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Gas flow-controlled microwave combustion synthesis of bismuth oxide nanoparticles

  • Abdulmajeed H. Y. Hendi
  • Saleh I. Al Quraishi
  • Nabil M. MaalejEmail author
Research Paper
  • 321 Downloads

Abstract

Bismuth oxide (Bi2O3) nanoparticles (NPs) were synthesized using a novel inert gas flow-controlled microwave (MW) combustion method. A domestic MW device was modified and used to evaporate bismuth and oxidize it in the ambient atmosphere of the MW cavity. We investigated the effect of synthesis temperature, carrier gas type (nitrogen, argon or helium), and gas flow rate on the structural, optical, morphological, and chemical properties of the synthesized Bi2O3 NPs. The X-ray diffraction analysis shows that all the NPs were of mixed polycrystalline α and β phases of Bi2O3 with predominance of β-phase. For NPs synthesized with N2, Ar, and He as carrier gases, the average NPs size was in the range of 19–86, 25–175, and 18–133 nm, respectively. The NPs size decreased with the increase of carrier gas flow rate. Consequently, the direct band gap values of the samples increased with the increase of flow rates of the carrier gases. The band gap values for the synthesized Bi2O3 NPs were in the ranges of 3.38–3.67 eV for N2 gas, 3.29–3.65 eV for Ar, and 3.25–3.64 eV for He. The FESEM analysis of the synthesized Bi2O3 NPs revealed the formation of plate-like structures. The energy dispersion X-ray spectroscopy analysis confirmed the purity of the NPs which contains only Bi and O. The oxidation state was investigated by the X-ray photoelectron spectroscopy and confirmed the formation of Bi2O3. The Bi2O3 NPs were coated with polyethylene glycol. The NPs have a high attenuation for X-rays and have a potential for X-ray use for X-ray contrast enhancement.

Keywords

Microwave-assisted-synthesis Metal oxide nanoparticles Bismuth oxide nanoparticles 

Notes

Acknowledgments

The author(s) would like to acknowledge the support provided by King Abdulaziz City for Science and Technology (KACST) through the Science & Technology Unit at King Fahd University of Petroleum & Minerals (KFUPM) for funding this work through project No. # 08-BIO96-4. as part of the National Science, Technology and Innovation Plan.

