Abstract
Poly (vinyl alcohol) (PVA) and poly (vinyl pyrrolidone) (PVP) nanofibers embedding Ag nanoparticles (5–18 nm) have been prepared successfully by electrospinning at room temperature. Scanning electron microscope (SEM), X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), Fourier transform IR spectra (FTIR), and Raman scattering were used to characterize the structure and properties of Ag nanoparticle-embedded PVA and PVP nanofibers before and after heat treatment at different temperature. The antibacterial activity of Ag nanoparticle-embedded PVP nanofibers after heat treatment was also tested, which indicated that the biological activity of yeast cells was effectively inhibited by these Ag nanoparticle-embedded PVP nanofibers.
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References
Boccara AC, Fournier D, Kumar A, Pandey GC (1997) Nondestructive evaluation of carbon fiber by mirage-FTIR spectroscopy. J Appl Polym Sci 63:1785–1791. doi:10.1002/(SICI)1097-4628(19970328)63:13<1785::AID-APP11>3.0.CO;2-Y
Bognitzki M, Czado W, Frese T, Schaper A, Hellwig M, Steinhart M, Greiner A, Wendorff JH (2001) Nanostructured fibers via electrospinning. Adv Mater 13:70–72. doi:10.1002/1521-4095(200101)13:1<70::AID-ADMA70>3.0.CO;2-H
Duan YY, Jia J, Wang SH, Yan W, Jin L, Wang ZY (2007) Preparation of antimicrobial poly (epsilon-caprolactone) electrospun nanofibers containing silver-loaded zirconium phosphate nanoparticles. J Appl Polym Sci 106:1208–1214. doi:10.1002/app.26786
Escribano R, Sloan J (2001) Raman spectroscopy of carbon-containing particles. Vib Spectrosc 26:179–186. doi:10.1016/S0924-2031(01)00106-0
Formo E, Lee E, Campbell D, Xia YN (2008) Functionalization of electrospun TiO2 nanofibers with Pt nanoparticles and nanowires for catalytic applications. Nano Lett 8:668–672. doi:10.1021/nl073163v
Hong KH (2007) Preparation and properties of electrospun poly (vinyl alcohol)/silver fiber web as wound dressings. Polym Eng Sci 47:43–49. doi:10.1002/pen.20660
Jana NR, Gearheart L, Murphy CJ (2001) Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio. Chem Commun (Camb) 7:617–618. doi:10.1039/b100521i
Jin WJ, Lee HK, Jeong EH, Park WH, Youk JH (2005) Preparation of polymer nanofibers containing silver nanoparticles by using poly (N-vinylpyrrolidone). Macromol Rapid Commun 26:1903–1907. doi:10.1002/marc.200500569
Jin M, Zhang XT, Nishimoto S, Liu ZY, Tryk DA, Murakami T, Fujishima A (2007a) Large-scale fabrication of Ag nanoparticles in PVP nanofibres and net-like silver nanofibre films by electrospinning. Nanotechnology 18:075605. doi:10.1088/0957-4484/18/7/075605
Jin WJ, Jeon HJ, Kim JH, Youka JH (2007b) A study on the preparation of poly (vinyl alcohol) nanofibers containing silver nanoparticles. Synth Met 157:454–459. doi:10.1016/j.synthmet.2007.05.011
Li D, Xia YN (2004) Electrospinning of nanofibers: reinventing the wheel? Adv Mater 16:1151–1170. doi:10.1002/adma.200400719
Li D, McCann JT, Gratt M, Xia YN (2004) Photocatalytic deposition of gold nanoparticles on electrospun nanofibers of titania. Chem Phys Lett 394:387–391. doi:10.1016/j.cplett.2004.07.044
Li ZY, Huang HM, Shang TC, Yang F, Zheng W, Wang C, Manohar SK (2006) Facile synthesis of single-crystal and controllable sized silver nanoparticles on the surfaces of polyacrylonitrile nanofibres. Nanotechnology 17:917–920. doi:10.1088/0957-4484/17/3/050
