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3D porous NiMoO4 nanoflakes arrays for advanced supercapacitor electrodes

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Abstract

In recent years, supercapacitors have been considered as one of the auspicious energy storage devices. In this work, two different kinds of mixed metal oxide NiMoO4 nanoflakes arrays were directly grown on 3D Ni foam. The electrode exhibited high specific capacitance of 2004 F/g at the current density of 2 A/g in 6 M KOH electrolyte. Additionally, it also exhibited low equivalent series resistance of 0.62 Ω and excellent cycling stability (80% capacitance retention after 1000 cycles). With these extraordinary electrochemical properties, the electrode material can be considered as potential candidate for supercapacitor applications.

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References

  • Bao F, Wang X, Zhao X, Wang Y, Ji Y, Zhang H, Liu X (2014) Controlled growth of mesoporous ZnCo2O4 nanosheet arrays on Ni foam as high-rate electrodes for supercapacitors. RSC Adv 4:2393–2397

    Article  Google Scholar 

  • DaopingCai DW, Liu B, Wang Y, Liu Y, Wang L, Li H, Huang H, Li Q, Wang T (2013) Comparison of the electrochemical performance of NiMoO4 nanorods and hierarchical nanospheres for supercapacitor applications. ACS Appl Mater Interfaces 5:12905–12910

  • DaopingCai BL, Wang D, Liu Y, Wang L, Li H, Wang Y, Wang C, Li Q, Wang T (2014) Facile hydrothermal synthesis of hierarchical ultrathin mesoporous NiMoO4 nanosheets for high performance supercapacitors. Electrochim Acta 115:358–363

    Article  Google Scholar 

  • Deng M-J, Wang C-C, Ho P-J, Lin C-M, Chen J-M, Lu K-T (2014) Facile electrochemical synthesis of 3D nanoarchitectured CuO electrodes for high performance supercapacitors. J Mater Chem A 2:12857–12865

    Article  Google Scholar 

  • Fang Y, Luo B, Jia Y, Li X, Wang B, Song Q, Kang F, Zhi L (2012) Renewing functionalized graphene as electrodes for high-performance supercapacitors. Adv Mater 24:6348–6355

    Article  Google Scholar 

  • Guo D, Zhang P, Zhang H, Yu X, Zhu J, Li Q, Wang T (2013) NiMoO4 nanowires supported on Ni foam as novel advanced electrodes for supercapacitors. J Mater Chem A 1:9024–9027

    Article  Google Scholar 

  • Hao L, Luo B, Li X, Jin M, Fang Y, Tang Z, Jia Y, Liang M, Thomas A, Yang J, Zhi L (2012) Terephthalonitrile-derived nitrogen-rich networks for high performance supercapacitors. Energy Environ Sci 5:9747–9751

    Article  Google Scholar 

  • Li B, Peng G, Feng Y, Zhang G, Huang K, Xue H, Pang H (2017) Ultrathin nickel-cobalt phosphate 2D nanosheets for electrochemical energy storage under aqueous/solid-state electrolyte. Adv Funct Mater 27(12):1605784

    Article  Google Scholar 

  • Liang Y, Liu Q, Asiri AM, Sun X (2015) Enhanced electro-oxidation of urea using NiMoO4.xH2O nanosheet arrays on Ni foam as anode. Electrochim Acta 153:456–460

    Article  Google Scholar 

  • Liu P, Deng Y, Zhang Q, Hu Z, Xu Z, Liu Y, Yao M, Ai Z (2015) Facile synthesis and characterization of high-performance NiMoO4·xH2O nanorods electrode material for supercapacitors. Ionics 21:2797–2804

    Article  Google Scholar 

  • Liu H, Tian Y, Amal R, Wang D-W (2016) An integrated nanocarbon-cellulose membrane for solid-state supercapacitors. Sci Bull 61:368–377

    Article  Google Scholar 

  • Pang H, Zhang Y, Cheng T, Lai W-Y, Huang W (2015a) Uniform manganese hexacyanoferrate hydrate nanocubes featuring superior performance for low-cost supercapacitors and nonenzymatic electrochemical sensors. Nano 7:16012–16019

