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Thermal and magnetic behavior of BiFeO3 nanoparticles prepared by glycine-nitrate combustion

  • N. A. LomanovaEmail author
  • M. V. Tomkovich
  • V. V. Sokolov
  • V. L. Ugolkov
  • V. V. Panchuk
  • V. G. Semenov
  • I. V. Pleshakov
  • M. P. Volkov
  • V. V. Gusarov
Research Paper

Abstract

The temperature behavior of bismuth orthoferrite nanoparticles obtained by the glycine-nitrate combustion method was studied by high-temperature X-ray diffractometry and complex thermal analysis. The region of stability of the material in a single-phase state was found. It was shown that the nanocrystalline BiFeO3 did not undergo decay in the temperature interval 550–780 °С. In this temperature interval, we have obtained the nanocrystalline material with average crystallite sizes 40–90 nm and average particle sizes 100–150 nm the sizes of which depend on temperature. The features of formation of BiFeO3 and the process of their sintering were studied. Results show that the crystallite growth slowed down after the amorphous phase disappeared. The sintering of nanopowder became more intense in the temperature interval 600–700 °С, but no noticeable increase in the crystallite sizes occurred. The magnetic behavior of obtained material was also discussed. It was found to be consistent with the concept of violation of the cycloidal magnetic order in bismuth orthoferrite.

Keywords

Bismuth orthoferrite Nanoparticles Nanocrystals Thermal properties Magnetic properties Glycine-nitrate combustion 

Notes

Funding information

This work was financially supported by the Russian Science Foundation (No. 16-13-10252).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no competing interests.

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  • N. A. Lomanova
    • 1
    Email author
  • M. V. Tomkovich
    • 1
  • V. V. Sokolov
    • 1
  • V. L. Ugolkov
    • 2
  • V. V. Panchuk
    • 3
  • V. G. Semenov
    • 3
  • I. V. Pleshakov
    • 1
  • M. P. Volkov
    • 1
  • V. V. Gusarov
    • 1
  1. 1.Ioffe InstituteSt. PetersburgRussian Federation
  2. 2.Grebenshchikov Institute of Silicate ChemistryRASSt. PetersburgRussian Federation
  3. 3.Saint Petersburg State UniversitySt. PetersburgRussian Federation

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