Abstract
In this work, a one-step hydrothermal method is used to synthesize Ni-doped Mn-based organic framework material (Ni-doped Mn-MOF) on NF with 1,4,5,8-naphthalenetetracarboxylic acid (NTC) as ligand. Ni doping results in a more unique structure combining nanoblocks and nanosheets, which facilitates the contact between active sites and electrolyte ions and enhances electrochemical performance. Acting as the electrode material of supercapacitors, Ni-doped Mn-MOF shows a specific capacity of 779.6 C g−1 and a specific capacitance of 1676.6 F g−1 at 1 A g−1. Besides, the retention rate reaches as high as 75.9% after 10,000 cycles at 10 A g−1. Meanwhile, the as-prepared Ni-doped Mn-MOF//AC device shows a high specific capacitance of 361 C g−1 (225.6 F g−1) at 8 A g−1. By the way, the device exhibits an energy density of 74.75 Wh kg−1 at a power density of 7985.16 W kg−1 with 70.6% specific capacitance retention after 10,000 consecutive charge–discharge cycles at 10 A g−1. The ease of composite manufacturing demonstrates that Ni-doped Mn-MOF has potential applications as electrode materials for supercapacitor.
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References
Borenstein A, Hanna O, Attias R, Luski S, Brousse T, Aurbach D (2017) Carbon-based composite materials for supercapacitor electrodes: a review. J Mater Chem A 5(25):12653–12672. https://doi.org/10.1039/c7ta00863e
Chavan HS, Hou B, Ahmed ATA, Jo Y, Cho S, Kim J, Kim H (2018) Nanoflake NiMoO4 based smart supercapacitor for intelligent power balance monitoring. Sol Energy Mater Sol Cells 185:166–173. https://doi.org/10.1016/j.solmat.2018.05.030
Chen C, Wu M, Tao K, Zhou J, Li Y, Han X, Han L (2018) Formation of bimetallic metal-organic framework nanosheets and their derived porous nickel-cobalt sulfides for supercapacitors. Dalton Trans 47(16):5639–5645. https://doi.org/10.1039/c8dt00464a
Chen H, Huo Y, Cai K, Teng Y (2021) Controllable preparation and capacitance performance of bimetal Co/Ni-MOF. Synth Met 276:116761. https://doi.org/10.1016/j.synthmet.2021.116761
Dam DT, Wang X, Lee JM (2013) Mesoporous ITO/NiO with a core/shell structure for supercapacitors. Nano Energy 2(6):1303–1313. https://doi.org/10.1016/j.nanoen.2013.06.011
Gao F, Tang X, Yi H, Zhao S, Wang J, Gu T (2019) Improvement of activity, selectivity and H2O&SO2-tolerance of micro-mesoporous CrMn2O4 spinel catalyst for low-temperature NH3-SCR of NOx. Appl Surf Sci 466:411–424. https://doi.org/10.1016/j.apsusc.2018.09.227
Gonçalves JM, Martins PR, Araki K, Angnes L (2021) Recent progress in water splitting and hybrid supercapacitors based on nickel-vanadium layered double hydroxides. J Energy Chem 57:496–515. https://doi.org/10.1016/j.jechem.2020.08.047
He Y, Pan X, Kuang L, Hu B, Zha Q, Chen X (2021). Hierarchical MnO2 nanosheets coated on MnCo2O4.5 nanoneedles as advanced electrode for high-efficient hybrid supercapacitor. J Nanopart Res 23:54. https://doi.org/10.1007/s11051-021-05161-0
Jiao Y, Pei J, Chen D, Yan C, Hu Y, Zhang Q, Chen G (2017) Mixed-metallic MOF based electrode materials for high performance hybrid supercapacitors. J Mater Chem A 5(2017):1094–1102. https://doi.org/10.1039/c6ta09805c
Jiao L, Wang Y, Jiang HL, Xu Q (2018) Metal-organic frameworks as platforms for catalytic applications. Adv Mater 30(37):1703663. https://doi.org/10.1002/adma.201703663
