Natural Molecular Hydrogen Seepage Associated with Surficial, Rounded Depressions on the European Craton in Russia
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In the Russian part of the European craton, several thousands of subcircular structures ranging in size from a hundred meters to several kilometers in diameter have been identified throughout the region extending from Moscow to Kazakhstan. Generally, these structures correspond to minor morphological depressions. In cultivated areas, the periphery of these structures is often outlined by a ring of soil bleaching associated with growth anomalies of vegetation. The cores of the structures commonly correspond to marshes, sometimes with lakes. Subsoil gas composition of these structures was studied. For this purpose, portable gas detectors were used, and the results obtained were confirmed by gas chromatography analysis. Inside and around these structures, the concentration of molecular hydrogen in soil was much greater inside than outside, up to 1.25% at 1.2 m in soils. The hydrogen is associated with a small quantity of methane. We estimated a daily hydrogen flow seeping out at the surface is between 21,000 and 27,000 m3 in one of these structures.
KeywordsHydrogen Seeps Craton Gas
We thank Hervé Toulhoat and Armand Lattes for their support for this research topic, ZAO “NTK” for their assistance with funding for this research, Pavel Vodnev, Aleksandr Sysolin, Olga Veretennikova, Irina Katsura, Vladimir Larin (Jr.) for their assistance with the fieldwork, and the anonymous reviewers for their comments and critics.
- Angino, E. E., Coveney, R. M. J., Goebel, E. D., Zeller, E. J., & Dreschhoff, G. A. M. (1984). Hydrogen and nitrogen—origin, distribution, and abundance, a followup. Oil & Gas Journal, 82, 142–146.Google Scholar
- Apps, J.A., Van De Kamp, P.C. (1993). Energy gases of abiogenic origin in the Earth’s crust. Future Energy Gases. United States Geological Survey Professional Paper, pp. 81–130.Google Scholar
- Birina, L.M. (Ed.). (1962). Map of pre-quaternary formations: N-37-III. Scale 1:200000. Geologic administration of Central regions (in Russian).Google Scholar
- Charlou, J.-L., Fouquet, Y., Bougault, H., Donval, J. P., Etoubleau, J., Jean-Baptiste, P., et al. (1998). Intense CH4 plumes generated by serpentinization of ultramafic rocks at the intersection of the 15°20′N fracture zone and the Mid-Atlantic Ridge. Geochimica et Cosmochimica Acta, 62, 2323–2333.CrossRefGoogle Scholar
- Coveney, R. M. J., Goebel, E. D., Zeller, E. J., Dreschhoff, G. A. M., & Angino, E. E. (1987). Serpentinization and origin of hydrogen gas in Kansas. AAPG Bulletin, 71, 39–48.Google Scholar
- Firstov, P. P., & Shirokov, V. A. (2005). Dynamics of molecular hydrogen and its relation to deformational processes at the Petropavlovsk–Kamchatskii geodynamic test site: Evidence from observations in 1999–2003. Geochemistry International, 43, 1056–1064.Google Scholar
- Iosifova, Yu. I., Gorbatkina, T. E., & Fadeeva, L. I. (1998). Geologic map of pre-quaternary sediments of Voronezh region. Scale 1:500 000. Ed. Gavryushova, E. A., Dashevskiy, V. V. Ministry of Natural Resources of Russian Federation (In Russian).Google Scholar
- Gusev, A. (1997). Gas-geochemical effects of modern geodynamic activity of platform structures (on example of South-East of Belarus). Schmidt Institute of Physics of the Earth of Russian Academy of Sciences. Dissertation (in Russian).Google Scholar
- Ikorsky, S. V., Gigashvili, G. M., Lanyov, V. S., Narkotiev, V. D., & Petersilye, I. A. (1999). The investigation of gases during the Kola Superdeep Borehole Drilling (to 11.6 km Depth), in: Whiticar, M. J., Faber, E. (Eds.), Geologisches Jahrbuch Reihe, D. E. Schweizerbart Science Publishers, Hannover, pp. 145–152.Google Scholar
- Jones, V.T., & Pirkle, R.J. (1981). Helium and hydrogen soil gas anomalies associated with deep or active faults, in: 181st ACS National Meeting. Atlanta.Google Scholar
