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Synthesis and characterization of magnetic silica-supported Mn(II)-substituted polyoxophosphotungstate as catalyst in sulfoxidation reaction

Journal of Nanoparticle Research volume 18, Article number: 298 (2016) Cite this article

Abstract

Polyoxometalate-functionalized magnetic nanoparticles (Fe3O4@SiO2–MnPOW) were successfully synthesized via covalent anchoring of Mn(II)-substituted phosphotungstate on ammonium-modified Fe3O4@SiO2 nanoparticles. The complete characterization of nanoparticles has been carried out by scanning electron microscope, energy-dispersive X-ray, X-ray diffraction, Fourier transform infrared and elemental analysis. The resulting nanocomposites were efficient catalysts for the selective oxidation of sulfides with different green oxidants in good to excellent yields and also high selectivity. Leaching and recycling tests showed that the nanocatalyst can be reused several times without significant loss of efficiency.

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Acknowledgments

The authors are grateful to the University of Guilan and the Golpayegan University of Technology for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, University of Guilan, P.O. Box 41335–1914, Rasht, Iran

    Zeinab Moradi-Shoeili

  2. Department of Basic Sciences, Golpayegan University of Technology, P.O. Box 8771765651, Golpayegan, Iran

    Maryam Zare

  3. Department of Chemistry, Sharif University of Technology, Azadi Ave., P.O. Box 11155–3516, Tehran, Iran

    Mojtaba Bagherzadeh

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  1. Zeinab Moradi-Shoeili
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  2. Maryam Zare
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  3. Mojtaba Bagherzadeh
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Correspondence to Zeinab Moradi-Shoeili.

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Moradi-Shoeili, Z., Zare, M. & Bagherzadeh, M. Synthesis and characterization of magnetic silica-supported Mn(II)-substituted polyoxophosphotungstate as catalyst in sulfoxidation reaction. J Nanopart Res 18, 298 (2016). https://doi.org/10.1007/s11051-016-3609-5

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