Abstract
Advances in nanoscale science and engineering suggest that many of the current problems involving the sustainable utilization and supply of critical materials in clean and renewable energy technologies could be addressed using (i) nanostructured materials with enhanced electronic, optical, magnetic and catalytic properties and (ii) nanotechnology-based separation materials and systems that can recover critical materials from non-traditional sources including mine tailings, industrial wastewater and electronic wastes with minimum environmental impact. This article discusses the utilization of nanotechnology to improve or achieve materials sustainability for energy generation, conversion and storage. We highlight recent advances and discuss opportunities of utilizing nanotechnology to address materials sustainability for clean and renewable energy technologies.
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References
Aricò AS, Bruce P, Scrosati B, Tarascon JM, van Schalkwijk W (2005) Nanostructured materials for advanced energy conversion and storage devices. Nat Mat 4:366–377
ARPA-E (Advanced Research Projects Agency-Energy) (2011) Rare earth alternatives in critical technologies (REACT). http://arpa-e.energy.gov/?q=arpa-e-programs/react
Ba C, Langer J, Economy J (2009) Chemical modification of P84 copolyimide membranes by polyethylenimine for nanofiltration. J Membr Sci 327:49–58
Bian Z, Mia X, Lei S, Chen SE, Wang W, Stuthers S (2012) The challenges of reusing mining and mineral-processing wastes. Science 337:702–703
Brinker JC, Ginger D (2011) Nanotechnology for sustainability: energy conversion, storage, and conservation. In: Roco MC, Mirkin MC, Hersham M (eds) Nanotechnology research directions for societal needs in 2020: retrospective and outlook. Springer, New York, pp 261–303
Callahan DM, Munday JN, Atwater HA (2012) Solar cell light trapping beyond the ray optic limit. Nano Lett 12:214–218
Cavaliere S, Subianto S, Savych I, Jones DJ, Rozière J (2011) Electrospinning: designed architectures for energy conversion and storage devices. Energy Environ Sci 4:4761–4785
Chen DP, Yu CJ, Chang C-Y, Wan Y, Frechet JMJ, Goddard WA, Diallo MS (2012) Branched polymeric media: perchlorate-selective resins from hyperbranched polyethyleneimine. Environ Sci Technol 46:10718–10726
Cheng S, Oatley DL, Williams PM, Wright CJ (2011) Positively charged nanofiltration membranes: review of current fabrication methods and introduction of a novel approach. Adv Colloid Interface Sci 164:12–20
Cohen SM, Petoud S, Raymond KN (2001) Synthesis and metal binding properties of salicylate-, catecholate-, and hydroxypyridinonate-functionalized dendrimers. Chemistry-A 7:272–279
Deceglie MG, Ferry VE, Alivisaos AP, Atwater HA (2012) Design of nanostructured solar cells using coupled optical and electrical modeling. Nano Lett 12:2894–2900
Déon S, Escoda A, Fievet P (2011) A transport model considering charge adsorption inside pores to describe salts rejection by nanofiltration membranes. Chem Eng Sci 66:2823–2832
Diallo MS (2008) Water treatment by dendrimer enhanced filtration. US Patent 7,470,369
Diallo MS, Brinker JC (2011) Nanotechnology for sustainability: environment, water, food, minerals and climate. In: Roco MC, Mirkin MC, Hersham M (eds) Nanotechnology research directions for societal needs in 2020: retrospective and outlook. Science policy reports. Springer, New York, pp 221–259
Diallo MS et al. (2013) Implications: convergence of knowledge and technology for a sustainable society. In: Roco MC, Bainbridge WS, Tonn B, Whitesides G (eds) Convergence of knowledge, technology, and society: beyond convergence of nano-bio-info-cognitive technologies. Science Policy Reports, Springer, Dordrecht
Diallo MS, Chritie S, Swaminathan P, Balogh L, Shi X, Um W, Papelis L, Goddard WA, Johnson JH (2004) Dendritic chelating agents 1. Cu(II) binding to ethylene diamine core poly(amidoamine) dendrimers in aqueous solutions. Langmuir 20:2640–2651
Diallo MS, Chritie S, Swaminathan P, Johnson JH, Goddard WA (2005) Dendrimer enhanced ultrafiltration. 1. Recovery of Cu(II) from aqueous solutions using Gx–NH2 PAMAM dendrimers with ethylene diamine ore. Environ Sci Technol 39:1366–1377
Diallo MS, Wondwossen A, Johnson JH, Goddard WA (2008) Dendritic chelating agents 2. U(VI) binding to poly(amidoamine) and poly(propyleneimine) dendrimers in aqueous solutions. Environ Sci Technol 42:1572–1579