Kazemi SH, Hosseinzadeh B, Kazemi H, Kiani MA, Hajati S (2018) Facile synthesis of mixed metal-organic frameworks: electrode materials for supercapacitors with excellent areal capacitance and operational stability. ACS Appl Mater Interfaces 10(27):23063–23073. https://doi.org/10.1021/acsami.8b04502
Kohei M, Siya H, Mitsumasa I, Wei P (2013) Enhanced conductivity and gating effect of p-type Li-doped NiO nanowires. Nanoscale 6:688–692. https://doi.org/10.1039/c3nr04953a
Kumar R, Soam A, Hossain R, Mansuri I, Sahajwalla V (2020) Carbon coated iron oxide (CC-IO) as high performance electrode material for supercapacitor applications. J Energy Storage 32:101737. https://doi.org/10.1016/j.est.2020.101737
Lakra R, Kumar R, Sahoo PK, Thatoi D, Soam A (2021) A mini-review: graphene based composites for supercapacitor application. Inorg Chem Commun 133:108929. https://doi.org/10.1016/j.inoche.2021.108929
Li Y, Henzie J, Park T, Wang J, Young C, Xie H, Na J (2020a) Fabrication of flexible microsupercapacitors with binder-free ZIF-8 derived carbon films via electrophoretic deposition. Bull Chem Soc Jpn 93(1):176–181. https://doi.org/10.1246/bcsj.20190298
Li Q, Guo H, Xue R, Wang M, Xu M, Yang W, Yang W (2020b) Self-assembled Mo doped Ni-MOF nanosheets based electrode material for high performance battery-supercapacitor hybrid device. Int J Hydrogen Energy 45(41):20820–20831. https://doi.org/10.1016/j.ijhydene.2020.05.143
Liu Y, Wang Y, Wang H, Zhao P, Hou H, Guo L (2019) Acetylene black enhancing the electrochemical performance of NiCo-MOF nanosheets for supercapacitor electrodes. Appl Surf Sci 492:455–463. https://doi.org/10.1016/j.apsusc.2019.06.238
Liu Y, Wang Y, Chen Y, Wang C, Guo L (2020) NiCo-MOF nanosheets wrapping polypyrrole nanotubes for high-performance supercapacitors. Appl Surf Sci 507:145089. https://doi.org/10.1016/j.apsusc.2019.145089
Liu R, Zhou A, Zhang X, Mu J, Che H, Wang Y, Kou Z (2021) Fundamentals, advances and challenges of transition metal compounds-based supercapacitors. Chem Eng J 412:128611. https://doi.org/10.1016/j.cej.2021.128611
Ma K, Liu X, Cheng Q, Saha P, Jiang H, Li C (2017) Flexible textile electrode with high areal capacity from hierarchical V2O5 nanosheet arrays. J Power Sources 357:71–76. https://doi.org/10.1016/j.jpowsour.2017.04.105
Ramachandran R, Lan Y, Xu Z, Wang F (2020) Construction of NiCo-layered double hydroxide microspheres from Ni-MOFs for high-performance asymmetric supercapacitors. ACS Appl Energy Mater 3(7):6633–6643. https://doi.org/10.1021/acsaem.0c00790
Raza N, Kumar T, Singh V, Kim KH (2021) Recent advances in bimetallic metal-organic framework as a potential candidate for supercapacitor electrode material. Coord Chem Rev 430:213660. https://doi.org/10.1016/j.ccr.2020.213660
Salunkhe RR, Tang J, Kamachi Y, Nakato T, Kim JH, Yamauchi Y (2015) Asymmetric supercapacitors using 3D nanoporous carbon and cobalt oxide electrodes synthesized from a single metal-organic framework. ACS Nano 9(6):6288–6296. https://doi.org/10.1021/acsnano.5b01790
Seo Y, Shinde PA, Park S, Chan Jun S (2020) Self-assembled bimetallic cobalt–manganese metal–organic framework as a highly efficient, robust electrode for asymmetric supercapacitors. Electrochim Acta 335:135327. https://doi.org/10.1016/j.electacta.2019.135327