References

  1. Al-Quraishi (2009) Method for synthesizing metal oxide. U.S. Patent 7601324 B1Google Scholar
  2. Anandan S, Wu JJ (2009) Microwave assisted rapid synthesis of Bi2O3 short nanorods. Mater Lett 63:2387CrossRefGoogle Scholar
  3. Barreca D, Morazzoni F, Rizzi GA, Scotti R, Tondello E (2001) Molecular oxygen interaction with Bi2O3: a spectroscopic and spectromagnetic investigation. Phys Chem Chem Phys 3:1743CrossRefGoogle Scholar
  4. Brezesinski K, Ostermann R, Hartmann P, Perlich J, Brezesinski T (2010) Exceptional photocatalytic activity of ordered mesoporous β-Bi2O3 thin films and electrospun nanofiber mats. Chem Mater 22:3079CrossRefGoogle Scholar
  5. Chakrabarti M, Dutta S, Chttapadhyay S, Sarkar A, Sanyal D, Chakrabarti A (2004) Grain size dependence of optical properties and positron annihilation parameters in Bi2O3 powder. Nanotechnology 15:1792CrossRefGoogle Scholar
  6. Cheng H, Huang B, Lu J, Wang Z, Xu B, Qin X, Zhang X, Dai Y (2010) Synergistic effect of crystal and electronic structures on the visible-light-driven photocatalytic performances of Bi2O3 polymorphs. Phys Chem Chem Phys 12:15468CrossRefGoogle Scholar
  7. Clark DE, Folz DC, West JK (2000) Processing materials with microwave energy. Mater Sci Eng A 287:153CrossRefGoogle Scholar
  8. Condurache-Bota S, Rusu GI, Tigau N, Drasovean R, Gheorghies C (2009) Structural and optical characterization of thermally oxidized bismuth films. Rev Roum Chim 54(3):205Google Scholar
  9. Dai Y, Wang Y, Yao J, Wang Q, Liu L, Chu W, Wang G (2008) Phosgene-free synthesis of phenyl isocyanate by catalytic decomposition of methyl N-phenyl carbamate over Bi2O3 catalyst. Catal Lett 123:307CrossRefGoogle Scholar
  10. Ding SN, Shan D, Xue HG (2010) A promising biosensing-platform based on bismuth oxide polycrystalline-modified electrode: characterization and its application in development of amperometric glucose sensor. Bioelectrochemistry 79:218CrossRefGoogle Scholar
  11. Durrani SMA, Khawaja EE, Salim MA, Al-Kuhaili MF, Al-Shukri AM (2002) Effect of preparation conditions on the optical and thermochromic properties of thin films of tungsten oxide. Sol Energy Mater Sol Cells 71:313CrossRefGoogle Scholar
  12. Fan HT, Fan Teng X M, Pan SS, Ye C, Li GH, Zhang LD (2005) Optical properties of δ-Bi2O3 thin films grown by reactive sputtering. Appl Phys Lett 87:231916CrossRefGoogle Scholar
  13. Finlayson AP, Ward E, Tsaneva VN, Glowacki B (2005) Bi2O3-WO3 compounds for photocatalytic applications by solid state and viscous processing. J Power Sources 145:667CrossRefGoogle Scholar
  14. Fowler BA, Sexton MJ (2007) Handbook on the Toxicology of Metals Editors: Nordberg GF, Fowler BA, Nordberg M & Friberg L, (Eds), Academic Press/Elsevier BV, Burlington MA 117Google Scholar
  15. Fruth V, Popa M, Berger D, Ramer R, Gartner M (2005) Deposition and characterization of bismuth oxide thin films. J Eur Ceram Soc 25:2171CrossRefGoogle Scholar
  16. Gehong Z, Xian Z, Yafan W, Weidong S, Weisheng G (2013) Rapid microwave-assisted synthesis of Bi2O3 tubes and photocatalytic properties for antibiotics. Micro Nano Lett 8(4):177–180CrossRefGoogle Scholar
  17. Hardy BG, Hagen C, Ferguson G, Norman DJ (2006) X-ray detection of the presence and/or condition of polymer components. United State Patent 0255511:A1Google Scholar
  18. Huidong X, Dezhong S, Xiaoqing W, Guangqiu S (2007) Microwave hydrothermal synthesis and visible-light photocatalytic activity of Bi2WO6 nanoplates. Mater Chem Phys 103:334–339CrossRefGoogle Scholar
  19. Husson E, Bény JM, Proust C, Benoit R, Erre R, Vaills Y, Belkhader K (1998) Raman and brillouin scattering and XPS spectroscopy in NaPb0.5Bi0.33PO4 glass-evolution as a function of temperature. J Non Cryst Solids 238:66CrossRefGoogle Scholar
  20. Jinhong B, Ling W, Jie L, Zhaohui L, Xuxu W, Xianzhi F (2007) Simple solvothermal routes to synthesize nanocrystalline Bi2MoO6 photocatalysts with different morphologies. Acta Mater 55:4699–4705CrossRefGoogle Scholar
