The process of precipitation of transition phases in quenched alloys Ti – 14% Mo and VST3553 is studied under aging at from 300 to 500°C. X-ray diffraction phase analysis and transmission electron microscopy are used to detect the presence of a metastable O″-phase in the alloys quenched from the β-range. The morphology of the precipitated particles and the kinetics of formation of the O″-phase are determined. It is shown that phases O′ and/or O″ are continuously associated with precipitation of phase ω and are transition phases up to the temperature of formation of the α-phase, i.e., 500°C.
This is a preview of subscription content, access via your institution.



References
A. A. Il’in, Titanium Alloys. Composition, Structure, Properties. A Reference Book [in Russian], VILS–MATI, Moscow (2009), 520 p.
S. P. Belov, M. Ya. Brun, S. G. Glazunov, et al., Titanium Alloys. Physical Metallurgy of Titanium Alloys [in Russian], Metallurgiya, Moscow (1992), 352 p.
A. A. Popov, “Processes of decomposition of metastable β-phase in high-alloy titanium alloys,” Fiz. Met. Metalloved., 53, 147 – 156 (1993).
A. G. Illarionov, A. A. Popov, S. V. Grib, and O. A. Elkina, “Special features of formation of omega-phase in titanium alloys under quenching,” Metalloved. Term. Obrab. Met., No. 10(664), 39 – 44 (2010).
T. Furuhara, T. Makino, Y. Idei, et al., “Morphology and crystallography of α precipitates in β Ti – Mo binary alloys,” Mater. Trans., 39(1), 31 – 39 (1998).
B. A. Hat and V. G. Rivlin, “Phase transformations in superconducting Ti – Nb alloys,” J. Phys. D: Appl. Phys., 1(9), 1145 – 1149 (1968).
T. Li, M. Lai, A. Kostka, et al., “Composition of the nanosized orthorhombic O′ phase and its direct transformation to fine α during ageing in metastable β-Ti alloys,” Scr. Mater., 170, 183 – 188 (2019).
Y. Zheng, D. Banerjee, and H. L. Frazer, “A nano-scale instability in the _-phase of dilute Ti – Mo alloys,” Scr. Mater., 116, 131 – 134 (2016).
Y. Zhang, R. E. A.Williams, and H. L. Frazer, “Characterization of previously unidentified orthorhombic metastable phase in Ti – 5Al – 5Mo – 5V – 3Cr,” Scr. Mater., 113, 202 – 205 (2016).
A. Antonov, R. Shi, D. Li, et al., “Nucleation and growth of β phase in a metastable β-titanium Ti – 5Al – 5Mo – 5V – 3Cr alloy: Influence from the nano-scale ordered-orthorhombic O″-phase and α compositional evolution,” Scr. Mater., 194, 113672 (2021).
B. Song, Y. Chen, W. Xiao, et al., “Formation of intermediate phases and their influences on the microstructure of high strength near-β titanium alloy,” Mater. Sci. Eng. A, 793, 139886 (2020).
P. Zhaáòal, P. Harcuba, J. Stráský, et al., “Transformation pathway upon heating of metastable β titanium alloy Ti – 15Mo investigated by neutron diffraction,” Materials, 12, 3570 (2019).
A. O. Petrova, A. A. Popov, P. A. Popov, et al., “Precipitation of second phases in heating of quenched alloy Ti – 14% Mo,” Metalloved. Term. Obrab. Met., No. 3, 18 – 22 (2022).
The work has been performed within a state assignment of the Ministry of Science and Higher Education of the Russian Federation (topic No. 0836-2020-0020).
Author information
Authors and Affiliations
Additional information
Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 8, pp. 27 – 32, August, 2022.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Petrova, A.O., Popov, A.A., Lugovaya, K.I. et al. Formation of Intermediate Phases in Decomposition of Metastable B-Phase in Titanium Alloys of Transition Class. Met Sci Heat Treat 64, 446–450 (2022). https://doi.org/10.1007/s11041-022-00829-3
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11041-022-00829-3
Key words
- titanium alloy
- heat treatment
- processes of decomposition of metastable phases
- transition phases
- microstructure