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A versatile and facile strategy for full-color emitting carbonized polymer dots

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Abstract

As a subclass of carbon dots, carbonized polymer dots (CPDs) are attracting more and more attention. But the facile preparation of full-color emitting CPDs has been rarely reported yet. Herein, we present a versatile and facile strategy for the preparation of photoluminescence (PL) CPDs, whose aqueous solutions can emit three primary colors under a single ultraviolet-light excitation. The difference in the PL emission of these CPDs is ascribed to the differences in nitrogen and oxygen contents. It is believed that the facile preparation approach would provide a promising alternative route for preparing full-color emitting CPDs.

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References

  • Barman MK, Patra A (2018) Current status and prospects on chemical structure driven photoluminescence behaviour of carbon dots. J Photochem Photobiol, C 37:1–22

    Article  CAS  Google Scholar 

  • Cao X, Ma J, Lin Y, Yao B, Li F, Weng W et al (2015) A facile microwave-assisted fabrication of fluorescent carbon nitride quantum dots and their application in the detection of mercury ions. Spectrochim Acta, Part A 151:875–880

    Article  CAS  Google Scholar 

  • Chen Y, Zhang Y, Lyu T, Wang Y, Yang X, Wu X (2019) A facile strategy for the synthesis of water-soluble fluorescent nonconjugated polymer dots and their application in tetracycline detection. J Mat Chem C 7:9241–9247

    Article  CAS  Google Scholar 

  • Ding H, Yu S-B, Wei J-S, Xiong H-M (2016) Full-color light-emitting carbon dots with a surface-state-controlled luminescence mechanism. ACS Nano 10:484–491

    Article  CAS  Google Scholar 

  • Feng T, Tao S, Yue D, Zeng Q, Chen W, Yang B (2020) Recent advances in energy conversion applications of carbon sots: from optoelectronic devices to electrocatalysis. Small 16:2001295

    Article  CAS  Google Scholar 

  • Jiang K, Sun S, Zhang L, Lu Y, Wu A, Cai C et al (2015) Red, green, and blue luminescence by carbon dots: full-color emission tuning and multicolor cellular imaging. Angew Chem Int Ed 54:5360–5363

    Article  CAS  Google Scholar 

  • Jian X, Yang H-M, Li J-G, Zhang E-H, Cao L-L, Liang Z-H (2017) Flexible all-solid-state high-performance supercapacitor based on electrochemically synthesized carbon quantum dots/polypyrrole composite electrode. Electrochim Acta 228:483–493

    Article  CAS  Google Scholar 

  • Hu S, Trinchi A, Atkin P, Cole I (2015) Tunable photoluminescence across the entire visible spectrum from carbon dots excited by white light. Angew Chem Int Ed 54:2970–2974

    Article  CAS  Google Scholar 

  • Gogoi S, Kumar M, Mandal BB, Karak N (2015) High performance luminescent thermosetting waterborne hyperbranched polyurethane/carbon quantum dot nanocomposite with in vitro cytocompatibility. Sci Technol 118:39–46

    CAS  Google Scholar 

  • Li X, Rui M, Song J, Shen Z, Zeng H (2015) Carbon and graphene quantum dots for optoelectronic and energy devices: a review. Adv Funct Mater 25:4929–4947

    Article  CAS  Google Scholar 

  • Lim SY, Shen W, Gao Z (2015) Carbon quantum dots and their applications. Chem Soc Rev 44:362–381

    Article  CAS  Google Scholar 

  • Liu J, Li D, Zhang K, Yang M, Sun H, Yang B (2018) One-step hydrothermal synthesis of nitrogen-doped conjugated carbonized polymer dots with 31% efficient red emission for in vivo imaging. Small 14:1703919

    Article  Google Scholar 

  • Liu C, Jin Y, Wang R, Han T, Liu X, Wang B, et al (2020) Indole carbonized polymer dots boost full-color emission by regulating surface state. iScience 23:101546

  • Liu J, Li R, Yang B (2020a) Carbon dots: a new type of carbon-based nanomaterial with wide applications. ACS Cent Sci

  • Liu J, Geng Y, Li D, Yao H, Huo Z, Li Y et al (2020b) Deep red emissive carbonized polymer dots with unprecedented narrow full width at half maximum. Adv Mater 32:1906641