    Google Scholar 

  • Pang M, Long G, Jiang S, Ji Y, Han W, Wang B, Liu X, Xi Y (2015b) One pot low-temperature growth of hierarchical δ-MnO2 nanosheets on nickel foam for supercapacitor applications. Electrochim Acta 161:297–304

    Article  Google Scholar 

  • Pang H, Li X, Zhao Q, Xue H, Lai W-Y, Hu Z, Huang W (2017) One-pot synthesis of heterogeneous Co3O4-nanocube/Co(OH)2-nanosheet hybrids for high-performance flexible asymmetric all-solid-state supercapacitors. Nano Energy 35:138–145

    Article  Google Scholar 

  • Purushothaman KK, Cuba M, Muralidharan G (2012) Supercapacitor behavior of α-MnMoO4 nanorods on different electrolytes. Mater Res Bull 47:99–110

    Article  Google Scholar 

  • Qiu T, Luo B, Giersig M, Akinoglu EM, Hao L, Wang X, Shi L, Jin M, Zhi L (2014) Au@MnO2 core-shell nanomesh electrodes for transparent flexible supercapacitors. Small 10:4136–4141

    Google Scholar 

  • Vijayakumar S, Lee S-H, Ryu K-S (2015) Hierarchical CuCo2O4 nanobelts as a supercapacitor electrode with high areal and specific capacitance. Electrochim Acta 182:979–986

    Article  Google Scholar 

  • Wang J, Wang S, Huang Z, Yu Y (2014) High-performance NiCo2O4@Ni3S2 core/shell mesoporous nanothorn arrays on Ni foam for supercapacitors. Mater Chem A 2:17595–17601

    Article  Google Scholar 

  • Wang Z, Wei G, Kun D, Zhao X, Liu M, ShutaoWang, Zhou Y, An C, Zhang J (2017) Ni foam-supported carbon-sheathed NiMoO4 nanowires as integrated electrode for high-performance hybrid supercapacitors. ACS Sustain Chem Eng 5:5964–5971

    Article  Google Scholar 

  • Yan Y, Peng G, Zheng S, Zheng M, Pang H, Xue H (2016) Facile synthesis of an accordion-like Ni-MOF superstructure for high-performance flexible supercapacitors. J Mater Chem A 4:19078–19085

    Article  Google Scholar 

  • Yao M, Hu Z, Liu Y, Liu P (2016) A novel synthesis of size-controllable mesoporous NiMoO4nanospheres for supercapacitor applications. Ionics 22:701–709

    Article  Google Scholar 

  • Yuan C, Wu HB, Xie Y, Lou XWD (2014) Mixed transition-metal oxides: design, synthesis, and energy-related applications. Angew Chem Int Ed 53:1488–1504

    Article  Google Scholar 

  • Zhang C, Kuila T, Kim NH, Lee SH, Lee JH (2015) Facile preparation of flower-like NiCo2O4/three dimensional graphene foam hybrid for high performance supercapacitor electrodes. Carbon 89:328–339

    Article  Google Scholar 

  • Zhao Y, Teng F, Liu Z, Du Q, Xu J, Teng Y (2016) Electrochemical performances of asymmetric super capacitor fabricated by one-dimensional CoMoO4 nanostructure. Chem Phys Lett 664:23–28

    Article  Google Scholar 

  • Zhou C, Yang W, Zeng G, Lei Y, Li G, Xi X, Xiao D (2015) Three-dimensional NiMoO4 nanosheets supported on a carbon fibers@pre-treated Ni foam (CF@PNF) substrate as advanced electrodes for asymmetric supercapacitors. Chem Asian J 10:1745–1752

    Article  Google Scholar 

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Correspondence to Munesh Chandra Adhikary.

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Adhikary, M.C., Priyadarsini, M.H., Rath, S.K. et al. 3D porous NiMoO4 nanoflakes arrays for advanced supercapacitor electrodes. J Nanopart Res 19, 314 (2017). https://doi.org/10.1007/s11051-017-4008-2

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