Abstract
Preparing ordered array of nanoparticles through interface assembly has been an effective way in synthesis of SERS substrates. However, transferring the interfacial film to solid substrates without disturbance has been difficult for a long time. Herein, we developed a novel strategy for transferring the interfacial film comprising Au nanoparticles (NPs) to arbitrary solid substrates without disturbance. After a continuous sheeny Au NP film was formed at the hexane/water interface, an in situ quadratic convective arrangement was performed with the drawdown of interface film by controlling the dropping speed of a Teflon funnel, depositing ordered Au NP films onto solid substrates. Both the SERS mapping results and low values of relative standard deviations (RSD) of Raman intensity obtained from crystal violet (CV) molecules show that the as-prepared Au NPs arrays are of sensitive and uniform SERS properties. This improved technique is superior to existing methods in self-assembly since there is no disturbance during the transferring, which can be applied to general colloidal crystals to fabricate large-scale monolayer films.
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References
Bigioni TP, Lin XM, Nguyen TT, Corwin EI, Witten TA, Jaeger HM (2006) Kinetically driven self assembly of highly ordered nanoparticle monolayers. Nat Mater 5:265–270. https://doi.org/10.1038/nmat1611
Dai Z, Li Y, Duan G, Jia L, Cai W (2012) Phase diagram, design of monolayer binary colloidal crystals, and their fabrication based on ethanol-assisted self-assembly at the air/water interface. ACS Nano 6:6706–6716. https://doi.org/10.1021/nn3013178
Dai Z, Dai H, Zhou Y, Liu D, Duan G, Cai W, Li Y (2015) Monodispersed Nb2O5Microspheres: facile synthesis, air/water interfacial self-assembly, Nb2O5-based composite films, and their selective NO2Sensing. Adv Mater Interfaces 2:1500167. https://doi.org/10.1002/admi.201500167
Deegan RD, Bakajin O, Dupont TF, Huber G, Nagel SR, Witten TA (1997) Capillary flow as the cause of ring stains from dried liquid drops. Nature 389:827–829. https://doi.org/10.1038/39827
Guo Q, Xu M, Yuan Y, Gu R, Yao J (2016) Self-assembled large-scale monolayer of Au nanoparticles at the air/water interface used as a SERS substrate. Langmuir 32:4530–4537. https://doi.org/10.1021/acs.langmuir.5b04393
Hu L, Chen M, Fang X, Wu L (2012) Oil-water interfacial self-assembly: a novel strategy for nanofilm and nanodevice fabrication. Chem Soc Rev 41:1350–1362. https://doi.org/10.1039/c1cs15189d
Hutter E, Fendler JH (2004) Exploitation of localized surface plasmon resonance. Adv Mater 16:1685–1706. https://doi.org/10.1002/adma.200400271
Im H, Bantz KC, Lindquist NC, Haynes CL, Oh SH (2010) Vertically oriented sub-10-nm plasmonic nanogap arrays. Nano Lett 10:2231–2236. https://doi.org/10.1021/nl1012085
Kim MH, Im SH, Park OO (2005) Rapid fabrication of two- and three-dimensional colloidal crystal films via confined convective assembly. Adv Funct Mater 15:1329–1335. https://doi.org/10.1002/adfm.200400602
Le F et al (2008) Metallic nanoparticle arrays: a common substrate for both surface-enhanced Raman scattering and surface-enhanced infrared absorption. ACS Nano 2:707–718. https://doi.org/10.1021/nn800047e
Li JF, Tian XD, Li SB, Anema JR, Yang ZL, Ding Y, Wu YF, Zeng YM, Chen QZ, Ren B, Wang ZL, Tian ZQ (2013) Surface analysis using shell-isolated nanoparticle-enhanced Raman spectroscopy. Nat Protoc 8:52–65. https://doi.org/10.1038/nprot.2012.141
