Abstract
Colloidal PbS nanocrystals have been synthesized by a developed procedure. UV–Vis absorption and Z-scan technique was also applied to study the nonlinear optical properties of prepared lead sulfide nanocrystals at 532 nm wavelength. The nonlinear refractive (n2) and absorption (β) were determined which are confirming the strong nonlinearity at 532 nm of colloidal PbS nanocrystals. The obtained results have not been reported before. In this study, only a weak thermal optical nonlinearity was observed and the dominating nonlinear response is resulted by the electronic origin. The nonlinear optical properties of prepared sample supported wide applications in nanophotonics.
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Ai, X., Guo, L., Zou, Y., Li, Q., Zhu, H.: The effect of surface modification on femtosecond optical Kerr effect of PbS nanoparticles. Mater. Lett. 38, 131–135 (1999)
Asunskis, D.J., Bolotin, I.L., Hanley, L.: Nonlinear optical properties of PbS nanocrystals grown in polymer solutions. J. Phys. Chem. C 112, 9555–9558 (2008)
Asunskis, D.J., Bolotin, I.L., Haley, J.E., Urbas, A., Hanley, L.: Effects of surface chemistry on nonlinear absorption of PbS nanocrystals. J. Phys. Chem. C 113, 19824–19829 (2009)
Bose, R., Gao, J., McMillan, J.F., Williams, A.D., Wong, C.W.: Cryogenic spectroscopy of ultra-low density colloidal lead chalcogenide quantum dots on chip-scale optical cavities towards single quantum dot near-infrared cavity QED. Opt. Exp. 17, 22474–22483 (2009)
Chen, S.Q., Liu, Z.B., Zang, W.P., Tian, J.G., Zhou, W.J., Song, F., Zhang, C.P.: Study on Z-scan characteristics for a large nonlinear phase shift. J. Opt. Soc. Am. B 22, 1911–1916 (2005)
Dementjev, A., Gulbinas, V.: Excited state absorption of PbS nanocrystals in silicate glass. Opt. Mater. 31, 647–652 (2009)
Dogan, S., Bielewicz, T., Cai, Y., Klinke, C.: Field-effect transistors made of individual colloidal PbS nanosheets. Appl. Phys. Lett. 101, 073102 (2012)
Dorranian, D., Golian, Y.: Effect of radio frequency plasma treatment on the nonlinear refractive index and absorption coefficient of red lake doped polyvinyl chloride film. Opt. Quantum Electron. 47, 2027–2038 (2015)
Dorranian, D., Golian, Y., Hojabri, A.: Investigation of nitrogen plasma effect on the nonlinear optical properties of PMMA. J. Theo. Appl. Phys. 6, 1–8 (2012)
Espinosa, D., Soga, D., Alves, S., De Boni, L., Carlos Zílio, S., Figueiredo Neto, A.M.: Investigation of the optical absorption of a magnetic colloid from the thermal to the electronic time-scale regime: measurement of the free carrier absorption cross-section. J. Opt. Soc. Am. B 29, 280–285 (2012)
Geethakrishnan, T., Palanisamy, P.K.: Z-scan determination of the third-order optical nonlinearity of a triphenylmethane dye using 633 nm He–Ne laser. Opt. Commun. 270, 424–428 (2007)
Kim, H.S., Lee, M.H., Jeong, N.C., Lee, S.M., Rhee, B.K., Yoon, K.B.: Very high third-order nonlinear optical activities of intrazeolite PbS quantum dots. J. Am. Chem. Soc. 128, 15070–15071 (2006)
Konstantatos, G., Sargent, E.H.: PbS colloidal quantum dot photoconductive photodetectors: transport, traps, and gain. Appl. Phys. Lett. 91, 173505 (2007)
Koushki, E., Farzaneh, A., Mousavi, S.H.: Closed aperture Z-scan technique using the Fresnel-Kirchhoff diffraction theory for materials with high nonlinear refractions. Appl. Phys. B 99, 565–570 (2010)
Kwak, C.H., Lee, Y.L., Kim, S.G.: Analysis of asymmetric Z-scan measurement for large optical nonlinearities in an amorphous As2S3 thin film. J. Opt. Soc. Am. B 16, 600–604 (1999)
Lee, K.-S., Prasad, P.N., Huyet, G., Tan, Ch.H.: Feature issue introduction: quantum dots for photonic applications. Opt. Mater. Express 2, 682–684 (2012)
Li, D., Liang, C.J., Liu, Y., Qian, S.X.: Femtosecond nonlinear optical properities of PbS nanoparticles. J. Lumin. 122–123, 549–551 (2007a)
