Abstract
Mesoporous Ag/TiO2 heterojunction films (Ag-MTHF) with enhanced photocatalytic activity were synthesized by a three-step approach including an electrochemical anodization technique followed by successive ionic layer adsorption and reaction (SILAR) and solvothermal methods. The distribution of Ag nanoparticles on the inner structure of the mesoporous TiO2 film was confirmed by field emission scanning electron (FE-SEM) and transmission electron microscopes (TEM). The formation progress of the novel mesoporous Ag/TiO2 nanojunction film with Ag average diameter of 17 nm was illuminated. The formed nanojunction between Ag and TiO2 nanoparticles largely enhanced the photocatalytic degradation of methyl orangey (MO), and the corresponding mechanism was proposed.
Similar content being viewed by others
References
Ashkarran AA, Aghigh SM, kavianipour M, Farahani NJ (2011) Visible light photo-and bioactivity of Ag/TiO2 nanocomposite with various silver contents. Curr Appl Phys 11:1048–1055
Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38
Girginov C, Stefchev P, Vitanov P, Dikov H (2012) Silver doped TiO2 photocatalyst for methyl orange degradation. J Eng Sci Technol Rev 5:14–17
Hartmann P, Lee DK, Smarsly BM, Janek J (2010) Mesoporous TiO2: comparison of classical sol-gel and nanoparticle based photoelectrodes for the water splitting reaction. ACS Nano 4:3147–3154
Kim D, Lee K, Roy P, Birajdar BI, Spiecker E, Schmuki P (2009) Formation of a non-thickness-limited titanium dioxide mesosponge and its use in dye-sensitized solar cells. Angew Chem 121:9490–9493
Krins N, Faustini M, Louis B, Grosso D (2010) Thick and crack-free nanocrystalline mesoporous TiO2 films obtained by capillary coating from aqueous solutions. Chem Mater 22:6218–6220
Lee K, Kim D, Roy P, Paramasivam I, Birajdar BI, Spiecker E, Schmuki P (2010) Anodic formation of thick anatase TiO2 mesosponge layers for high-efficiency photocatalysis. J Am Chem Soc 132:1478–1479
Li D, Zhang Y, Zhang Y, Zhou X, Guo S (2013) Fabrication of bidirectionally doped β-Bi2O3/TiO2-NTs with enhanced photocatalysis under visible light irradiation. J Hazard Mater 258:42–49
Lin Y, Tung K, Tzeng Y, Chen J, Chang K (2012) Rapid atmospheric plasma spray coating preparation and photocatalytic activity of macroporous titania nanocrystalline membranes. J Membr Sci 389:83–90
Ohko Y, Tatsuma T, Fujii T, Naoi K, Niwa C, Kubota Y, Fujishima A (2003) Multicolour photochromism of TiO2 films loaded with silver nanoparticles. Nat Mater 2:29–31
Onsuratooma S, Chavadej S, Sreethawong T (2011) Hydrogen production from water splitting under UV light irradiation over Ag-loaded mesoporous-assembled TiO2–ZrO2 mixed oxide nanocrystal photocatalysts. Int J Hydrogen Energy 36:5246–5261
Periyat P, Leyland N, McCormack DE, Colreavy J, Corr D, Pillai SC (2010) Rapid microwave synthesis of mesoporous TiO2 for electrochromic displays. J Mater Chem 20:3650–3655
Sauthier G, Pino AP, Figueras A, Gyorgy E (2011) Synthesis and characterization of Ag nanoparticles and Ag-loaded TiO2 photocatalysts. J Am Ceram Soc 94:3780–3786
Sauvage F, Chen D, Comte P, Huang F, Heiniger LP, Cheng YB, Caruso RA, Graetzel M (2010) Dye-sensitized solar cells employing a single film of mesoporous TiO2 beads achieve power conversion efficiencies over 10 %. ACS Nano 4:4420–4425
Wang Q, Yang X, Liu D, Zhao J (2012a) Fabrication, characterization and photocatalytic properties of Ag nanoparticles modified TiO2 NTs. J Alloy Compd 527:106–111
Wang Q, Yang X, Wang X, Huang M, Hou J (2012b) Synthesis of N-doped TiO2 mesosponge by solvothermal transformation of anodic TiO2 nanotubes and enhanced photoelectrochemical performance. Electrochim Acta 32:158–162
Xiong Z, Ma J, Ng WJ, Waite TD, Zhao XS (2011) Silver-modified mesoporous TiO2 photocatalyst for water purification. Water Res 45:2095–2103
Yang G, Jiang Z, Shi H, Xiao T, Yan Z (2010) Preparation of highly visible-light active N-doped TiO2 photocatalyst. J Mater Chem 20:5301–5309
Zheng Z, Huang B, Qin X, Zhang X, Dai Y, Whangbo MH (2011) Facile in situ synthesis of visible-light plasmonic photocatalysts M@TiO2 (M = Au, Pt, Ag) and evaluation of their photocatalytic oxidation of benzene to phenol. J Mater Chem 21:9079–9087
Acknowledgments
This work was financially supported by the National Nature Science Foundation of China (51402145), Science and Technology Development Project of Jilin Province (20140520161JH), Zhejiang Province Natural Science Foundation of China (LQ14E020006), Ph.D Programs Foundation of Ludong University (LY2013015, LY2014016), Shandong Province Natural Science Foundation of China (ZR2013BQ020), and Key Project of Natural Science Foundation of Shandong Province (ZR2013EMZ001).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Wang, Q.Y., Qiao, J.L., Cui, X.Y. et al. Preparation of mesoporous Ag-containing TiO2 heterojunction film and its photocatalytic property. J Nanopart Res 17, 133 (2015). https://doi.org/10.1007/s11051-015-2941-5
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11051-015-2941-5