Liu C, Li YJ, Wang MH, He Y, Yeung ES (2009) Rapid fabrication of large-area nanoparticle monolayer films via water-induced interfacial assembly. Nanotechnology 20:065604. https://doi.org/10.1088/0957-4484/20/6/065604
Liu D, Li C, Zhou F, Zhang T, Zhang H, Li X, Duan G, Cai W, Li Y (2015) Rapid synthesis of monodisperse Au nanospheres through a laser irradiation-induced shape conversion, self-assembly and their electromagnetic coupling SERS enhancement. Sci Rep 5:7686. https://doi.org/10.1038/srep07686
Liu D, Li C, Zhou F, Zhang T, Liu G, Cai W, Li Y (2017a) Capillary gradient-induced self-assembly of periodic Au spherical nanoparticle arrays on an ultralarge scale via a bisolvent system at air/water interface. Adv Mater Interfaces 4:1600976. https://doi.org/10.1002/admi.201600976
Liu HL, Cao J, Hanif S, Yuan C, Pang J, Levicky R, Xia XH, Wang K (2017b) Size-controllable gold nanopores with high SERS Activity. Anal Chem 89:10407–10413. https://doi.org/10.1021/acs.analchem.7b02410
Malaquin L, Kraus T, Schmid H, Delamarche E, Wolf H (2007) Controlled particle placement through convective and capillary assembly. Langmuir 23:11513–11521. https://doi.org/10.1021/la700852c
Mao M, Zhou B, Tang X, Chen C, Ge M, Li P, Huang X, Yang L, Liu J (2018) Natural deposition strategy for interfacial, self-assembled, large-scale, densely packed, monolayer film with ligand-exchanged gold nanorods for in situ surface-enhanced Raman scattering drug detection. Chemistry 24:4094–4102. https://doi.org/10.1002/chem.201705700
Matricardi C, Hanske C, Garcia-Pomar JL, Langer J, Mihi A, Liz-Marzan LM (2018) Gold nanoparticle plasmonic superlattices as surface-enhanced Raman spectroscopy substrates. ACS Nano 12:8531–8539. https://doi.org/10.1021/acsnano.8b04073
Miccichè C, Arrabito G, Amato F, Buscarino G, Agnello S, Pignataro B (2018) Inkjet printing Ag nanoparticles for SERS hot spots. Anal Methods-Uk 10:3215–3223. https://doi.org/10.1039/c8ay00624e
Park YK, Park S (2008) Directing close-packing of midnanosized gold nanoparticles at a water/hexane interface. Chem Mater 20:2388–2393. https://doi.org/10.1021/cm703498y
Park YK, Yoo SH, Park S (2007) Assembly of highly ordered nanoparticle monolayers at a water/hexane interface. Langmuir 23:10505–10510. https://doi.org/10.1021/la701445a
Pienpinijtham P, Han XX, Ekgasit S, Ozaki Y (2012) An ionic surfactant-mediated Langmuir-Blodgett method to construct gold nanoparticle films for surface-enhanced Raman scattering. Phys Chem Chem Phys 14:10132–10139. https://doi.org/10.1039/c2cp41419h
Pieranski P (1980) Two-dimensional interfacial colloidal crystals. Phys Rev Lett 45:569–572. https://doi.org/10.1103/PhysRevLett.45.569
Que RH, Shao MW, Zhuo SJ, Wen CY, Wang SD, Lee ST (2011) Highly reproducible surface-enhanced Raman scattering on a capillarity-assisted gold nanoparticle assembly. Adv Funct Mater 21:3337–3343. https://doi.org/10.1002/adfm.201100641
Reincke F, Kegel WK, Zhang H, Nolte M, Wang DY, Vanmaekelbergh D, Mohwald H (2006) Understanding the self-assembly of charged nanoparticles at the water/oil interface. Phys Chem Chem Phys 8:3828–3835. https://doi.org/10.1039/b604535a
Sharma V, Krishnan V (2018) Fabrication of highly sensitive biomimetic SERS substrates for detection of herbicides in trace concentration. Sensors Actuators B Chem 262:710–719. https://doi.org/10.1016/j.snb.2018.01.230
Sharma V, Balaji R, Walia R, Krishnan V (2017a) Au nanoparticle aggregates assembled on 3D mirror-like configuration using Canna generalis leaves for SERS applications. Colloid Interf Sci Commun 18:9–12. https://doi.org/10.1016/j.colcom.2017.04.002
