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Lead sulfide colloidal nanocrystals with strong optical nonlinearity

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Abstract

Colloidal PbS nanocrystals have been synthesized by a developed procedure. UV–Vis absorption and Z-scan technique was also applied to study the nonlinear optical properties of prepared lead sulfide nanocrystals at 532 nm wavelength. The nonlinear refractive (n2) and absorption (β) were determined which are confirming the strong nonlinearity at 532 nm of colloidal PbS nanocrystals. The obtained results have not been reported before. In this study, only a weak thermal optical nonlinearity was observed and the dominating nonlinear response is resulted by the electronic origin. The nonlinear optical properties of prepared sample supported wide applications in nanophotonics.

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References

  • Ai, X., Guo, L., Zou, Y., Li, Q., Zhu, H.: The effect of surface modification on femtosecond optical Kerr effect of PbS nanoparticles. Mater. Lett. 38, 131–135 (1999)

    Article  Google Scholar 

  • Asunskis, D.J., Bolotin, I.L., Hanley, L.: Nonlinear optical properties of PbS nanocrystals grown in polymer solutions. J. Phys. Chem. C 112, 9555–9558 (2008)

    Article  Google Scholar 

  • Asunskis, D.J., Bolotin, I.L., Haley, J.E., Urbas, A., Hanley, L.: Effects of surface chemistry on nonlinear absorption of PbS nanocrystals. J. Phys. Chem. C 113, 19824–19829 (2009)

    Article  Google Scholar 

  • Bose, R., Gao, J., McMillan, J.F., Williams, A.D., Wong, C.W.: Cryogenic spectroscopy of ultra-low density colloidal lead chalcogenide quantum dots on chip-scale optical cavities towards single quantum dot near-infrared cavity QED. Opt. Exp. 17, 22474–22483 (2009)

    Article  ADS  Google Scholar 

  • Chen, S.Q., Liu, Z.B., Zang, W.P., Tian, J.G., Zhou, W.J., Song, F., Zhang, C.P.: Study on Z-scan characteristics for a large nonlinear phase shift. J. Opt. Soc. Am. B 22, 1911–1916 (2005)

    Article  ADS  Google Scholar 

  • Dementjev, A., Gulbinas, V.: Excited state absorption of PbS nanocrystals in silicate glass. Opt. Mater. 31, 647–652 (2009)

    Article  ADS  Google Scholar 

  • Dogan, S., Bielewicz, T., Cai, Y., Klinke, C.: Field-effect transistors made of individual colloidal PbS nanosheets. Appl. Phys. Lett. 101, 073102 (2012)

    Article  ADS  Google Scholar 

  • Dorranian, D., Golian, Y.: Effect of radio frequency plasma treatment on the nonlinear refractive index and absorption coefficient of red lake doped polyvinyl chloride film. Opt. Quantum Electron. 47, 2027–2038 (2015)

    Article  Google Scholar 

  • Dorranian, D., Golian, Y., Hojabri, A.: Investigation of nitrogen plasma effect on the nonlinear optical properties of PMMA. J. Theo. Appl. Phys. 6, 1–8 (2012)

    Article  Google Scholar 

  • Espinosa, D., Soga, D., Alves, S., De Boni, L., Carlos Zílio, S., Figueiredo Neto, A.M.: Investigation of the optical absorption of a magnetic colloid from the thermal to the electronic time-scale regime: measurement of the free carrier absorption cross-section. J. Opt. Soc. Am. B 29, 280–285 (2012)

    Article  ADS  Google Scholar 

  • Geethakrishnan, T., Palanisamy, P.K.: Z-scan determination of the third-order optical nonlinearity of a triphenylmethane dye using 633 nm He–Ne laser. Opt. Commun. 270, 424–428 (2007)

    Article  ADS  Google Scholar 

  • Kim, H.S., Lee, M.H., Jeong, N.C., Lee, S.M., Rhee, B.K., Yoon, K.B.: Very high third-order nonlinear optical activities of intrazeolite PbS quantum dots. J. Am. Chem. Soc. 128, 15070–15071 (2006)

    Article  Google Scholar 

  • Konstantatos, G., Sargent, E.H.: PbS colloidal quantum dot photoconductive photodetectors: transport, traps, and gain. Appl. Phys. Lett. 91, 173505 (2007)

    Article  ADS  Google Scholar 

  • Koushki, E., Farzaneh, A., Mousavi, S.H.: Closed aperture Z-scan technique using the Fresnel-Kirchhoff diffraction theory for materials with high nonlinear refractions. Appl. Phys. B 99, 565–570 (2010)

    Article  ADS  Google Scholar 

  • Kwak, C.H., Lee, Y.L., Kim, S.G.: Analysis of asymmetric Z-scan measurement for large optical nonlinearities in an amorphous As2S3 thin film. J. Opt. Soc. Am. B 16, 600–604 (1999)

    Article  ADS  Google Scholar 

  • Lee, K.-S., Prasad, P.N., Huyet, G., Tan, Ch.H.: Feature issue introduction: quantum dots for photonic applications. Opt. Mater. Express 2, 682–684 (2012)

    Article  Google Scholar 

  • Li, D., Liang, C.J., Liu, Y., Qian, S.X.: Femtosecond nonlinear optical properities of PbS nanoparticles. J. Lumin. 122–123, 549–551 (2007a)

    Article  Google Scholar 

  • Li, C., Shi, G., Xu, H., Guang, S., Yin, R., Song, Y.: Nonlinear optical properties of the PbS nanorods synthesized via surfactant-assisted hydrolysis. Mater. Lett. 61, 1809–1811 (2007b)

