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Electrolytic synthesis of metallic aluminum nanoparticles in aqueous solution

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Abstract

The present paper describes the preparation of metallic aluminum (Al) nanoparticles in an aqueous solution. An aqueous colloidal solution containing metallic Al nanoparticles was prepared by electrolyzing an Al salt aqueous solution using two metallic Al plate electrodes. Simultaneous electrolysis and sonication was necessary for the successful synthesis of metallic Al particles with a cubic crystal structure. Metallic Al particles were mainly produced on the cathode. Electrolysis under sonication was performed under various conditions. The morphology of the particles strongly depended on the temperature, electrolysis time, and sonication frequency, which could be mainly explained by changes in particle collision frequency and dissolution, particle collision frequency, and attenuation in the medium and/or cavitation stability, respectively. Metallic Al particles could be prepared using a stainless-steel plate as the cathode. Under the appropriate conditions, metallic Al particles with particle sizes of ca. 75–130 nm could be synthesized.

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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

We would like to thank Takehiro Yonezawa of the Innovation Center, Mitsubishi Materials Corporation, Japan, for facilitating the fruitful discussion on the present work.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Graduate School of Science and Engineering, Ibaraki University, 4-12-1 Naka-narusawa-cho, Hitachi, Ibaraki, 316-8511, Japan

    Takefumi Hosoya, Shiori Sato, Yoshiki Ueno, Ayumi Takahashi, Noriko Yamauchi, Shohei Tada & Yoshio Kobayashi

  2. Division of Applied Chemistry, Graduate School of Engineering, Hokkaido University, N13 W8, Kita-ku, Sapporo, Hokkaido, 060-8628, Japan

    Shohei Tada

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  1. Takefumi Hosoya
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  2. Shiori Sato
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Contributions

Takefumi Hosoya: methodology, investigation, formal analysis, writing—original draft. Shiori Sato: methodology, investigation. Yoshiki Ueno: methodology, investigation. Ayumi Takahashi: methodology, investigation. Noriko Yamauchi: investigation, writing—review and editing. Shohei Tada: writing—review and editing. Yoshio Kobayashi: conceptualization, supervision, writing—review and editing.

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Correspondence to Yoshio Kobayashi.

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Hosoya, T., Sato, S., Ueno, Y. et al. Electrolytic synthesis of metallic aluminum nanoparticles in aqueous solution. J Nanopart Res 25, 164 (2023). https://doi.org/10.1007/s11051-023-05814-2

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