Journal of Nanoparticle Research

, Volume 11, Issue 4, pp 879–884 | Cite as

Wide colour gamut generated in triply lanthanide doped sol–gel nano-glass–ceramics

  • J. del-Castillo
  • J. Méndez-Ramos
  • A. C. Yanes
  • V. D. Rodríguez
Research Paper

Abstract

The generation of a wide colour gamut, based on up-conversion of cheap near-infrared photons into the visible range, is of great importance for general lighting appliances and integrated optical devices. Here, we report for the first time on up-conversion luminescence under infrared excitation at 980 nm in Yb3+–Er3+–Tm3+ triply doped sol–gel derived SiO2–LaF3 based nano-glass–ceramics (SOL-YET), containing LaF3 nanocrystals with a size about 13 nm. Efficient simultaneous up-conversion emission of the three primary colours (blue, green and red) gives rise to a balanced white overall emission. The ratio between up-conversion emission bands can be varied by changing pump power intensity resulting in colour tuneable up-conversion phosphor.

Keywords

Nano-structured materials Glass–ceramics Sol–gel White light generation Synthesis method 

References

  1. Alivisatos AP (1996) Semiconductor clusters, nanocrystals, and quantum dots. Science 271:933−937. doi:10.1126/science.271.5251.933 CrossRefADSGoogle Scholar
  2. Amorim HT, Vermelho MVD, Gouveia-Neto AS, Cassanjes FC, Ribeiro SJL, Messaddeq Y (2003) Red–green–blue upconversion emission and energy-transfer between Tm3+ and Er3+ ions in tellurite glasses excited at 1.064 μm. J Solid State Chem 171:278–281. doi:10.1016/S0022-4596(02)00176-7 CrossRefADSGoogle Scholar
  3. Bernius MT, Inbasekaran M, O’Brien J, Wu W (2000) Progress with light-emitting polymers. Adv Mater 12:1737–1750CrossRefGoogle Scholar
  4. Biswas A, Maciel GS, Friends CS, Prasad PN (2003) Up-conversion properties of a transparent Er3+–Yb3+ co-doped LaF3–SiO2 glass-ceramics prepared by sol–gel method. J Non-Cryst Solids 316:393–397. doi:10.1016/S0022-3093(02)01951-8 CrossRefADSGoogle Scholar
  5. Brinker JC, Sherer GW (1990) Sol-gel science. The physics and chemistry of sol-gel processing. Academic Press Inc, NYGoogle Scholar
  6. Brovelli S, Chiodini N, Lauria A, Meniardi F, Paleari A (2006) Energy transfer to erbium ions from wide-band-gap SnO2 nanocrystals in silica. Phys Rev B 73:073406–073409. doi:10.1103/PhysRevB.73.073406 CrossRefADSGoogle Scholar
  7. Chen CT (2004) Evolution of red organic light-emitting diodes: materials and devices. Chem Mater 16:4389–4400. doi:10.1021/cm049679m CrossRefADSGoogle Scholar
  8. Chen D, Wang Y, Yu Y, Ma E, Zhou L (2006) Microstructure and luminescence of transparent glass-ceramic containing Er3+:BaF2 nano-crystals. J Solid State Chem 179:532–537. doi:10.1016/j.jssc.2005.11.010 CrossRefADSGoogle Scholar
  9. Chen D, Wang Y, Zheng K, Guo T (2007) Bright up-conversion white light emission in transparent glass ceramic embedding Tm3+/Er3+/Yb3+:β-YF3 nanocrystals. Appl Phys Lett 91:251903–251905. doi:10.1063/1.2825285 CrossRefADSGoogle Scholar
  10. Cheng G, Zhao Y, Zhang YF, Liu SY, He F, Zhang HQ et al (2004) White organic light-emitting devices using 2,5,2′,5′-tetrakis(4′-biphenylenevinyl)-biphenyl as blue light-emitting layer. Appl Phys Lett 84:4457–4459. doi:10.1063/1.1738179 CrossRefADSGoogle Scholar
  11. Chiodini N, Paleari A, DiMartino D, Spignolo G (2002) SnO2 nanocrystals in SiO2: a wide-band-gap quantum-dot system. Appl Phys Lett 81:1702–1704CrossRefADSGoogle Scholar
  12. CIE Colorimetry (1971) Official recommendations of the International Commission on Illumination. CIE Publication 15, CIE, ParisGoogle Scholar
  13. D’Andrade BW, Thompson ME, Forrest SR (2002) Controlling exciton diffusion in multilayer white phosphorescent organic light emitting devices. Adv Mater 14:147–151CrossRefGoogle Scholar
  14. Dejneka MJ, Snitzer E, Riman RE (1995) Blue, green and red fluorescence and energy transfer of Eu3+ in fluoride glasses. J Lumin 65:227–245. doi:10.1016/0022-2313(95)00073-9 CrossRefGoogle Scholar
  15. del-Castillo J, Rodríguez VD, Yanes AC, Méndez-Ramos J, Torres ME (2005) Luminescent properties of transparent nanostructured Eu3+ doped SnO2-SiO2 glass-ceramics prepared by sol-gel method. Nanotechnology 16:300–303CrossRefADSGoogle Scholar
  16. del-Castillo J, Yanes AC, Méndez-Ramos J, Rodríguez VD (2008a) Luminescence of nanostructured SnO2-SiO2 glass-ceramics. J Nanosci Nanotechnol 8/1:2143–2146CrossRefGoogle Scholar
