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Interatomic Chemical Interactions in Alloys

  • STRUCTURE AND PHASE TRANSFORMATIONS
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Metal Science and Heat Treatment Aims and scope

Results of electron microscope studies of some binary and three-component alloys are analyzed. It is inferred that the chemical interatomic interactions in the alloys occur according to the principle of pair interaction. It is shown that a ternary alloy undergoes separation into diffusion pairs already in the liquid solution. When the temperature of the alloy decreases, particles of a new phase form inside each type of diffusion micropair. It is supposed that the high-entropy alloys, where diffusion micropairs cannot form due to decelerated diffusion of atoms, should not be suitable for industrial applications.

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References

  1. Y. Ustinovshchikov, M. Shirobokova, and B. Pushkarev, “A structural study of the Fe – Cr system alloys,” Acta Mater., 44, 5021 – 5032 (1996).

    Article  Google Scholar 

  2. Y. Ustinovshchikov, “’Chemical’ phase transition in alloys: Ordering – phase separation,” Curr. Opin. Solid State Mater. Sci., 14,7– 20 (2010).

    Article  Google Scholar 

  3. Y. Ustinovshchikov, “Changes in electronic structure of metallic alloys at the transition “ordering – phase separation,” J. Alloys. Compd., 714, 476 – 483 (2017).

    Article  Google Scholar 

  4. Y. Ustinovshchikov, “Phase and structural transformations in the Ni65Mo20Cr15 alloy at changing the temperature of heat treatment,” J. Alloys. Compd., 588, 470 – 473 (2014).

    Article  Google Scholar 

  5. Y. Ustinovshchikov, “Phase transition “ordering – phase separation,” in alloys of Ni – Cr system,” Mat. Chem. Phys., 165, 14 – 18 (2015).

    Article  Google Scholar 

  6. Y. Ustinovshchikov, The “Ordering – Phase Separation” Transition in Alloys, Cambridge Scholars Publishing, Great Britain (2019), 127 p.

    Google Scholar 

  7. E. P. George, D. Raabe, and R. O. Ritchie, “High-entropy alloys,” Nat. Rev. Mater., 4, 515 – 534 (2019).

    Article  CAS  Google Scholar 

  8. Michael C. Gao, Raymundo Arro’yave, John E. Morral, and Ursula R. Kattner, “Thermodynamic and kinetics of high-entropy alloys,” J. Phase Equil. Diffus., 42, 549 – 550 (2021).

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Correspondence to Yu. I. Ustinovshchikov.

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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 9, pp. 3 – 9, September, 2022.

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Ustinovshchikov, Y.I. Interatomic Chemical Interactions in Alloys. Met Sci Heat Treat 64, 485–490 (2023). https://doi.org/10.1007/s11041-023-00839-9

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  • DOI: https://doi.org/10.1007/s11041-023-00839-9

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