DOE (Department of Energy) (2006) Basic research needs for advanced nuclear energy systems. http://science.energy.gov/bes/news-and-resources/reports/abstracts/#ANES
DOE (Department of Energy) (2011) Critical materials strategy. http://energy.gov/pi/office-policy-and-international-affairs/downloads/2010-critical-materialsstrategy
Dvornic PR, Uppuluri S (2002) Rheology and solution properties of dendrimers. In: Fréchet JMJ, Tomalia DA (eds) Dendrimers and other dendritic polymers. Wiley, New York
Escoda A, Lanteri Y, Fievet P, Déon S, Szymczyk A (2010) Determining the dielectric constant inside pores on nanofiltration membranes from membrane potential measurements. Langmuir 26:14628–14635
Fréchet JMJ, Tomalia DA (2002) Dendrimers and other dendritic polymers. Wiley, New York
Fromer N, Eggert RG, Lifton J (2011) Critical materials for sustainable energy applications. Resnick Institute Report, California Institute of Technology. http://resnick.caltech.edu/programs/critical-materials/index.html
Gloe K, Stephan H, Grotjahn M (2003) Where is the anion extraction going? Chem Eng Technol 26:1107–1117
Gomes CP, Almeida MF, Loureiro JM (2001) Gold recovery with ion exchange used resins. Sep Purif Technol 24:35–57
Grandidier J, Callahan DM, Munday JN, Atwater HA (2012) Gallium arsenide solar cell absorption enhancement using whispering gallery modes of dielectric nanospheres. IEEE J Photovolt 2:123–128
Guo Q, Ford GM, Yang WC, Walker BC, Stach EA, Hillhouse HW, Agrawal R (2010) Fabrication of 7.2% efficient CZTSSe solar cells using CZTS nanocrystals. J Am Chem Soc 132:17384–17386
Gur I, Fromer NA, Geier ML, Alivisatos AP (2005) Air-stable all inorganic nanocrystal solar cells processed from solution. Science 310:462–465
Harland CE (1994) Ion-exchange: theory and practice, 2nd edn. Royal Society of Chemistry, London
IPCC (Intergovernmental Panel on Climate Change) (2007) Solomon, S, Quin, D, Manning, M, Chen, Z, Marquis, M, Averyt, KB, Tignor, M, Miller, HL (eds) Climate change 2007: the physical science basis. Cambridge University Press, Cambridge
Ji Y, An Q, Zhao Q, Chen H, Gao C (2011) Preparation of novel positively charged copolymer membranes for nanofiltration. J Membr Sci 376:254–265
Johnson J, Harper EM, Lifset R, Graedel TE (2007) Dining at the periodic table: metals concentration as they relate to recycling. Environ Sci Technol 41:1759–1765
Kneller EF, Hawig R (1991) The exchange-spring magnet—a new material principle for permanent-magnets. IEEE Trans Magn 27:3588–3600
Krämer M, Stumbé JF, Grimm G, Kaufmann B, Krüger U, Webe M, Haag R (2004) ChemBioChem 5:1081–1087
Lewis NS, Nocera DG (2006) Powering the planet: chemical challenges in solar energy utilization. Proc Natl Acad Sci 103:15729–15735
Liu XQ, He SH, Qiq JM, Wang JP (2011) Nanocomposite exchange-spring magnet synthesized by gas phase method: from isotropic to anisotropic. Appl Phys Lett 98:222507
Ma W, Luther JM, Zhend HM, Wu Y, Alivisatos AP (2009) Photovoltaic devices employing ternary PbS x Se1−x nanocrystals. Nano Lett 9:1699–1703
Maiti PK, Lin T, Cagin ST, Goddard WA (2005) The effect of solvent and pH on the structure of PAMAM dendrimers. Macromolecules 38:979–991
Martell AE, Hancock RD (1996) Metal complexes in aqueous solutions. Plenum Press, New York
Matejka Z, Parschova H, Ruszova P et al (2004) Selective uptake and separation of oxoanions of molybdenum, vanadium, tungsten, and germanium by synthetic sorbents having polyol moieties and polysaccharide-based biosorbents. In: Moyer BA, Singh P (eds) Fundamentals and applications of anion separations. Kluwer Academic/Plenum Publishers, New York
Mckone J, Sadtler B, Werlang C, Lewis NS, Gray HB (2013) Ni–Mo nanopowders for efficient electrochemical hydrogen evolution. ACS Catal 3:166–169
Mishra H, Yu, CJ, Chen DP, Dalleska NF, Hoffmann MR, Goddard, WA, Diallo MS (2012) Branched polymeric media: boron-chelating resins from hyperbranched polyethyleneimine. Environ Sci Technol 46:8998–9004
Moss R, Tzimas E, Kara H, Willis P, Kooroshy J (2011) Critical metals in strategic energy technologies. Publications Office of the European Union. http://publications.jrc.ec.europa.eu/repository/handle/111111111/22726
Moyer BA, Bonnesen PV (1997) Physical factors in anion separations. In: Bianchi A, Bowman-James K, GarcÃa-Espana E (eds) Supramolecular chemistry of anions. VCH, New York, pp 1–44
Nakamuro E, Sato K (2011) Managing the scarcity of chemical elements. Nat Mat 10:158–161
NRC (National Research Council) (2008) Minerals, critical minerals, and the U.S. economy. ISBN: 0-309-11283
