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Effects of Methane Saturation and Nitrogen Pressure on N2–Enhanced Coalbed Methane Desorption Strain Characteristics of Medium-Rank Coal

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To understand the characteristics of medium-rank coal reservoir desorption in N2–enhanced coalbed methane (N2–ECBM), three groups of nitrogen injection–sealing–desorption strain tests, including atmospheric pressure and successive decreasing outlet pressure (SDOP) desorption, methane saturation and I/A pressure ratio tests (nitrogen injection pressure/methane adsorption pressure), were carried out with four coal samples using an adsorption/desorption strain instrument designed in-house. The results showed that atmospheric pressure desorption cannot represent the samples’ desorption characteristics during the process of reservoir drainage, and the test data for desorption shrinkage strain were 20–40% less than the SDOP desorption data. The average shrinkage/swelling strain ratios (SSRs) during the nitrogen sealing of the samples were directly proportional to the sample saturation. The shrinkage strain in samples with high methane saturations was assumed to arise from methane desorption in the micropore system. When the I/A pressure ratios were 2.3, 1.75 and 1.4, the cumulative SSR of the nitrogen sealing and the SDOP desorption were 198.01%, 118.07%, and 104.06%, respectively; the shrinkage strain was produced mainly during the nitrogen sealing stage. The relationship between the shrinkage/swelling strain and the volume of adsorbed/desorbed gas was a polynomial, while the relationship between the shrinkage strain and time was a negative exponential function. The shrinkage strain rate (the relationship between shrinkage strain and time) was affected by gas saturation and I/A pressure ratio. With increasing gas saturation, the shrinkage strain rate gradually decreased and then increased with increasing I/A pressure ratio. N2–ECBM was more effective for high-saturation and low-gas-content coal reservoirs. This work revealed the properties of desorption rate and strain deformation in N2–ECBM, providing guidance for N2–ECBM of medium-rank coal.

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References

  • Anggara, F., Sasaki, K., Rodrigues, S., & Sugai, Y. (2014). The effect of megascopic texture on swelling of a low rank coal in supercritical carbon dioxide. International Journal of Coal Geology, 125, 45–56.

    Google Scholar 

  • Busch, A., Gensterblum, Y., Krooss, B. M., & Siemons, N. (2006). Investigation of high-pressure selective adsorption/desorption behaviour of CO2 and CH4 on coals: An experimental study. International Journal of Coal Geology, 66(1–2), 53–68.

    Google Scholar 

  • Bustin, A. M. M., Bustin, R. M., Chikatamarla, L., Downey, R., & Mansoori, J. (2016). Learnings from a failed nitrogen enhanced coalbed methane pilot: Piceance Basin, Colorado. International Journal of Coal Geology, 165, 64–75.

    Google Scholar 

  • Chikatamarla, L., Cui, X., Bustin, R. M. (2004). Implications of volumetric swelling/shrinkage of coal in sequestration of acid gases. In 2004 international coalbed methane symposium proceedings, Tuscaloosa, Alabama. Paper 0435.

  • Cui, X., Bustin, R. M., & Dipple, G. (2004). Selective transport of CO2, CH4, and N2 in coals: insights from modeling of experimental gas adsorption data. Fuel, 83(3), 293–303.

    Google Scholar 

  • Czerw, K. (2011). Methane and carbon dioxide sorption/desorption on bituminous coal—Experiments on cubicoid sample cut from the primal coal lump. International Journal of Coal Geology, 85(1), 72–77.

    Google Scholar 

  • Czerw, K., Baran, P., & Zarębska, K. (2017). Application of the stretched exponential equation to sorption of mine gases and sorption induced swelling of bituminous coal. International Journal of Coal Geology, 173, 76–83.

    Google Scholar 

  • Day, S., Fry, R., Sakurovs, R., & Weir, S. (2010). Swelling of coals by supercritical gases and its relationship to sorption. Energy & Fuels, 24(4), 2777–2783.

    Google Scholar 

  • Fitzgerald, J. E., et al. (2005). Adsorption of methane, nitrogen, carbon dioxide and their mixtures on wet Tiffany coal. Fuel, 84(18), 2351–2363.

    Google Scholar 

  • Geng, Y., Tang, D., Xu, H., Tao, S., Ma, L., & Zhu, X. (2017). Experimental study on permeability stress sensitivity of reconstituted granular coal with different lithotypes. Fuel, 202, 12–22.

    Google Scholar 

  • Harpalani, S., & Schraufnagel, R. A. (1990). Shrinkage of coal matrix with release of gas and its impact on permeability of coal. Fuel, 69(5), 551–556.

    Google Scholar 

  • Hoch, O. F. (2005). The dry coal anomaly—The Horseshoe Canyon Formation of Alberta, Canada. In SPE 95872, annual technical conference and exhibition. Society of Petroleum Engineers.

  • Kang, J., Fu, X., Li, X., & Liang, S. (2019). Nitrogen injection to enhance methane and water production: An experimental study using the LF-NMR relaxation method. International Journal of Coal Geology, 211, 103228.

