Abstract
Recently, we have demonstrated the successful synthesis of Fe x Co1−x /Co y Fe3−y O4 nanocomposites with various alkaline solutions by using surfactants-assisted-hydrothermal (SAH) process. In this article, the synthesis of Fe x Co1−x /CoyFe3−y O4 nanocomposites with their sizes varying between 20 nm and 2 μm was reported. X-ray powder diffraction (XRD) analyses showed that the surfactants, pH, precipitator, and temperature of the system play important roles in the nucleation and growth processes. The magnetic properties tested by vibrating sample magnetometer (VSM) at room temperature exhibit ferromagnetic behavior of the nanocomposites. These Fe x Co1−x /Co y Fe3−y O4 nanocomposites may have a potential application as magnetic carriers for drug targeting because of their excellent soft-magnetic properties.
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References
Berkowitz AE, Shuele WJ, Flanders PJ (1968) Influence of crystallite size on the magnetic properties of acicular γ-Fe2O3 particles. J Appl Phys 39:1261–1263
Caillof T, Pourroy G, Stuerga D (2004) Microwave hydrothermal flash synthesis of nanocomposites Fe–Co cobalt alloy/cobalt ferrite. J Solid State Chem 177:3843–3848. doi:10.1016/j.jssc.2004.06.009
Cornell RM, Schwertmann U (1996) The iron oxide: structure, properties, reactions, occurrence and uses. VCH, Weinheim
Cullity BD, Stock SR (2001) Elements of X-ray diffraction, 3rd edn. Prentice Hall, London, UK
Estournes C, Cornu N, Guille JL (1994) Reduction of copper in soda-lime silicate glass by hydrogen. J Non-Cryst Solids 170:287–294. doi:10.1016/0022-3093(94)90058-2
Fröba M, Köhn R, Bouffaud G, Richard O, Van Tendeloo G (1999) Fe2O3 nanoparticles within mesoporous MCM-48 silica. In situ formation and characterization. Chem Mater 11:2858–2865
Hunter RJ (1987) Foundations of colloid science, vol 1. Oxford University Press, Oxford, p 420
Läkamp S, Pourroy G (1996) Influence of Co/Fe ratio on the synthesis of cobalt containing metal–spinel composites by using iron disproportionation. J Solid State Chem 123:109–114
Li D, Kaner RB (2006) Shape and aggregation control of nanoparticles: not shaken, not stirred. J Am Chem Soc 128:968–975. doi:10.1021/ja056609n
Lopez-Quintela MA, Rivas J (1993) Chemical reactions in microemulsions: a powerful method to obtain ultrafine particles. J Colloid Interface Sci 158:446–451. doi:10.1006/jcis.1993.1277
Martinez B, Obradors X, Balcells L, Rouanet A, Monty C (1998) Low temperature surface spin–glass transition in γ-Fe2O3 nanoparticles. Phys Rev Lett 80:181–184. doi:10.1103/PhysRevLett.80.181
Osso D, Tillement O, Le Caer G, Mocellin AJ (1998) Alumina-alloy nanocomposite powders by mechanosynthesis. Mater Sci 33:3109–3119. doi:10.1023/A:1004343806144
Parker FT, Foster MW, Margulies DT, Berkowitz AE (1993) Spin canting, surface magnetization, and finite-size effects in γ-Fe2O3 particles. Phys Rev B 47:7885. doi:10.1103/PhysRevB.47.7885
Pelecky DLL, Rieke RD (1996) Magnetic properties of nanostructured materials. Chem Mater 8:1770–1783. doi:10.1021/cm960077f
Peng ZA, Peng X (2001) Mechanisms of the shape evolution of CdSe nanocrystals. J Am Chem Soc 123:1389–1395. doi:10.1021/ja0027766
Peng ZA, Peng X (2002) Nearly monodisperse and shape-controlled CdSe nanocrystals via alternative routes: nucleation and growth. J Am Chem Soc 124:3343–3353. doi:10.1021/ja0173167
Tihay F, Roger AC, Kiennemann A, Lakamp S, pourroy G (2000) Fe–Co based metal/spinel to produce light olefins from syngas. Catal Today 58:263–269
Tihay F, Roger AC, Pourroy G, Kiennemann A (2002) Role of the alloy and spinel in the catalytic behaviour of Fe–Co/cobalt magnetite composites under CO and CO2 hydrogenation. Energy Fuels 16:1271–1276. doi:10.1021/ef020059m
Tyan HL, Liu YC, Wei KH (1999) Thermally and mechanically enhanced clay/polyimide nanocomposite via reactive organoclay. Chem Mater 11:1942–1947. doi:10.1021/cm990187x
Voit W, Kim DK, Zapka W, Muhammed M, Rao KV (2001) Magnetic behaviour of coated superparamagnetic iron oxide nanoparticles in ferrofluids. Mater Res Soc 676:781–786
Zhao L, Zhang H, Xin Y, Sun S, Yu S (2007) Morphology-controlled synthesis of magnetites with nanoporous structures and excellent magnetic properties. Chem Mater 20:198–204. doi:10.1021/cm702352y
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This work is supported by the National Natural Science Foundation of China.
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Wang, Q., Yang, H. Morphology and magnetic properties of Fe x Co1−x /Co y Fe3−y O4 nanocomposites prepared by surfactants-assisted-hydrothermal process. J Nanopart Res 11, 1043–1051 (2009). https://doi.org/10.1007/s11051-008-9495-8
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DOI: https://doi.org/10.1007/s11051-008-9495-8