O’Donnell KP, Maur MAD, Di Carlo A, Lorenz K (2012) It’s not easy being green: strategies for all-nitrides, all colour solid state lighting. Phys Stat Solidi 6:49–52
Park S-J, Cheedrala RK, Diallo MS, Kim CH, Kim IS, Goddard WA (2012) Nanofiltration membranes based on polyvinyldene fluoride nanofibrous scaffolds and crosslinked polyethyleimine networks. J Nanopart Res 14:884
Raghavan P, Lim DH, Ahn JH et al (2012) Electrospun polymer nanofibers: the booming cutting edge technology. React Funct Polym 72:915–930
Reck BK, Graedel TE (2012) Challenges in metal recycling. Science 337:690–695
Schäefer A, Fane AG, Waite TD (2005) Nanofiltration: principles and applications. Elsevier, New York
Scott RWJ, Wilson OM, Crooks RM (2005) Synthesis, characterization and applications of dendrimer-encapsulated manoparticles. J Phys Chem B 109:692–704
Seiler M (2006) Hyperbranched polymers: phase behavior and new applications in the field of chemical engineering. Fluid Phase Equilib 241:155–174
Shen Y, Huang MQ, Lee D, Bauser S, Higgins A, Chen C, Liu S (2006) Hybrid nanograin rare earth magnets with improved thermal stability. J Appl Phys 99:08B520
Soldenhoff K, McCulloh J, Manis A, Macintosh P (2005) Nanofiltration in metal and acid recovery. In: Schäefer A, Fane AG, Waite TD (eds) Nanofiltration: principles and applications. Elsevier, New York, pp 459–477
Strathmann H (2011) Introduction to membrane science and technology. Wiley-VCH, Weinheim
Stricker N (2013) Reverse mining: scientists extract rare earth materials from consumer products. https://inlportal.inl.gov/portal/server.pt/community/newsroom/257/feature_story_details/1269?featurestory=DA_606590)
Stumm W, Morgan JJ (1996) Aquatic chemistry: chemical equilibria and rates in natural waters, 3rd edn. Wiley, New York
Suntivich J, May K, Gasteiger H, Goodenough J, Shao-Horn Y (2011) A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles. Science 334:1383–1385
Tomalia DA, Diallo MS (2012) Dendrimers: synthetic science to controlled organic nanostructures and a window to a new systematic framework for unifying nanoscience. In: Goddard WA, Brenner DW, Lyshevski SE, Iafrate GJ (eds) Handbook of nanoscience, engineering and technology, 3rd edn. CRC Press, Boca Raton, pp 413–467
Valdivia CE, Chow S, Fafard S, et al. (2010) Measurement of high efficiency 1 cm2 AlGaInP/InGaAs/Ge solar cells with embedded InAs quantum dots at up to 1000 suns continuous concentration. In: Proceedings of the 35th IEEE photovoltaic specialists conference (PVSC), pp 1253–1258
Vankelecom IFJ, De Smet K, Gevers LEM, Jacobs PA (2005) Nanofiltration membrane materials and preparation. In: Schäefer A, Fane AG, Waite TD (eds) Nanofiltration: principles and applications. Elsevier, New York, pp 34–65
Vezzani D, Bandini S (2002) Donnan equilibrium and dielectric exclusion for characterization of nanofiltration membranes. Desal 149:477–483
Vrubel H, Merki D, Hu X (2012) Hydrogen evolution catalyzed by MoS3 and MoS2 particles. Energy Environ Sci 5:6136–6144
Zhang Y, Xie C, Su H et al (2011) Employing heavy metal-free colloidal quantum dots in solution-processed white light-emitting diodes. Nano Lett 11:329–332
Zhao T, Zheng Y, Poly J, Wang W (2013) Controlled multi-vinyl monomer homopolymerization through vinyl oligomer combination as a universal approach to hyperbranched architectures. Nat Commun 4:1873. (http://www.nature.com/ncomms/journal/v4/n5/full/ncomms2887.html)
Acknowledgments
Neil A. Fromer thanks the Resnick Sustainability Institute, as well as the LMI-EFRC, Rod Eggert, and Jack Lifton and the other attendees of the Resnick Institute critical materials workshop for helpful discussions. Mamadou Diallo thanks the EEWS Initiative (Grant # NT080607C0209721), the National Research Foundation of Korea (NRF) [MEST grant No. 2012M1A2A2026588] and the National Science Foundation (NSF) of United States [CBET grants 0948485 and 0506951] for funding his research on sustainable chemistry, engineering and materials (SusChEM).
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Special Issue Editors: Mamadou Diallo, Neil Fromer, Myung S. Jhon
This article is part of the Topical Collection on Nanotechnology for Sustainable Development
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Fromer, N.A., Diallo, M.S. Nanotechnology and clean energy: sustainable utilization and supply of critical materials. J Nanopart Res 15, 2011 (2013). https://doi.org/10.1007/s11051-013-2011-9
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DOI: https://doi.org/10.1007/s11051-013-2011-9