nanocrystals. J. Microsc. 264, 143–152 (2016)
Ţălu, Ş., Bramowicz, M., Kulesza, S., Dalouji, V., Solaymani, S., Valedbagi, S.: Fractal features of carbon–nickel composite thin films. Microsc. Res. Tech. 79, 1208–1213 (2016a). doi:10.1002/jemt.22779
Ţălu, Ş., Bramowicz, M., Kulesza, S., Ghaderi, A., Dalouji, V., Solaymani, S., Khalaj, Z.: Microstructure and micromorphology of Cu/Co nanoparticles: surface texture analysis. Electron. Mater. Lett. 12(5), 580–588 (2016b)
Ţălu, Ş., Bramowicz, M., Kulesza, S., Shafiekhani, A., Ghaderi, A., Mashayekhi, F., Solaymani, S.: Microstructure and tribological properties of FeNPs@ aC: H films by micromorphology analysis and fractal geometry. Ind. Eng. Chem. Res. 54(33), 8212–8218 (2015a)
Ţălu, Ş., Stach, S., Ghodselahi, T., Ghaderi, A., Solaymani, S., Boochani, A., Garczyk, Ż., Phys, J.: Topographic characterization of Cu–Ni NPs@ aC: H films by AFM and multifractal analysis. Chem. B 119(17), 5662–5670 (2015b)
Wemple, S.H.: Refractive-index behavior of amorphous semiconductors and glasses. J. Phys. Rev. B 7, 3767–3777 (1973)
Wemple, S.H., Didomenico, M.: Behavior of the electronic dielectric constant in covalent and ionic materials. J. Phys. Rev. B 3, 1338–1351 (1971)
Yahia, I.S., Farag, A.A.M., Cavas, M., Yakuphanoglu, F.: Effects of stabilizer ratio on the optical constants and optical dispersion parameters of ZnO nano-fiber thin films. Superlatt. Microstruct. 53, 63–75 (2013)
Yang, S., Jones, A.H.S., Teer, D.G.: The development of sputtered carbon based coatings incorporating Cr, Ti, B and N. Surf. Coat. Technol. 369, 133–134 (2000)
Zhao, C.-H., Zhang, B.-P., Wang, S.-J., Shang, P.-P., Li, S., Yan, L.-P.: Microstructure and optical absorption property of the Cu/SiO 2 nano-films. Mater. Des. 32, 947–950 (2011)
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Dalouji, V., Asareh, N. Nonmetal–metal transition in carbon films embedded by nickel nanoparticles: absorption coefficients studies and Wemple–Didomenico dispersion parameters. Opt Quant Electron 49, 262 (2017). https://doi.org/10.1007/s11082-017-1092-6
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DOI: https://doi.org/10.1007/s11082-017-1092-6