Abstract
The purpose of this paper was to apply terahertz time-domain spectroscopy (THz-TDS) combined with clustering by fast search and find of density peaks (CFSFDP) for pesticide detection. To solve similar distance problem in THz spectra data, we proposed a method PCA-CFSFDP. Principal component analysis (PCA) was used to reduce dimensions of THz spectrum data, and then used the result of PCA as the input of CFSFDP. The performance of PCA-CFSFDP was investigated, and the experimental results showed that PCA-CFSFDP approach can get a satisfactory detection result. In addition, the proposed method was compared with K-means. The comparison results demonstrated that PCA-CFSFD outperforms K-means. Therefore, THz-TDS combined with PCA-CFSFDP is a potential identification tool for pesticide detection.
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References
Burnett, A.D., Fan, W., Upadhya, P.C., Cunningham, J.E., Hargreaves, M.D., Munshi, T., Edwards, H.G.M., Linfield, E.H., Davies, A.G.: Broadband terahertz time-domain spectroscopy of drugs-of-abuse and the use of principal component analysis. Analyst 134(8), 1658–1668 (2009)
Chen, T., Li, Z., Mo, W.: Identification of biomolecules by terahertz spectroscopy and fuzzy pattern recognition. Spectrochim. Acta A 106, 48–53 (2013). doi:10.1016/j.saa.2012.12.096
Chen, T., Li, Z., Yin, X., Hu, F., Hu, C.: Discrimination of genetically modified sugar beets based on terahertz spectroscopy. Spectrochim. Acta A 153, 586–590 (2016)
Dorney, T., Baraniuk, R., Mittleman, D.: Material parameter estimation with terahertz time-domain spectroscopy. J. Opt. Soc. Am. A 18(7), 1562–1571 (2001). doi:10.1364/JOSAA.18.001562
Du, S.Q., Li, H., Xie, L., Chen, L., Peng, Y., Zhu, Y.M., Li, H., Dong, P., Wang, J.T.: Vibrational frequencies of anti-diabetic drug studied by terahertz time-domain spectroscopy. Appl. Phys. Lett. 100(14), 1592 (2012)
Duvillaret, L., Garet, F., Coutaz, J.: A reliable method for extraction of material parameters in terahertz time-domain spectroscopy. IEEE J. Sel. Top. Quant. 2(3), 739–746 (1996). doi:10.1109/2944.571775
Exter, A.U., Fattinger, C.G.M.: Terahertz time-domain spectroscopy of water vapor. Opt. Lett. 14, 1128–1130 (1989)
Ge, H., Jiang, Y., Xu, Z., Lian, F., Zhang, Y., Xia, S.: Identification of wheat quality using THz spectrum. Opt. Express 22(10), 12533–12544 (2014)
Jain, A., Murty, M., Flynn, P.: Data clustering: a review. ACM Comput. Surv. 31(3), 264–323 (1999)
Leahy-Hoppa, M.R., Fitch, M.J., Osiander, R.: Terahertz spectroscopy techniques for explosives detection. Anal. Bioanal. Chem. 395(2), 247–257 (2009)
Liu, H.B., Zhong, H., Karpowicz, N., Chen, Y., Zhang, X.C.: Terahertz spectroscopy and imaging for defense and security applications. P. IEEE 95(8), 1514–1527 (2007)
Liu, J., Li, Z., Hu, F., Chen, T., Du, Y., Xin, H.: Identification of GMOs by terahertz spectroscopy and ALAP-SVM. Opt. Quant. Electron. 47(3), 685–695 (2015a)
Liu, J., Li, Z., Hu, F., Chen, T., Zhu, A.: A THz spectroscopy nondestructive identification method for transgenic cotton seed based on GA-SVM. Opt. Quant. Electron. 47(2), 313–322 (2015b)
Ma, Y., Li, X., Huang, P., Hou, D., Wang, Q., Zhang, G.: THz spectral data analysis and components unmixing based on non-negative matrix factorization methods. Spectrochim. Acta A 177, 49–57 (2017). doi:10.1016/j.saa.2017.01.009
Mehmood, R., Zhang, G., Bie, R., Dawood, H., Ahmad, H.: Clustering by fast search and find of density peaks via heat diffusion. Neurocomputing 208(SI), 210–217 (2016)
Melinger, J.S., Laman, N., Grischkowsky, D.: The underlying terahertz vibrational spectrum of explosives solids. Appl. Phys. Lett. 93(1), 44 (2008)
Pickwell, E., Cole, B., Fitzgerald, A., Pepper, M., Wallace, V.: In vivo study of human skin using pulsed terahertz radiation. Phys. Med. Biol. 49(9), 1595–1607 (2004)
Qi, N., Zhang, Z., Xiang, Y., Yang, Y., Liang, X., Harrington, PdB: Terahertz time-domain spectroscopy combined with support vector machines and partial least squares-discriminant analysis applied for the diagnosis of cervical carcinoma. Anal. Methods UK 7(6), 2333–2338 (2015)
Rodriguez, A., Laio, A.: Clustering by fast search and find of density peaks. Science 344(6191), 1492–1496 (2014)
Shi, Wei, Yujie, J.D.: Direct measurement of resonant frequencies for \(H_{2}O\) in the range of 0.2-4.2 THz by frequency-tuning monochromatic THz source. Lasers Electro Optics 1, 1–3 (2004)
You, T., Cheng, H.M., Ning, Y.Z., Shia, B.C., Zhang, Z.Y.: Community detection in complex networks using density-based clustering algorithm and manifold learning. Phys. A Stat. Mech. Appl. 464, 221–230 (2016)
Zeitler, J.A., Kogermann, K., Rantanen, J., Rades, T., Taday, P.F., Pepper, M., Aaltonen, J., Strachan, C.J.: Drug hydrate systems and dehydration processes studied by terahertz pulsed spectroscopy. Int. J. Pharm. 334(1–2), 78–84 (2007)
Zhan, H., Xi, J., Zhao, K., Bao, R., Xiao, L.: A spectral-mathematical strategy for the identification of edible and swill-cooked dirty oils using terahertz spectroscopy. Food Control 67, 114–118 (2016)
Zhong, J., Tse, P.W., Wei, Y.: An intelligent and improved density and distance-based clustering approach for industrial survey data classification. Expert Syst. Appl. 68, 21–28 (2017)
Acknowledgements
The authors gratefully acknowledge the support for this research by Yulin Normal University Research Grant (Grant No. 2016YJKY06), Nature Science Foundation of China (Grant No. 21565028), Guangxi Colleges and Universities Program of Innovative Research Team and Outstanding Talent.
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Qin, B., Li, Z., Luo, Z. et al. Terahertz time-domain spectroscopy combined with PCA-CFSFDP applied for pesticide detection. Opt Quant Electron 49, 244 (2017). https://doi.org/10.1007/s11082-017-1080-x
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DOI: https://doi.org/10.1007/s11082-017-1080-x
Keywords
- Terahertz time-domain spectroscopy
- PCA-CFSFDP
- Unsupervised learning
- Pesticide detection