    Google Scholar 

  • Kang, J., Fu, X., Liang, S., Zhou, F., & Li, Y. (2018). Experimental study of changes in fractures and permeability during nitrogen injection and sealing of low-rank coal. Journal of Natural Gas Science and Engineering, 57, 21–30.

    Google Scholar 

  • Kiyama, T., et al. (2011). Coal swelling strain and permeability change with injecting liquid/supercritical CO2 and N2 at stress-constrained conditions. International Journal of Coal Geology, 85(1), 56–64.

    Google Scholar 

  • Levine, J. R. (1996). Model study of the influence of matrix shrinkage on absolute permeability of coal bed reservoirs. In R. Gayer & I. Harris (Eds.), Coalbed methane and coal geology (Vol. 109, pp. 197–212). London: Geological Society Special Publication.

    Google Scholar 

  • Li, Y., Yang, Z., & Li, X. (2019). Molecular simulation study on the effect of coal rank and moisture on CO2/CH4 competitive adsorption. Energy & Fuels, 33(9), 9087–9098.

    Google Scholar 

  • Lin, J., Ren, T., Cheng, Y., Nemcik, J., & Wang, G. (2019). Cyclic N2 injection for enhanced coal seam gas recovery: A laboratory study. Energy, 188, 116115.

    Google Scholar 

  • Liu, J., Fokker, P. A., & Spiers, C. J. (2017). Coupling of swelling, internal stress evolution, and diffusion in coal matrix material during exposure to methane. Journal of Geophysical Research: Solid Earth, 122(2), 844–865.

    Google Scholar 

  • Liu, J., Peach, C. J., & Spiers, C. J. (2016a). Anisotropic swelling behaviour of coal matrix cubes exposed to water vapour: Effects of relative humidity and sample size. International Journal of Coal Geology, 167, 119–135.

    Google Scholar 

  • Liu, S., Wang, Y., & Harpalani, S. (2016b). Anisotropy characteristics of coal shrinkage/swelling and its impact on coal permeability evolution with CO2 injection. Greenhouse Gases: Science and Technology, 5(6), 615–632.

    Google Scholar 

  • Lu, Y., et al. (2009). Influence of hydroxyapatite-coated and growth factor–releasing interference screws on tendon-bone healing in an ovine model. Arthroscopy: The Journal of Arthroscopic & Related Surgery, 25(12), 1427–1434.

    Google Scholar 

  • Majewska, Z., Ceglarska-Stefańska, G., Majewski, S., & Ziętek, J. (2009). Binary gas sorption/desorption experiments on a bituminous coal: Simultaneous measurements on sorption kinetics, volumetric strain and acoustic emission. International Journal of Coal Geology, 77(1–2), 90–102.

    Google Scholar 

  • Mavor, M. J., Corp., T., & Gunter, W. D. (2004). Secondary porosity and permeability of coal vs. gas composition and pressure. SPE90255.

  • Mavor, M. J., Gunter, W. D., Robinson, J. R., Law, D. H., & Gale, J. (2002). Testing for CO2 sequestration and enhanced methane production from coal. In SPE gas technology symposium. Society of Petroleum Engineers, Calgary, Alberta, Canada (p. 14).

  • Meng, Z., & Li, G. (2013). Experimental research on the permeability of high-rank coal under a varying stress and its influencing factors. Engineering Geology, 162, 108–117.

    Google Scholar 

  • Meng, Y., & Li, Z. (2018). Experimental comparisons of gas adsorption, sorption induced strain, diffusivity and permeability for low and high rank coals. Fuel, 234, 914–923.

    Google Scholar 

  • Moore, T. A. (2012). Coalbed methane: A review. International Journal of Coal Geology, 101, 36–81.

    Google Scholar 

  • Mosher, K., He, J., Liu, Y., Rupp, E., & Wilcox, J. (2013). Molecular simulation of methane adsorption in micro- and mesoporous carbons with applications to coal and gas shale systems. International Journal of Coal Geology, 109–110, 36–44.

    Google Scholar 

  • Nie, B., Fan, P., & Li, X. (2018). Quantitative investigation of anisotropic characteristics of methane-induced strain in coal based on coal particle tracking method with X-ray computer tomography. Fuel, 214, 272–284.

    Google Scholar 

  • Niu, Q., Cao, L., Sang, S., Zhou, X., & Liu, S. (2019). Experimental study of permeability changes and its influencing factors with CO2 injection in coal. Journal of Natural Gas Science and Engineering, 61, 215–225.

    Google Scholar 

  • Niu, Q., Cao, L., Sang, S., Zhou, X., & Wang, Z. (2018). Anisotropic adsorption swelling and permeability characteristics with injecting CO2 in coal. Energy & Fuels, 32(2), 1979–1991.

    Google Scholar 

  • Niu, Q., Cao, L., Sang, S., Zhou, X., Wang, Z., & Wu, Z. (2017). The adsorption–swelling and permeability characteristics of natural and reconstituted anthracite coals. Energy, 141, 2206–2217.