Li, C., Shi, G., Xu, H., Guang, S., Yin, R., Song, Y.: Nonlinear optical properties of the PbS nanorods synthesized via surfactant-assisted hydrolysis. Mater. Lett. 61, 1809–1811 (2007b)
Liu, B., Li, H., Chew, C.H., Que, W., Lam, Y.L., Kam, C.H., Gan, L.M., Xu, G.Q.: PbS–polymer nanocomposite with third-order nonlinear optical response in femtosecond regime. Mater. Lett. 51, 461–469 (2001)
Liu, C., Kwon, Y.K., Heo, J.: Absorption and photoluminescence of PbS QDs in glasses. J. Non-Crystal Solids 355, 1880–1883 (2009)
Liu, X., Adachi, Y., Tomita, Y., Oshima, J., Nakashima, T., Kawai, T.: High-order nonlinear optical response of a polymer nanocomposite film incorporating semiconductor CdSe quantum dots. Opt. Exp. 20, 13457–13469 (2012)
Lu, S.W., Sohling, U., Mennig, M., Schmidt, H.: Nonlinear optical properties of lead sulfide nanocrystals in polymeric coatings. Nanotechnology 13, 669–673 (2002)
Lyakhovetsky, V.R., Volkov, V.I., Borshch, A.A., Brodyn, M.S., Strashnikova, M.I., Reznichenko, V.Y., Kutsenko, A.S., Maloletov, S.M., Kuchmy, S.Y., Kajzar, F.: New optical nonlinear material based upon PVA with PbS quantum dots. Mol. Cryst. Liq. Cryst. 426, 205–217 (2005)
Pálfalvi, L., Tóth, B.C., Almási, G., Fülöp, J.A., Hebling, J.: A general Z-scan theory. Appl. Phys. B 97, 679–685 (2009)
Samad, R.E., Vieira, N.D.: Analytical description of Z-scan on-axis intensity based on the Huygens-Fresnel principle. J. Opt. Soc. Am. B 15, 2742–2747 (1998)
Sasani Ghamsari, M., Radiman, S., Ambar Yarmo, M., Abdul-Hamid, M.A., Bananej, A.: Colloidal PbS nanocrystals with narrow photoluminescence spectra. Mater. Lett. 65, 1381–1384 (2011)
Sasani Ghamsari, M., Majles Ara, M.H., Radiman, S., Zhang, X.H.: Colloidal lead sulfide nanocrystals with strong green emission. J. Lumin. 137, 241–244 (2013)
Sendhil, K., Vijayan, C., Kothiyal, M.P.: Low-threshold optical power limiting of cw laser illumination based on nonlinear refraction in zinc tetraphenyl porphyrin. Opt. Laser Technol. 38(3), 512–515 (2006)
Seol, Y., Carpenter, A.E., Perkins, T.T.: Gold nanoparticles: enhanced optical trapping and sensitivity coupled with significant heating. Opt. Lett. 31, 2429–2431 (2006)
Sheik-Bahae, M., Said, A.A., Wei, T., Hagan, D.J., Van Stryland, E.W.: Sensitive measurement of optical nonlinearities using a single beam. IEEE J. Quantum Electron. 26, 760–769 (1990)
Szendrei, K., Gomulya, W., Yarema, M., Heiss, W., Loi, M.A.: PbS nanocrystal solar cells with high efficiency and fill factor. Appl. Phys. Lett. 97, 203501 (2010)
Wu, F.X., Yu, J.H., Joo, J., Hyeon, T., Zhang, J.Z.: Ultrafast electronic dynamics of monodisperse PbS and CdS nanoparticles/nanorods: effects of size on nonlinear relaxation. Opt. Mater. 29, 858–866 (2007)
Yao, B., Ren, L., Hou, X.: Z-scan theory based on a diffraction model. J. Opt. Soc. Am. B 20, 1290–1294 (2003)
Yu, B., Yin, G., Zhu, C., Gan, F.: Optical nonlinear properties of PbS nanoparticles studied by the Z-scan technique. Opt. Mater. 11, 17–21 (1998)
Yu, B., Gu, Y., Mao, Y., et al.: Nonlinear optical properties of PbS nanoparticles under CW laser illumination”. J. Nonlinear Opt. Phys. Mater. 9, 117–125 (2000)
Yue, F., Tomm, J.W., Kruschke, D., Glas, P., Bzheumikhov, K.A., Ch Margushev, Z.: PbS: Glass as broad-bandwidth near-infrared light source material. Opt. Express 21, 2287–2296 (2013)
Zhang, Y.D., Cao, B., Zhang, H.G., Zhu, J.J.: Nonlinear optical behavior of PbS nano-particles. Solid State Phenom. 121–123, 1367–1370 (2007)
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Sasani Ghamsari, M. Lead sulfide colloidal nanocrystals with strong optical nonlinearity. Opt Quant Electron 49, 168 (2017). https://doi.org/10.1007/s11082-017-1003-x
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DOI: https://doi.org/10.1007/s11082-017-1003-x