- Larin, V.N. (1993). Hydridic Earth: the New Geology of Our Primordially Hydrogen-rich Planet. Ed. C. W. Hunt. Polar publishing, Alberta.Google Scholar
- Larin, N.V., Larin, V.N., & Gorbatikov A.V. (2010). Circular structures, caused by the deep seeping of hydrogen. Degassing of the Earth: Geotectonics, geodynamics, Deep Fluids, oil and gas; hydrocarbons and life. Russian Conference with International Participation Dedicated to the 100th Anniversary of Academician P.N. Kropotkin, p. 282 (in Russian).Google Scholar
- McCarthy, H., & McGuire, E. (1998). Soil gas studies along the Carlin trend, Eureka and Elko counties, Nevada. In: Tosdal, R.M. (Ed.), Contributions to the Gold Metallogeny of Northern Nevada. Open-File Report 98-338 1998. U.S. Dept. of the Interior, U.S. Geological Survey, pp. 243–250.Google Scholar
- Mukhin, Y. (1970). Main results of the deep hydrogeological studies in Central Russia sedimentation basin in connection with estimation of the prospects for oil and gas. Proceedings of VNIIGaz, (33/41), pp. 157–295 (in Russian).Google Scholar
- Semlitsch, R. D. (2000). Size does matter: The value of small isolated wetlands. National Wetlands Newsletter, 22, 5–6.Google Scholar
- Shcherbakov, A. V., & Kozlova, N. D. (1986). Occurrence of hydrogen in subsurface fluids and the relationship of anomalous concentrations to deep faults in the USSR. Geotectonics, 20, 120–128.Google Scholar
- Shestopalov, V. M., & Makarenko, A. N. (2013). On several results of research, developing the idea of V.I. Vernadskiy about “gas breathing” of the Earth. Geological Journal, 3, 7–25. (in Russian).Google Scholar
- Shik, S.M. (Ed.), (2000). Map of pre-quaternary formations: M-37, (38) (Voronezh). Scale 1:1000000. FGUP “VSEGEI” (in Russian).Google Scholar
- Shishov, S. I. (2010). Geography and soil geochemistry characteristics of delineated depressions in the Ryazan region. Bulletin of the Esenin Ryazan State University, 28(3), 116–129. (in Russian).Google Scholar
- Smith, N.J.P., Shepherd, T.J., Styles, M.T., & Williams, G.M., (2005). Hydrogen exploration: a review of global hydrogen accumulations and implications for prospective areas in NW Europe, in: Petroleum Geology: North-West Europe and Global Perspectives—Proceedings of the 6th Petroleum Geology Conference. Geological Society, London, pp. 349–358. Google Scholar
- Syvorotkin, V. L. (2010). Hydrogen degassing of the earth: Natural disasters and the biosphere. Man and the Geosphere (pp. 307–347). New York: Nova Science Publishers.Google Scholar
- Takai, K., Gamo, T., Tsunogai, U., Nakayama, N., Hirayama, H., Nealson, K.H., & Horikoshi, K. (2004). Geochemical and microbiological evidence for a hydrogen-based, hyperthermophilic subsurface lithoautotrophic microbial ecosystem (HyperSLiME) beneath an active deep-sea hydrothermal field. Extremophiles, 8, 269–82.Google Scholar
- Toulhoat, H., Beaumont, V., Zgonnik, V., Larin, N. V., & Larin, V. N. (2012). Chemical differentiation of planets: a core issue. Submitted for publication. Available at: http://arxiv.org/abs/1208.2909.
- Urdukhanov, R. I., Nikolaev, I. N., Voytov, G. I., Daniyalov, M. G., Prutskaya, L. D., Parshikova, N. G., et al. (2002). Instability of the hydrogen field in atmosphere of soils and subsoils in response to the earthquake in Dagestan in 1998–2000. Proceedings of the Academy of Science, Section Geophysics, 385(6), 818–822. (in Russian).Google Scholar
- Vacquand, C., (2011). Genèse et mobilité de l’hydrogène dans les roches sédimentaires: source d’énergie naturelle ou vecteur énergétique stockable? PhD dissertation. IFP Energies Nouvelles and Institut de Physique du Globe de Paris. Available at: http://www.ipgp.fr/docs/publications/theses/20110318-vacquand.pdf.
- Zgonnik, V., Beaumont, V., Deville, E., Larin, N., Pillot, D., & Farrell, K. Evidence for natural molecular hydrogen seepage associated with surficial, rounded depressions. The Atlantic Coastal Plain Province of the USA (Under review).Google Scholar