    Google Scholar 

  • Niu, Q., Cao, L., Sang, S., Zhou, X., Wang, W., Yuan, W., et al. (2020). Study on the anisotropic permeability in different rank coals under influences of supercritical CO2 adsorption and effective stress and its enlightenment for CO2 enhance coalbed methane recovery. Fuel, 262, 116515.

    Google Scholar 

  • Pan, Z., & Connell, L. D. (2007). A theoretical model for gas adsorption-induced coal swelling. International Journal of Coal Geology, 69(4), 243–252.

    Google Scholar 

  • Pan, Z., & Connell, L. D. (2011). Modelling of anisotropic coal swelling and its impact on permeability behaviour for primary and enhanced coalbed methane recovery. International Journal of Coal Geology, 85(3), 257–267.

    Google Scholar 

  • Pekot, L. J. & Reeves, S. R. (2002). Modeling coal matrix shrinkage and differential swelling with CO2 injection for enhanced coalbed methane recovery and carbon sequestration applications. Topical report, Contract No. DE-FC26-00NT40924, U.S. DOE, Washington, DC, 14, 17 pp.

  • Perera, M. S. A., & Ranjith, P. G. (2015). Enhanced coal bed methane recovery: Using injection of nitrogen and carbon dioxide mixture. In Handbook of clean energy systems. Wiley.

  • Reeves, S. R., & Oudinot, A. (2004). The Tiffany unit N2-ECBM pilot—A reservoir and economic analysis. In International coalbed methane symposium, Tuscaloosa, Alabama.

  • Reucroft, P. J., & Patel, H. (1986). Gas-induced swelling in coal. Fuel, 65(6), 816–820.

    Google Scholar 

  • Reucroft, P. J., & Sethuraman, A. R. (1987). Effect of pressure on carbon dioxide induced coal swelling. Energy & Fuels, 1(1), 72–75.

    Google Scholar 

  • Schepers, K. C., Oudinot, A. Y., & Ripepi, N. (2010). Enhanced gas recovery and CO2 storage in coalbed-methane reservoirs: Optimized injected–gas composition for mature basins of various coal rank. In SPE international conference on CO2 capture, storage, and utilization. Society of Petroleum Engineers.

  • St. George, J. D., & Barakat, M. A. (2001). The change in effective stress associated with shrinkage from gas desorption in coal. International Journal of Coal Geology, 45, 105–113.

    Google Scholar 

  • van Bergen, F., Spiers, C., Floor, G., & Bots, P. (2009). Strain development in unconfined coals exposed to CO2, CH4 and Ar: Effect of moisture. International Journal of Coal Geology, 77(1–2), 43–53.

    Google Scholar 

  • Wang, X. (2006). Influence of coal quality factors on seam permeability associated with coalbed methane production (p. 338). Sydney: University of New South Wales.

    Google Scholar 

  • Wang, H., Fu, X., Jian, K., Li, T., & Luo, P. (2015). Changes in coal pore structure and permeability during N2 injection. Journal of Natural Gas Science and Engineering, 27, 1234–1241.

    Google Scholar 

  • Wang, Z., Pan, J., Hou, Q., Niu, Q., Tian, J., Wang, H., et al. (2018). Changes in the anisotropic permeability of low-rank coal under varying effective stress in Fukang mining area, China. Fuel, 234, 1481–1497.

    Google Scholar 

  • Wang, K., Wang, G., Ren, T., & Cheng, Y. (2014). Methane and CO2 sorption hysteresis on coal: A critical review. International Journal of Coal Geology, 132, 60–80.

    Google Scholar 

  • Zhang, M., & Fu, X. (2019). Influence of reservoir properties on the adsorption capacity and fractal features of shales from Qinshui coalfield. Journal of Petroleum Science and Engineering, 177, 650–662.

    Google Scholar 

  • Zhou, Y., Li, Z., Zhang, R., Wang, G., Yu, H., Sun, G., et al. (2020). Desorption hysteresis of CO2 and CH4 in different coals with cyclic desorption experiments. Journal of CO2 Utilization, 40, 101200.

    Google Scholar 

  • Zhou, Y., Zhang, R., Wang, J., Huang, J., Li, X., & Wu, J. (2019). CO2 injection in coal: Advantages and influences of temperature and pressure. Fuel, 236, 493–500.

    Google Scholar 

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Acknowledgments

This study was sponsored by the independent innovation project of “Double First-Class” construction of the China University of Mining and Technology (2018ZZCX05) and the National Natural Science Foundation of China (41772158). The authors are grateful to the Research Institute of Petroleum Exploration and Development for the experimental support.

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Correspondence to Xuehai Fu.

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Wang, Z., Deng, Z., Fu, X. et al. Effects of Methane Saturation and Nitrogen Pressure on N2–Enhanced Coalbed Methane Desorption Strain Characteristics of Medium-Rank Coal. Nat Resour Res 30, 1527–1545 (2021). https://doi.org/10.1007/s11053-020-09783-4

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