Abstract
Doping with transition metal ions in TiO2 has been found effective to modify the electronic structure of TiO2 nanoparticles. Application of synchrotron radiation photoelectron spectroscopy (SRPES) to Nd-doped TiO2 nanoparticles revealed that there existed different peak positions and structure with different doping concentration in the valence band spectra. From the onset of valence band spectrum, it was observed that doping Nd ions alters the electronic structure and makes the band gap of TiO2 narrow.
Similar content being viewed by others
References
Adil F., Christian M., Bernard S. and Mauro C., (1993). Theoretical analysis of the structures of titanium dioxide crystals. Phys. Rev. B 47: 11717Gȴ11724
Anpo M. and Takeuchi M., (2003). The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation. J. Cata. 216(1Gȴ2): 505Gȴ516
Choi W.K., Termin A. and Hoffmann M.R., (1994). The role of metal-ion dopants in quantum-sized TiO2: Correlation between photoreactivity and charge-carrier recombination dynamics. J. Phys. Chem. 98: 13669Gȴ13679
Fumitaka Arai, Kimural Shin-ichi and Ikezawa Mikihiko, (1998). Resonant photoemission study of electronic structure of rare-earth sesquioxides. J. Phys. Soc. Jpn. 67: 225Gȴ229
Lai B., Ding X.M., Yuan Z.L., Zhou X., Liao L.S., Zhang S.K., Yuan S., Hou X.Y., Lu E.D., Xu P.S. and Zhang X.Y., (2000). Synchrotron radiation photoelectron spectroscopy study of ITO surface. Appl. Sur. Sci. 157(1Gȴ2):35Gȴ38
Laurent C.D., Cristian B.S., James D., Kevin E.S., Dimitris K., Theodore D.M., Guo J.H. and Joseph N., (1998). Density of states, hybridization, and band gap evolution in AlxGal-xN alloys. Phys. Rev. B 58: 1928Gȴ1933
Li W., Lin H., Ismat Shah S., Doren D.J., Sergey Rykov A., Chen J.G. and Barteau M.A., (2003). Bandgap tailoring of Nd3+-doped TiO2 nanoparticles. Appl. Phys. Lett. 83: 4143Gȴ4145
Kucherenko Yu., Finken M., Molodtsov S.L., Heber M., Boysen J. and Laubschat C., (2002). Giant hybridization effects in 4f photoemission spectra of Pr and Nd transition-metal compounds. Phys. Rev. B 65:165119Gȴ165122
Matsuo S., Sakaguchi N., Yamada K., Matsuo T., and Wakita H., (2004). Role in photocatalysis and coordination structure of metal ions adsorbed on titanium dioxide particles: A comparison between lanthanide and iron ions. Appl. Surf. Sci. 228(1Gȴ4): 233Gȴ244
Morris D., Dou Y., Rebane J., Mitchell C.E.J., Egdell R.G., Law D.S.L., Vittadini A. and Casarin M., (2000). Photoemission and STM study of the electronic structure of Nd-doped TiO2. Phys. Rev. B 61: 13445Gȴ13457
Ranjit K.T., Cohen H., Willner I., Bossmann S., and Braun A.M., (1999). Lanthanide oxide-doped titanium dioxide: Effective photocatalysts for the degradation of organic pollutants. J. Mater. Sci. 34(21): 5273Gȴ5280
Ranjit K.T., Willner I., Bossmann S.H., and Braun A.M., (2001). Lanthanide oxide-doped titanium dioxide photocatalysts: Novel photocatalysts for the enhanced degradation of p-chlorophenoxyacetic acid. Environ. Sci. Tech. 35(7): 1544Gȴ1549
Sanjin+¬s R., Tang H., Berger H., Gozzo F., Margaritondo G. and L+¬vy F., (1994). Electronic Structure of Anatase TiO2 oxide. J. Appl. Phys. 75(6): 2945Gȴ2951
Sekiyama A., Suga S., Fujikawa M., Imada S., Iwasaki T., Matsuda K., Matsushita T., Kaznacheyev K.V., Fujimori A., Kuwahara H. and Tokura Y., (1999). Electronic states of charge-ordering Nd0.5Sr0.5MnO3 probed by photoemission. Phys. Rev. B 59: 15528Gȴ15532
Umebayashi T., Yamaki T., Sumita T., Yamamoto S., Tanaka S. and Asai K., (2003). UV-ray photoelectron and ab initio band calculation studies on electronic structures of Cr- or Nb-ion implanted titanium dioxide. Nucl. Instrum. Meth. B 206: 264Gȴ267
Acknowledgements
This work was partially supported by National Synchrotron Radiation Laboratory in University of Science and Technology of China.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hou, T., Mao, J., Pan, H. et al. Investigation of electronic structure of Nd-doped TiO2 nanoparticles using synchrotron radiation photoelectron spectroscopy. J Nanopart Res 8, 293–297 (2006). https://doi.org/10.1007/s11051-005-9020-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11051-005-9020-2