Misra A, Tyagi PK, Singh MK, Misra DS (2006) FTIR studies of nitrogen doped carbon nanotubes. Diam Relat Mater 15:385–388. doi:10.1016/j.diamond.2005.08.013
Moran-Mirabal JM, Slinker JD, DeFranco JA, Verbridge SS, Ilic R, Flores-Torres S, Abruna H, Malliaras GG, Craighead HG (2007) Electrospun light-emitting nanofibers. Nano Lett 7:458–463. doi:10.1021/nl062778+
Patel AC, Li SX, Wang C, Zhang WJ, Wei Y (2007) Electrospinning of porous silica nanofibers containing silver nanoparticles for catalytic applications. Chem Mater 19:1231–1238. doi:10.1021/cm061331z
Piperno S, Lozzi L, Rastelli R, Passacantando M, Santucci S (2006) PMMA nanofibers production by electrospinning. Appl Surf Sci 252:5583–5586. doi:10.1016/j.apsusc.2005.12.142
Rafizah WAW, Ismail AF (2008) Effect of carbon molecular sieve sizing with poly (vinyl pyrrolidone) K-15 on carbon molecular sieve-polysulfone mixed matrix membrane. J Membr Sci 307:53–61. doi:10.1016/j.memsci.2007.09.007
Shao CL, Yang XH, Guan HY, Liu YC, Gong J (2004) Electrospun nanofibers of NiO/ZnO composite. Inorg Chem Commun 7:625–627. doi:10.1016/j.inoche.2004.03.006
Song HW, Yu HQ, Pan GH, Bai X, Dong B, Zhang XT, Hark SK (2008) Electrospinning preparation, structure, and photoluminescence properties of YBO3: Eu3+ nanotubes and nanowires. Chem Mater 20:4762–4767. doi:10.1021/cm8007864
Tachikawa T, Ishigaki T, Li JG, Fujitsuka M, Majima T (2008) Defect-mediated photoluminescence dynamics of Eu3+-doped TiO2 nanocrystals revealed at the single-particle or single-aggregate level. Angew Chem Int Ed 47:5348–5352. doi:10.1002/anie.200800528
Wang YZ, Li YX, Yang ST, Zhang GL, An DM, Wang C, Yang QB, Chen XS, Jing XB, Wei Y (2006) A convenient route to polyvinyl pyrrolidone/silver nanocomposite by electrospinning. Nanotechnology 17:3304–3307. doi:10.1088/0957-4484/17/13/037
Wu J, Coffer JL (2007) Emissive erbium-doped silicon and germanium oxide nanofibers derived from an electrospinning process. Chem Mater 19:6266–6276. doi:10.1021/cm702226x
Xu XY, Yang QB, Wang YZ, Yu HJ, Chen XS, Jing XB (2006) Biodegradable electrospun poly (l-lactide) fibers containing antibacterial silver nanoparticles. Eur Polym J 42:2081–2087. doi:10.1016/j.eurpolymj.2006.03.032
Zaporojtchenko V, Podschun R, Schurmann U, Kulkarni A, Faupel F (2006) Physico-chemical and antimicrobial properties of co-sputtered Ag-Au/PTFE nanocomposite coatings. Nanotechnology 17:4904–4908. doi:10.1088/0957-4484/17/19/020
Zhang YW, Peng HS, Huang W, Zhou YF, Yan DY (2008) Facile preparation and characterization of highly antimicrobial colloid Ag or Au nanoparticles. J Colloid Interface Sci 325:371–376. doi:10.1016/j.jcis.2008.05.063
Acknowledgments
This study was financially supported by the National Natural Science Foundation of China (Grant Nos. 50872123 and 50802083), the National Basic Research Program of China (2006CB806000b), and the Program for Changjiang Scholars and Innovative Research Team in University (IRT0651).
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Dong, G., Xiao, X., Liu, X. et al. Preparation and characterization of Ag nanoparticle-embedded polymer electrospun nanofibers. J Nanopart Res 12, 1319–1329 (2010). https://doi.org/10.1007/s11051-009-9665-3
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DOI: https://doi.org/10.1007/s11051-009-9665-3