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Preparation of high-sensitivity In2S3/Si heterojunction photodetector by chemical spray pyrolysis

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Abstract

High photosensitivity n-In2S3/p-Si heterojunction photodetectors were made by depositing indium sulfide In2S3 thin film on a p-type silicon substrate using chemical spray pyrolysis with molarity of 0.1 and 0.2 M at 400 °C. Characterization techniques of X-ray diffraction XRD, scanning electron microscopy SEM, energy dispersive X-ray EDX, atomic force microscopy AFM, UV–Vis spectrophotometer, and Hall measurements were utilized to investigate structural, optical and electrical properties of the films. XRD investigation revealed polycrystalline grown films. EDX analysis showed good stoichiometry synthesized films with [S]/[In] ratios of 1.04 and 1.08 for In2S3 films prepared with 0.1 and 0.2 M respectively. Optical energy gap of the films decreased from 2.87 to 2.7 eV after increasing film morality from 0.15 to 0.2 M. Photo-response investigation of photodetector prepared with 0.2 M showed two peaks of response located at 400 and 750 nm with photosensitivity of 0.5 and 0.68 A W−1 respectively. Pulsed responsivity of photodetectors at 365 nm was found to be 200 mV W−1 at 0.1 M and 250 mV W−1 at 0.2 M.

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References

  • Asikainen, T., Ritala, M., Leskela, M.: Growth of InS thin films by atomic layer epitaxy. Appl. Surf. Sci. 82(83), 122–125 (1994)

    Article  ADS  Google Scholar 

  • El Sbazly, A., Abd Elhady, D., Metwally, H., Seyam, M.: Electrical properties of thin films. J. Phys. Condens. Matter 10, 5943–5954 (1998)

    Article  ADS  Google Scholar 

  • Gopinath, G., Miles, R., Reddy, K.: Influence of bath temperature on the properties of In2S3 films grown by chemical bath deposition. Energy Proc. 34, 399–406 (2013)

    Article  Google Scholar 

  • Hariskos, D., Ruckh, M., Rühle, U., Walter, T., Schock, H., Hedström, J., Stolt, L.: A novel cadmium free buffer layer for Cu (In, Ga) Se2 based solar cells. Sol. Energy Mater. Sol. Cells 41(42), 345–353 (1996)

    Article  Google Scholar 

  • Hsiao, Y., Lu, C., Ji, L., Meen, T., Chen, Y., Chi, H.: Characterization of photovoltaics with In2S3 nanoflakes/p-Si heterojunction. Nanoscale Res. Lett. 9, 32–39 (2014)

    Article  ADS  Google Scholar 

  • Ismail, R.: Fabrication and characteristics study of n-Bi2O3/n-Si heterojunction. J. Semicond. Technol. Sci. 6, 119–123 (2006)

    Google Scholar 

  • Ismail, R., Al-Samarai, A.-M.E., Mohmed, S., Ahmed, H.: Characteristics of nanostructured CdO/Si heterojunction photodetector synthesized by CBD. Solid State Electron. 82, 115–121 (2013)

    Article  ADS  Google Scholar 

  • John, E., Thomas, W., Robert, I., Roy, K.: Measurement of minority carrier life time in solar cells from photo-induced open circuit voltage decay. IEEE Trans. Electron. Dev. 26, 733–739 (1979)

    Article  Google Scholar 

  • John, T., Kartha, C., Vijayakumar, K., Abe, T., Kashiwaba, Y.: Spray pyrolyzed β-In2S3 thin films: effect of postdeposition annealing. Vacuum 80, 870–875 (2006)

    Article  ADS  Google Scholar 

  • Kaleel, S.G., Suhail, M.H., Yasser, F.M.: Spray deposition of Cu:In2S3 thin films. Int. J. Emerg. Technol. Adv. Eng. 4, 613–622 (2014)

    Google Scholar 

  • Kim, W., Kim, C.: Optical energy gaps of β‐In2S3 thin films grown by spray pyrolysis. J. Appl. Phys. 60, 2631–2633 (1986)

    Article  ADS  Google Scholar 

  • Kraini, M., Bouguila, N., Halidou, I., Timoumi, A., Alaya, S.: Properties of In2O3 films obtained by thermal oxidation of sprayed In2S3. Mater. Sci. Semicond. Process. 16, 1388–1396 (2013)