Shi Y, Chu Q, Xiong W, Gao J, Huang L, Zhang Y, Ding Y (2021) A new type bimetallic NiMn-MOF-74 as an efficient low-temperatures catalyst for selective catalytic reduction of NO by CO. Chem Eng Process 159:108232. https://doi.org/10.1016/j.cep.2020.108232
Soam A, Kumar R, Thatoi D, Singh M (2020) Electrochemical performance and working voltage optimization of nickel ferrite/graphene composite based supercapacitor. J Inorg Organomet Polym Mater 30:3325–3331. https://doi.org/10.1007/s10904-020-01540-7
Strauss I, Mundstock A, Hinrichs D, Himstedt R, Knebel A, Reinhardt C, Caro J (2018) The interaction of guest molecules with Co-MOF-74: a Vis/NIR and Raman approach. Angew Chem Int Ed Engl 57(25):7434–7439. https://doi.org/10.1002/anie.201801966
Sun X, Liu X, Wang J, Jiang X, Liu R, Li A, Li W (2020) Nanobundles structural Co-HKUST on the foamed nickel with a high supercapacitor performance. SN Appl Sci 2(3):414. https://doi.org/10.1007/s42452-020-2205-6
Wang T, Zhang S, Yan X, Liu M, Wang L, Bell J, Wang H (2017a) 2-Methylimidazole-derived Ni-Co layered double hydroxide nanosheets as high rate capability and high energy density storage material in hybrid supercapacitors. ACS Appl Mater Interfaces 9(18):15510–15524. https://doi.org/10.1021/acsami.7b02987
Wang X, Liu X, Rong H, Song Y, Wen H, Liu Q (2017b) Layered manganese-based metal–organic framework as a high capacity electrode material for supercapacitors. RSC Adv 7(47):29611–29617. https://doi.org/10.1039/c7ra04374k
Wang J, Zhong Q, Xiong Y, Cheng D, Zeng Y, Bu Y (2019a) Fabrication of 3D Co-doped Ni-based MOF hierarchical micro-flowers as a high-performance electrode material for supercapacitors. Appl Surf Sci 483:1158–1165
Wang J, Zhong Q, Zeng Y, Cheng D, Xiong Y, Bu Y (2019b) Rational construction of triangle-like nickel-cobalt bimetallic metal-organic framework nanosheets arrays as battery-type electrodes for hybrid supercapacitors. J Colloid Interface Sci 555:42–52. https://doi.org/10.1016/j.jcis.2019.07.063
Wang X, Yang N, Li Q, He F, Yang Y, Wu B, Xiong S (2019c) Solvothermal synthesis of flower-string-like NiCo-MOF/MWCNT composites as a high-performance supercapacitor electrode material. J Solid State Chem 277:575–586. https://doi.org/10.1016/j.jssc.2019.07.019
Wang Y, Nie S, Liu Y, Yan W, Lin S, Cheng G, Lou J (2019d) Room-temperature fabrication of a nickel-functionalized copper metal(-)organic framework (Ni@Cu-MOF) as a new pseudocapacitive material for asymmetric supercapacitors. Polymers 11(5):821. https://doi.org/10.3390/polym11050821
Wang R, Li X, Nie Z, Zhao Y, Wang H (2021) Metal/metal oxide nanoparticles-composited porous carbon for high-performance supercapacitors. J Energy Storage 38:102479. https://doi.org/10.1016/j.est.2021.102479
Xu C, Xu B, Gu Y, Xiong Z, Sun J, Zhao X (2013) Graphene-based electrodes for electrochemical energy storage. Energy Environ Sci 6(5):1388–1414. https://doi.org/10.1039/c3ee23870a
Yang Q, Xu Q, Jiang HL (2017) Metal-organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis. Chem Soc Rev 46(15):4774–4808. https://doi.org/10.1039/c6cs00724d
Yang C, Li X, Yu L, Liu X, Yang J, Wei M (2020) A new promising Ni-MOF superstructure for high-performance supercapacitors. Chem Commun (camb) 56(12):1803–1806. https://doi.org/10.1039/c9cc09302h