  17. del-Castillo J, Rodríguez VD, Yanes AC, Méndez-Ramos J (2008b) Energy transfer from the host to Er3+ dopants in semiconductor SnO2 nanocrystals segregated in sol-gel silica glasses. J Nanopart Res 10:499–506CrossRefGoogle Scholar
  18. Feldmann C, Jüstel T, Ronda CR, Schmidt PJ (2003) Inorganic luminescent materials: 100 years of research and application. Adv Funct Mater 13(7):511–516CrossRefGoogle Scholar
  19. Friend RH et al (1999) Electroluminescence in conjugated polymers. Nature 397:121–128CrossRefADSGoogle Scholar
  20. Fujihara S, Mochizuki C, Kimura T (1999) Formation of LaF3 microcrystals in sol-gel silica. J Non-Cryst Solids 244:267–274CrossRefGoogle Scholar
  21. Gouveia-Neto AS, Bueno LA, do Nascimento RF, da Silva EA, da Costa EB, do Nascimento VB (2007) White light generation by frequency up-conversion in Tm3+/Ho3+/Yb3+-codoped fluorolead germanate glass. Appl Phys Lett 91:091114–091117CrossRefADSGoogle Scholar
  22. Li Y, Rizzo A, Cingolani R, Gigli G (2006) Bright white-light-emitting device from ternary nanocrystal composites. Adv Mater 18:2545–2548CrossRefGoogle Scholar
  23. Méndez-Ramos J, Lavín V, Martín IR, Rodríguez-Mendoza UR, Rodríguez VD, Lozano-Gorrín AD, Núñez P (2003) Site selective study of Eu3+-doped transparent oxyfluoride glass-ceramics. J Appl Phys 94:2295–2301CrossRefADSGoogle Scholar
  24. Mueller AH, Petruska MA, Achermann M, Werder DJ, Akhadov EA, Koleske DD, Hoffbauer MA, Klimov VI (2005) Multicolor light-emitting diodes based on semiconductor nanocrystals encapsulated in GaN charge injection layers. Nano Lett 5:1039–1044PubMedCrossRefGoogle Scholar
  25. Nogami M, Enomoto T, Hayakawa T (2002) Enhanced fluorescence of Eu3+ induced by energy transfer from nanosized SnO2 crystals in glass. J Lumin 97:147–152CrossRefGoogle Scholar
  26. Park JR, Lee TW, Kim YC (2005) White polymer light-emitting devices from ternary-polymer blend with concentration gradient. Chem Phys Lett 403:293–297CrossRefADSGoogle Scholar
  27. Rodríguez VD, Tikhomirov VK, Méndez-Ramos J, Seddon AB (2005) The shape of the 1.55 micron emission band of the Er3+-dopant in oxyfluoride nano-scaled glass-ceramics. Europhys Lett 69:128–134CrossRefADSGoogle Scholar
  28. Sheets JR (1997) Stacked organic light-emitting diodes in full color. Science 277:191–192CrossRefGoogle Scholar
  29. Suyver JF, Grimm J, Van Veen MK, Biner D, Krämer KW, Güdel HU (2006) Up-conversion spectroscopy and properties of NaYF4 doped with Er3+, Tm3+ and/or Yb3+. J Lumin 117:1–12CrossRefGoogle Scholar
  30. Tikhomirov VK, Furniss D, Seddon AB, Reaney IM, Beggiora M, Ferrari M, Montagna M, Rolli R (2002) Fabrication and characterization of nanoscale, Er3+-doped, ultratransparent oxy-fluoride glass ceramics. Appl Phys Lett 81:1937–1939CrossRefADSGoogle Scholar
  31. Tsao JY (2002) Light emitting diodes (LEDs) for general illumination—an OIDA Technology Roadmap UpdatedGoogle Scholar
  32. Wang YH, Ohwaki J (1993) New transparent vitroceramics codoped with Er3+ and Yb3+ for efficient frequency upconversion. Appl Phys Lett 63:3628–3630CrossRefGoogle Scholar
  33. Yanes AC, del-Castillo J, Torres ME, Peraza J, Rodríguez VD, Méndez-Ramos J (2004) Nanocrystal-size selective spectroscopy in SnO2:Eu3+ semiconductor quantum-dots. Appl Phys Lett 85:2343–2346CrossRefADSGoogle Scholar
  34. Yanes AC, del-Castillo J, Méndez-Ramos J, Rodríguez VD, Torres ME, Arbiol J (2007) Luminescence and structural characterization of transparent nanostructured Eu3+-doped LaF3-SiO2 glass-ceramics prepared by sol-gel method. Opt Mater 29:999–1003; Rodríguez VD, del-Castillo J, Yanes AC, Méndez-Ramos J, Torres ME, Peraza J (2007) Luminescence of Er3+-doped nanostructured SiO2-LaF3 glass-ceramics prepared by sol-gel method. Opt Mater 29:1557–1561; Velázquez JJ, Yanes AC, del-Castillo J, Méndez-Ramos J, Rodríguez VD (2007) Optical properties of Ho3+-Yb3+ co-doped SiO2-LaF3-glass-ceramics prepared by sol–gel method. Physica Status Solidi (a) 204:1762–1769; Méndez-Ramos J, Velázquez JJ, Yanes AC, del-Castillo J, Rodríguez VD (2008) Up-conversion in nanostructured Yb3+-Tm3+ co-doped sol–gel derived SiO2-LaF3 transparent glass-ceramics. Physica Status Solidi (a) 205:330–334Google Scholar

Copyright information

© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  • J. del-Castillo
    • 1
  • J. Méndez-Ramos
    • 2
  • A. C. Yanes
    • 1
  • V. D. Rodríguez
    • 2
  1. 1.Dpto. Física BásicaUniversidad de La LagunaLa LagunaSpain
  2. 2.Dpto. Física Fundamental y Experimental, Electrónica y SistemasUniversidad de La LagunaLa LagunaSpain

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