  21. Kanazawa E, Sakai G, Shimanoe K, Kanmura Y, Teraoka Y, Miura N, Yamazoe N (2001) Metal oxide semiconductor N2O sensor for medical use. Sens Actuators B 77:72CrossRefGoogle Scholar
  22. Kharissova OV, Osorio M, Kharisov BI, José Yacamán M, Ortiz Méndez U (2010) A comparison of bismuth nanoforms obtained in vacuum and air by microwave heating of bismuth powder. Mater Chem Phys 121:489–496CrossRefGoogle Scholar
  23. Kharissova OV, Osorio M, Kharisov BI (2012) Less-common bismuth nanostructures obtained by hydrothermal microwave heating. Synth React Inorg Chem 42:246–250CrossRefGoogle Scholar
  24. Kumari L, Lin JH, Ma YR (2007) Synthesis of bismuth oxide nanostructures by an oxidative metal vapour phase deposition technique. Nanotechnology 18:295–605Google Scholar
  25. Leontie L, Caraman M, Rusu GI (2000) On the photoconductivity of Bi2O3 in thin films. J Optoelectron Adv Mater 2:385Google Scholar
  26. Leontie L, Caraman M, Alexe M, Harnagea C (2002) Structural and optical characteristics of bismuth oxide thin films. Surf Sci 507–510:480CrossRefGoogle Scholar
  27. Leslie E, Sparks Pilat J (1970) Effect of diffusiophoresis on particle collection by wet scrubbers. Atmos Environ 4:651CrossRefGoogle Scholar
  28. Lin G, Tan D, Luo F, Chen D, Zhao Q, Qiu J, Xu Z (2010) Fabrication and photocatalytic property of α-Bi2O3 nanoparticles by femtosecond laser ablation in liquid. J Alloy Compd 507:L43CrossRefGoogle Scholar
  29. Malinger KA, Laubernds K, Son YC, Suib SL (2004) Effects of microwave processing on chemical, physical, and catalytic properties of todorokite-type manganese oxide. Chem Mater 16:4296CrossRefGoogle Scholar
  30. Miersch L, Rüffer T, Lang H, Schulze S, Hietschold M, Zahn D, Mehring M (2010) A novel water-soluble hexanuclear bismuth oxido cluster: synthesis, structure and complexation with polyacrylate. Eur J Inorg Chem 30:4763CrossRefGoogle Scholar
  31. Morales AE, Mora ES, Pal U (2007) Use of diffuse reflectance spectroscopy for optical characterization of un-supported nanostructures. Rev Mexicana de Física S 53(5):18Google Scholar
  32. Pan A, Ghosh A (2000) A new family of lead–bismuthate glass with a large transmitting window. J Non Cryst Solids 271:157CrossRefGoogle Scholar
  33. Park S, Kim H, Lee C (2008) Synthesis of very straight bismuth oxide nanowires by using thermal evaporation of bismuth powders. J Korean Phys Soc 53(4):1965Google Scholar
  34. Rajagopal R, Mona J, Joshee RS, Kale SN, Pradhan S, Gaikwad AB, Ravi V (2008) La0.67Ce0.03Sr0.3MnO3-coupled microwave assisted ultra-fast synthesis of nanocrystalline cobalt oxide and bismuth oxide. Mater Lett 62:1511CrossRefGoogle Scholar
  35. Sammes NM, Tompsett GA, Näfe H, Aldinger F (1999) Bismuth based oxide electrolytes: structure and ionic conductivity. J Eur Ceram Soc 19:1801CrossRefGoogle Scholar
  36. Simon V, Todea M, Takács AF, Neumann M, Simon S (2007) XPS study on silica–bismuthate glasses and glass ceramics. Solid State Commun 141:42CrossRefGoogle Scholar
  37. Sirimanne PM, Takahashi K, Sonoyama N, Sakata T (2002) Photocurrent enhancement of wide band gap Bi2O3 by Bi2S3 over layers. Sol Energy Mater Sol Cells 73:175CrossRefGoogle Scholar
  38. Thayer RL, Randall CA, McKinstry TS (2003) Medium permittivity bismuth zinc niobate thin film capacitors. J Appl Phys 94(3):1941CrossRefGoogle Scholar
  39. Voskresenskaya EN, Kurteeva LI, Anshits AG (1992) Solid solutions of bismuth oxide as promising catalysts for oxidative coupling of methane. Appl Catal A 90:209CrossRefGoogle Scholar
  40. Wang C, Shao C, Wang L, Zhang L, Li X, Liu Y (2009) Electrospinning preparation, characterization and photocatalytic properties of Bi2O3 nanofibers. J Colloid Interface Sci 333:242CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • Abdulmajeed H. Y. Hendi
    • 1
  • Saleh I. Al Quraishi
    • 1
    • 2
  • Nabil M. Maalej
    • 1
    • 2
    Email author
  1. 1.Physics DepartmentKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia
  2. 2.Center of Excellence in NanotechnologyKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia

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