    Article  CAS  Google Scholar 

  • Ma Z, Zhang Y-L, Wang L, Ming H, Li H, Zhang X et al (2013) Bioinspired photoelectric conversion system based on carbon-quantum-dot-doped dye–semiconductor complex. ACS Appl Mater Interfaces 5:5080–5084

    Article  CAS  Google Scholar 

  • Ragazzon G, Cadranel A, Ushakova EV, Wang Y, Guldi DM, Rogach AL et al (2021) Optical Processes in Carbon Nanocolloids. Chem 7:606–628

    Article  CAS  Google Scholar 

  • Shamsipur M, Barati A, Karami S (2017) Long-wavelength, multicolor, and white-light emitting carbon-based dots: achievements made, challenges remaining, and applications. Carbon 124:429–472

    Article  CAS  Google Scholar 

  • Shi Y, Xu H, Yuan T, Meng T, Wu H, Chang J, et al (2021) Carbon dots: an innovative luminescent nanomaterial. Aggregate 7: https://doi.org/10.1002/agt2.108

  • Sun J, Yu J, Jiang Z, Zhao Z, Xia Y (2020) Fluorescent carbonized polymer dots prepared from sodium alginate based on the CEE effect. ACS Omega 5:27514–27521

    Article  CAS  Google Scholar 

  • Tao S, Feng T, Zheng C, Zhu S, Yang B (2019) Carbonized polymer dots: a brand new perspective to recognize luminescent carbon-based nanomaterials. J Phys Chem Lett 10:5182–5188

    Article  CAS  Google Scholar 

  • Tian R, Hu S, Wu L, Chang Q, Yang J, Liu J (2014) Tailoring surface groups of carbon quantum dots to improve photoluminescence behaviors. Appl Surf Sci 301:156–160

    Article  CAS  Google Scholar 

  • Wang C, Jiang K, Wu Q, Wu J, Zhang C (2016) Green synthesis of red-emitting carbon nanodots as a novel “Turn-on” nanothermometer in living cells. Chem Eur J 22:14475–14479

    Article  CAS  Google Scholar 

  • Weng C-I, Chang H-T, Lin C-H, Shen Y-W, Unnikrishnan B, Li Y-J et al (2015) One-step synthesis of biofunctional carbon quantum dots for bacterial labeling. Biosens Bioelectron 68:1–6

    Article  CAS  Google Scholar 

  • Wu M, Wang Y, Wu W, Hu C, Wang X, Zheng J et al (2014) Preparation of functionalized water-soluble photoluminescent carbon quantum dots from petroleum coke. Carbon 78:480–489

    Article  CAS  Google Scholar 

  • Xia C, Zhu S, Feng T, Yang M, Yang B (2019) Evolution and synthesis of carbon dots: from carbon dots to carbonized polymer dots. Advanced Science 6:1901316

    Article  CAS  Google Scholar 

  • Xia C, Zhu S, Zhang S-T, Zeng Q, Tao S, Tian X et al (2020) Carbonized polymer dots with tunable room-temperature phosphorescence lifetime and wavelength. ACS Appl Mater Interfaces 12:38593–38601

    Article  CAS  Google Scholar 

  • Yuan F, Wang Z, Li X, Li Y, Tan Za, Fan L, et al (2017) Bright multicolor bandgap fluorescent carbon quantum dots for electroluminescent light-emitting diodes. Adv Mater 29:1604436

  • Zhu Z, Zhai Y, Li Z, Zhu P, Mao S, Zhu C et al (2019) Red carbon dots: optical property regulations and applications. Mater Today 30:52–79

    Article  CAS  Google Scholar 

  • Zhao X, Tang Q, Zhu S, Bu W, Yang M, Liu X et al (2019) Controllable acidophilic dual-emission fluorescent carbonized polymer dots for selective imaging of bacteria. Nanoscale 11:9526–9532

    Article  CAS  Google Scholar 

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Correspondence to Hongwei Zhang.

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Wang, X., Yang, H., Zuo, D. et al. A versatile and facile strategy for full-color emitting carbonized polymer dots. J Nanopart Res 23, 250 (2021). https://doi.org/10.1007/s11051-021-05367-2

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