Yu P, Zhang Z, Zheng L, Teng F, Hu L, Fang X (2016) A novel sustainable flour derived hierarchical nitrogen-doped porous carbon/polyaniline electrode for advanced asymmetric supercapacitors. Adv Energy Mater 6(20):1601111. https://doi.org/10.1002/aenm.201601111
Yuan B, Wang X, Zhou X, Xiao J, Li Z (2019) Novel room-temperature synthesis of MIL-100(Fe) and its excellent adsorption performances for separation of light hydrocarbons. Chem Eng J 355:679–686. https://doi.org/10.1016/j.cej.2018.08.201
Zhang R, Pang H (2021) Application of graphene-metal/conductive polymer based composites in supercapacitors. J Energy Storage 33:102037. https://doi.org/10.1016/j.est.2020.102037
Zhang J, Cai G, Zhou D, Tang H, Wang X, Gu C, Tu J (2014) Co-doped NiO nanoflake array films with enhanced electrochromic properties. J Mater Chem C 2(34):7013–7021. https://doi.org/10.1039/c4tc01033g
Zhang S, Yin B, Wang Z, Peter F (2016) Super long-life all solid-state asymmetric supercapacitor based on NiO nanosheets and α-Fe2O3 nanorods. Chem Eng J 306:193–203. https://doi.org/10.1016/j.cej.2016.07.057
Zhang Z, Zhu Q, Chen X, Wu Z, He Y, Lv Y, Zou Y (2019) Ni@C composites derived from Ni-based metal organic frameworks with a lightweight, ultrathin, broadband and highly efficient microwave absorbing properties. Appl Phys Express 12(1):011001. https://doi.org/10.7567/1882-0786/aaeedc
Zhang X, Wang J, Ji X, Sui Y, Wei F, Qi J, Zhuang D (2020a) Flake-like nickel/cobalt metal-organic framework as high-performance electrodes for supercapacitors. J Mater Sci-Mater El 31(19):16260–16268. https://doi.org/10.1007/s10854-020-04174-0
Zhang X, Wang J, Ji X, Sui Y, Wei F, Qi J, He Y (2020b) Nickel/cobalt bimetallic metal-organic frameworks ultrathin nanosheets with enhanced performance for supercapacitors. J Alloys Compd 825:154069. https://doi.org/10.1016/j.jallcom.2020.154069
Zhang X, Yang S, Lu W, Lei D, Tian Y, Guo M, Zhao Y (2021a) MXenes induced formation of Ni-MOF microbelts for high-performance supercapacitors. J Colloid Interface Sci 592:95–102. https://doi.org/10.1016/j.jcis.2021.02.042
Zhang X, Qu N, Yang S, Lei D, Liu A, Zhou Q (2021b) Cobalt induced growth of hollow MOF spheres for high performance supercapacitors. Mater Chem Front 5(1):482–491. https://doi.org/10.1039/d0qm00597e
Zhao C, Zheng W (2015) A review for aqueous electrochemical supercapacitors. Front Energy Res 3:23. https://doi.org/10.3389/fenrg.2015.00023
Zhao X, Li M, Dong H, Liu Y, Hu H, Cai Y, Zheng M (2017) Interconnected 3D network of graphene-oxide nanosheets decorated with carbon dots for high-performance supercapacitors. Chemsuschem 10(12):2626–2634. https://doi.org/10.1002/cssc.201700474
Funding
This work was supported by the National Natural Science Foundation of China (No. 22004002), the University Natural Science Research Project of Anhui Province (No. KJ2018A0107), and the Open Fund of Anhui Laboratory of Functional Coordinated Complexes for Materials Chemistry and Application (LFCCMCA-08, LFCCMCA-10).
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Liu, X., Zhang, X., Liu, R. et al. A Ni-doped Mn-MOF decorated on Ni-foam as an electrode for high-performance supercapacitors. J Nanopart Res 24, 23 (2022). https://doi.org/10.1007/s11051-022-05411-9
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DOI: https://doi.org/10.1007/s11051-022-05411-9