Sharma V, Kumar S, Jaiswal A, Krishnan V (2017b) Gold deposited plant leaves for SERS: role of surface morphology, wettability and deposition technique in determining the enhancement factor and sensitivity of detection. Chem Select 2:165–174. https://doi.org/10.1002/slct.201601451
Shin Y, Song J, Kim D, Kang T (2015) Facile preparation of ultrasmall void metallic nanogap from self-assembled gold-silica core-shell nanoparticles monolayer via kinetic control. Adv Mater 27:4344–4350. https://doi.org/10.1002/adma.201501163
Wang H, Levin CS, Halas NJ (2005) Nanosphere arrays with controlled sub-10-nm gaps as surface-enhanced Raman spectroscopy substrates. J Am Chem Soc 127:14992–14993. https://doi.org/10.1021/ja055633y
Wang HH, Liu CY, Wu SB, Liu NW, Peng CY, Chan TH, Hsu CF, Wang JK, Wang YL (2006) Highly Raman-enhancing substrates based on silver nanoparticle arrays with tunable sub-10nm gaps. Adv Mater 18:491–495. https://doi.org/10.1002/adma.200501875
Wei H, Leng W, Song J, Willner MR, Marr LC, Zhou W, Vikesland PJ (2018) Improved quantitative SERS enabled by surface plasmon enhanced elastic light scattering. Anal Chem 90:3227–3237. https://doi.org/10.1021/acs.analchem.7b04667
Xiong S, Dunphy DR, Wilkinson DC, Jiang Z, Strzalka J, Wang J, Su Y, de Pablo JJ, Brinker CJ (2013) Revealing the interfacial self-assembly pathway of large-scale, highly-ordered, nanoparticle/polymer monolayer arrays at an air/water interface. Nano Lett 13:1041–1046. https://doi.org/10.1021/nl304253y
Xu L, Han G, Hu J, He Y, Pan J, Li Y, Xiang J (2009) Hydrophobic coating- and surface active solvent-mediated self-assembly of charged gold and silver nanoparticles at water-air and water-oil interfaces. Phys Chem Chem Phys 11:6490–6497. https://doi.org/10.1039/b820970g
Yamazoe S, Naya M, Shiota M, Morikawa T, Kubo A, Tani T, Hishiki T, Horiuchi T, Suematsu M, Kajimura M (2014) Large-area surface-enhanced Raman spectroscopy imaging of brain ischemia by gold nanoparticles grown on random nanoarrays of transparent boehmite. ACS Nano 8:5622–5632. https://doi.org/10.1021/nn4065692
Yang G, Hu L, Keiper TD, Xiong P, Hallinan DT Jr (2016) Gold nanoparticle monolayers with tunable optical and electrical properties. Langmuir 32:4022–4033. https://doi.org/10.1021/acs.langmuir.6b00347
Zhang YR, Xu YZ, Xia Y, Huang W, Liu FA, Yang YC, Li ZL (2011) A novel strategy to assemble colloidal gold nanoparticles at the water-air interface by the vapor of formic acid. J Colloid Interface Sci 359:536–541. https://doi.org/10.1016/j.jcis.2011.04.012
Zhou B, Mao M, Cao X, Ge M, Tang X, Li S, Lin D, Yang L, Liu J (2018) Amphiphilic functionalized acupuncture needle as SERS sensor for in situ multiphase detection. Anal Chem 90:3826–3832. https://doi.org/10.1021/acs.analchem.7b04348
Funding
This work was supported by the National Special Fund for the Development of Major Research Equipment and Instruments (2011YQ03013403), National Natural Science Foundation of China (61371057 and 11574195), and Innovation Action Plan of International Academic Cooperation and Exchange Program of Shanghai Municipal Science and Technology Commission (16520720800).
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Wu, J., Yang, X. & Fang, J. Convective combined interfacial assembly of surfactantless ordered Au nanoparticles and SERS performance. J Nanopart Res 21, 78 (2019). https://doi.org/10.1007/s11051-019-4520-7
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DOI: https://doi.org/10.1007/s11051-019-4520-7