    Article  Google Scholar 

  • Liu, B., Li, H., Chew, C.H., Que, W., Lam, Y.L., Kam, C.H., Gan, L.M., Xu, G.Q.: PbS–polymer nanocomposite with third-order nonlinear optical response in femtosecond regime. Mater. Lett. 51, 461–469 (2001)

    Article  Google Scholar 

  • Liu, C., Kwon, Y.K., Heo, J.: Absorption and photoluminescence of PbS QDs in glasses. J. Non-Crystal Solids 355, 1880–1883 (2009)

    Article  ADS  Google Scholar 

  • Liu, X., Adachi, Y., Tomita, Y., Oshima, J., Nakashima, T., Kawai, T.: High-order nonlinear optical response of a polymer nanocomposite film incorporating semiconductor CdSe quantum dots. Opt. Exp. 20, 13457–13469 (2012)

    Article  ADS  Google Scholar 

  • Lu, S.W., Sohling, U., Mennig, M., Schmidt, H.: Nonlinear optical properties of lead sulfide nanocrystals in polymeric coatings. Nanotechnology 13, 669–673 (2002)

    Article  ADS  Google Scholar 

  • Lyakhovetsky, V.R., Volkov, V.I., Borshch, A.A., Brodyn, M.S., Strashnikova, M.I., Reznichenko, V.Y., Kutsenko, A.S., Maloletov, S.M., Kuchmy, S.Y., Kajzar, F.: New optical nonlinear material based upon PVA with PbS quantum dots. Mol. Cryst. Liq. Cryst. 426, 205–217 (2005)

    Article  Google Scholar 

  • Pálfalvi, L., Tóth, B.C., Almási, G., Fülöp, J.A., Hebling, J.: A general Z-scan theory. Appl. Phys. B 97, 679–685 (2009)

    Article  ADS  Google Scholar 

  • Samad, R.E., Vieira, N.D.: Analytical description of Z-scan on-axis intensity based on the Huygens-Fresnel principle. J. Opt. Soc. Am. B 15, 2742–2747 (1998)

    Article  ADS  Google Scholar 

  • Sasani Ghamsari, M., Radiman, S., Ambar Yarmo, M., Abdul-Hamid, M.A., Bananej, A.: Colloidal PbS nanocrystals with narrow photoluminescence spectra. Mater. Lett. 65, 1381–1384 (2011)

    Article  Google Scholar 

  • Sasani Ghamsari, M., Majles Ara, M.H., Radiman, S., Zhang, X.H.: Colloidal lead sulfide nanocrystals with strong green emission. J. Lumin. 137, 241–244 (2013)

    Article  Google Scholar 

  • Sendhil, K., Vijayan, C., Kothiyal, M.P.: Low-threshold optical power limiting of cw laser illumination based on nonlinear refraction in zinc tetraphenyl porphyrin. Opt. Laser Technol. 38(3), 512–515 (2006)

    Article  ADS  Google Scholar 

  • Seol, Y., Carpenter, A.E., Perkins, T.T.: Gold nanoparticles: enhanced optical trapping and sensitivity coupled with significant heating. Opt. Lett. 31, 2429–2431 (2006)

    Article  ADS  Google Scholar 

  • Sheik-Bahae, M., Said, A.A., Wei, T., Hagan, D.J., Van Stryland, E.W.: Sensitive measurement of optical nonlinearities using a single beam. IEEE J. Quantum Electron. 26, 760–769 (1990)

    Article  ADS  Google Scholar 

  • Szendrei, K., Gomulya, W., Yarema, M., Heiss, W., Loi, M.A.: PbS nanocrystal solar cells with high efficiency and fill factor. Appl. Phys. Lett. 97, 203501 (2010)

    Article  ADS  Google Scholar 

  • Wu, F.X., Yu, J.H., Joo, J., Hyeon, T., Zhang, J.Z.: Ultrafast electronic dynamics of monodisperse PbS and CdS nanoparticles/nanorods: effects of size on nonlinear relaxation. Opt. Mater. 29, 858–866 (2007)

    Article  ADS  Google Scholar 

  • Yao, B., Ren, L., Hou, X.: Z-scan theory based on a diffraction model. J. Opt. Soc. Am. B 20, 1290–1294 (2003)

    Article  ADS  MathSciNet  Google Scholar 

  • Yu, B., Yin, G., Zhu, C., Gan, F.: Optical nonlinear properties of PbS nanoparticles studied by the Z-scan technique. Opt. Mater. 11, 17–21 (1998)

    Article  ADS  Google Scholar 

  • Yu, B., Gu, Y., Mao, Y., et al.: Nonlinear optical properties of PbS nanoparticles under CW laser illumination”. J. Nonlinear Opt. Phys. Mater. 9, 117–125 (2000)

    ADS  Google Scholar 

  • Yue, F., Tomm, J.W., Kruschke, D., Glas, P., Bzheumikhov, K.A., Ch Margushev, Z.: PbS: Glass as broad-bandwidth near-infrared light source material. Opt. Express 21, 2287–2296 (2013)

    Article  ADS  Google Scholar 

  • Zhang, Y.D., Cao, B., Zhang, H.G., Zhu, J.J.: Nonlinear optical behavior of PbS nano-particles. Solid State Phenom. 121–123, 1367–1370 (2007)

    Article  Google Scholar 

Download references

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Sasani Ghamsari, M. Lead sulfide colloidal nanocrystals with strong optical nonlinearity. Opt Quant Electron 49, 168 (2017). https://doi.org/10.1007/s11082-017-1003-x

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