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Continuous supercritical hydrothermal synthesis of iron oxide nanoparticle dispersions and their characterization

  • M. Daschner de TerceroEmail author
  • C. Röder
  • U. Fehrenbacher
  • U. Teipel
  • M. Türk
Research Paper

Abstract

Electrostatically stabilized iron oxide nanoparticle dispersions were synthesized using a continuous hydrothermal process at 673 K and 30 MPa. The average size of the primary particles was in the range 5–30 nm. The influence of the flow conditions as well as the composition of the starting material on the dispersion properties was investigated. A new Raman spectroscopic measurement setup was used for the characterization of the structure of the nanoparticles in dispersed form. The use of differential centrifugal sedimentation for the determination of the size distribution of the dispersed particles proved to be convenient and powerful to determine the influence of the investigated parameters on the dispersion properties. For certain compositions of the starting material and flow conditions using a conventional T-union, narrow size distributions concerning both primary particles and agglomerates could be obtained.

Keywords

Hydrothermal synthesis Iron oxides Metal oxide nanoparticles Raman spectroscopy Supercritical water Differential centrifugal sedimentation 

Notes

Acknowledgments

This work was carried out with the support of the Fraunhofer-Gesellschaft. The assistance of J. Graf, S. Unser, D. Rückert (building up and maintaining the high-pressure pilot plant), J. Schubert, F. Keilmann, C. Mönius, M. Zang (carrying out experimental runs), W. Send, C. Kübel (TEM), U. Förter-Barth, M. Herrmann (PXRD), L. Tercero Espinoza (assistance in programming with “R” for conveniently processing and visualizing data), and G. Irmer (Raman spectroscopy) is gratefully acknowledged.

Supplementary material

11051_2014_2350_MOESM1_ESM.pdf (3.8 mb)
Supplementary material 1 (pdf 3913 KB)

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Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  • M. Daschner de Tercero
    • 1
    • 2
    • 5
    Email author
  • C. Röder
    • 3
  • U. Fehrenbacher
    • 1
  • U. Teipel
    • 4
  • M. Türk
    • 5
  1. 1.Fraunhofer Institute for Chemical Technology ICTPfinztalGermany
  2. 2.Projektträger Karlsruhe (PTKA)Karlsruhe Institute of Technology (KIT)Eggenstein-LeopoldshafenGermany
  3. 3.Institut für Theoretische PhysikTechnische Universität Bergakademie FreibergFreibergGermany
  4. 4.Particle TechnologyTechnische Hochschule NürnbergNurembergGermany
  5. 5.Institute for Technical Thermodynamics and RefrigerationKarlsruhe Institute of Technology (KIT)KarlsruheGermany

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