Abstract
Nanoparticles intended for high value added applications often require special size distributions. Based on model calculations, this article compares the particle size distributions obtained with conventional and plasma processes. The model is based on an estimation of the probability for collisions; either for neutral or equally charged particles, whereas the growth of the particles is calculated using a model derived from Markov chains. The results of these calculations confirm the empirical knowledge that, under the special conditions of particles carrying electric charges of equal sign, plasma processes deliver products with the narrowest particle size distribution. Synthesis of extremely small particles with conventional processes leads to a significant residue of unreacted precursor. This finding is important in cases of expensive educts. The results of these model calculations are in perfect agreement with experimental findings.
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Albriet B, Sartelet KN, Lacour S, Carissimo B, Seigneur C (2010) Modeling aerosol number distributions from a vehicle exhaust with an aerosol CFD model. Atmos Environ 44:1126–1137
Bean CP, Livingston JD (1959) Superparamagnetism. J Appl Phys 30:120–129
Binder K (1979) Monte Carlo methods in statistical physics. Springer, Berlin
Dang H, Swihart MT (2009) Computational modeling of silicon nanoparticle synthesis: II. A two-dimensional bivariate model for silicon nanoparticle synthesis in a laser-driven reactor including finite-rate coalescence. Aerosol Sci Technol 43:554–569
Dijken A, van Makkinje J, Meijerink A (2001) The influence of particle size on the luminescence quantum efficiency of nanocrystalline ZnO particles. J Lumin 92:323–328
Fiedler SL, Izvekov S, Angela Violi A (2007) The effect of temperature on nanoparticle clustering. Carbon 45:1786–1794
Levin DA, Peres Y, Wilmer EL (2009) Markov chains and mixing times. Am Math Soc, USA, pp 1–45
MacDonald AD (1966) Microwave breakdown in gases. Wiley, New York
Matsui I (2006) Preparation of magnetic nanoparticles by pulsed plasma vapor synthesis. J Nanopart Res 8:429–443
Nitsche R, Rodewald M, Skandan G, Fuess H, Hahn H (1996) HRTEM study of nanocrystalline zirconia powders. NanoStr Mater 7:535–546
Paur HR, Baumann W, Mätzing H, Seifert H (2005) Formation of nanoparticles in flames; measurement by particle mass spectrometry and numerical simulation. Nanotechnology 16:S354–S361
Takagahara T, Takeda K (1992) Theory of the quantum confinement effect on excitons in quantum dots of indirect-gap materials. Phys Rev B 46:15578–15581
Tekna Plasma Systems Inc. Canada (2007). http//www.tekna.com
Vollath D (2008) Nanomaterials—an introduction to synthesis, properties, and applications. Wiley-VCH, Weinheim
Vollath D, Szabó DV (2006) The microwave plasma process—a versatile process to synthesize nanoparticulate materials. J Nanopart Res 8:417–428
Vollath D, Szabó DV, Taylor RD, Willis JO, Sickafus KE (1995) Synthesis and properties of nanocrystalline superparamagnetic γ-Fe2O3. Nanostruct Mater 6:941–944
Vollath D, Szabo DV, Taylor RD, Willis JO (1997) Synthesis and magnetic properties of nanostructured maghemite. J Mater Res 12:2175–2182
Wang G, Garrick SC (2005) Modeling and simulation of Titania synthesis in two-dimensional methane—air flames. J Nanopart Res 7:621–632
Wang G, Garrick SC (2006) Modeling and simulation of Titania formation and growth in temporal mixing layers. Aerosol Sci 37:431–451
Wang Y, Herron N (1991) Nanometer-sized semiconductor clusters: materials synthesis, quantum size effects, and photophysical properties. J Phys Chem 95:525–532
Widiyastuti W, Purwanto A, Wang WN, Iskandar F, Setyawan H, Okuyama K (2009) Nanoparticle formation through solid-fed flame synthesis: experiment and modelling. Particle Technol 55:885–895
Widiyastuti W, Hidayat D, Purwanto A, Iskandar F, Okuyama K (2010) Particle dynamics simulation of nanoparticle formation in a flame reactor using a polydispersed submicron-sized solid precursor. Chem Eng J 158:362–367
Yu M, Lin J, Chan T (2008) Numerical simulation of nanoparticle synthesis in diffusion flame reactor. Powder Technol 181:9–20
Zieman PJ, Kittelson DB, McMurry PH (1996) Effect of particle shape and chemical composition on the electron impact charging properties of submicron inorganic particles. J Aerosol Sci 27:587–606
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Vollath, D. Estimation of particle size distributions obtained by gas phase processes. J Nanopart Res 13, 3899–3909 (2011). https://doi.org/10.1007/s11051-011-0343-x
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DOI: https://doi.org/10.1007/s11051-011-0343-x