    Article  Google Scholar 

  • Lajnef, M., Ezzaouia, H.: Structural and optical studies of In2S3 thin films prepared by sulferization of indium thin films. Open Appl. Phys. J. 2, 23–26 (2009)

    Article  ADS  Google Scholar 

  • Lin, P., Lin, S., Cheng, S., Ma, J., Lai, Y., Zhou, H., Jia, H.: Optical and electrical properties of Ag-doped ln2S3 thin films prepared by thermal evaporation. Adv. Mater. Sci. Eng. 4, 37086–37090 (2014)

    Google Scholar 

  • Liu, S., Yuan, X., Wang, P., Chen, Z., Tang, L., Zhang, E., Zhang, C., Liu, Y., Wang, W., Liu, C., Chen, C., Zou, J., Hu, W., Xiu, F.: Controllable growth of vertical heterostructure GaTexSe1−x/Si by molecular beam epitaxy. ACS Nano 9, 8592–8598 (2015)

    Article  Google Scholar 

  • Naghavi, N., Spiering, S., Powalla, M., Cavana, B., Lincot, D.: High‐efficiency copper indium gallium diselenide (CIGS) solar cells with indium sulfide buffer layers deposited by atomic layer chemical vapor deposition (ALCVD). Prog. Photovolt. Res. Appl. 11, 437–443 (2003)

    Article  Google Scholar 

  • Sabnis, S., Bhadane, P., Kulkarni, P.: Process flow of spray pyrolysis technique. IOSR J. Appl. Phys. 4, 7–11 (2013)

    Article  Google Scholar 

  • Sall, T., Nafidi, A., Soucase, B., Mollar, M., Hartitti, B., Fahoume, M.: Synthesis of In2S3 thin films by spray pyrolysis from precursors with different [S]/[In] ratios. J. Semicond. 35, 063002 (2014)

    Article  ADS  Google Scholar 

  • Streetman, B., Banerjee, S.: Solid State Electronic Devices, 6th edn, p. 221. Pearson Prentice Hall, Upper Saddle River (2010)

    Google Scholar 

  • Tauc, J., Grigorovici, R., Vancu, A.: Optical properties and electronic structure of amorphous germanium. Phys. Status Solidi B 15, 627–637 (1966)

    Article  ADS  Google Scholar 

  • Warrier, A., John, T., Vijayakumar, K., Kartha, C.: Structural and optical properties of indium sulfide thin films prepared by silar technique. Open Condens. Matter Phys. J. 2, 9–14 (2009)

    Article  ADS  Google Scholar 

  • Yoshida, T., Yamaguchi, K., Toyoda, H., Akao, K., Sugiura, T., Minoura, H., Nosaka, Y.: Chemical bath deposition of band gap tailored indium sulfide thin films. Electrochem. Soc. Proc. 97, 20–57 (1997)

    Google Scholar 

  • Yuan, X., Tang, L., Liu, S., Wang, P., Chen, Z., Zhang, C., Liu, Y., Wang, W., Zou, Y., Liu, C., Guo, N., Zou, J., Zhou, P., Hu, W., Xiu, F.: Arrayed van der Waals vertical heterostructures based on 2D GaSe grown by molecular beam epitaxy. Nano Lett. 15, 3571–3577 (2015a)

    Article  ADS  Google Scholar 

  • Yuan, X., Tang, L., Wang, P., Chen, Z., Zou, Y., Su, X., Zhang, C., Liu, Y., Wang, W., Liu, C., Chen, F., Zou, J., Zhou, P., Hu, W., Xiu, F.: Wafer-scale arrayed pn junctions based on few-layer epitaxial GaTe. Nano Res. 8, 3332–3341 (2015b)

    Article  Google Scholar 

  • Zhong, C., Luo, L., Tan, H., Geng, K.: Band gap optimization of the window layer in silicon heterojunction solar cells. Sol. Energy 108, 570–575 (2014)

    Article  ADS  Google Scholar 

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Ismail, R.A., Habubi, N.F. & Abbod, M.M. Preparation of high-sensitivity In2S3/Si heterojunction photodetector by chemical spray pyrolysis. Opt Quant Electron 48, 455 (2016). https://doi.org/10.1007/s11082-016-0725-5

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