Skip to main content
Log in

Effect of Hydrogen on the Structure and Properties of Eutectic Silumin with 15% Silicon

  • ALUMINUM AND ITS ALLOYS
  • Published:
Metal Science and Heat Treatment Aims and scope

The effect of melt hydrogen treatment on structure, morphology, and on physical and mechanical properties of hypereutectic alloy Al – 15% Si in cast and deformed conditions is studied. A melt is treated with hydrogen by different methods, i.e., with wet asbestos, in a steam atmosphere, and flushing with hydrogen prepared by alkali decomposition with aluminum. Ingots are deformed plastically by open forging and rolling. Alloy microstructure is studied by metallographic, electron microscopic, x-ray diffraction, and dilatometric analyses. Alloy density and microhardness are measured. Alloy atomic hydrogen content is studied by vacuum heating. It is shown that hydrogen treatment improves cast alloy structural parameters and deformability, raises post-deformation strength by a factor of 1.3 – 1.4, and lowers linear expansion coefficient.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

References

  1. G. B. Stroganov, V. A. Rotenburg, and G. B. Gershman, Aluminum Alloys with Silicon [in Russian], Metallurgiya, Moscow (1977).

  2. E. I. Dobatkin and V. I. Elagin, Granulated Aluminum Alloys [in Russian], Metallurgiya, Moscow (1981).

  3. B. G. Gopienko, M. E. Smagoritskii, A. A. Grigor’ev, and A. D. Bezlavin, Sintered Materials Made of Aluminum Alloys [in Russian], Metallurgiya, Moscow (1993).

  4. G. B. Stroganov, Hig-Strength Cast Aluminum Alloys [in Russian], Metallurgiya, Moscow (1985).

  5. V. K. Afanas’ev, A. N. Prudnikov, A. A. Ruzhilo, and M. V. Popova, “Prospects of developing powder eutectic silumins,” Metall. Mashin., No. 4, 16 – 18 (2003).

  6. J. E. Hatch (ed.), Aluminum Properties and Physical Metallurgy: Handbook [in Russian] Metallurgiya, Moscow (1989).

  7. L. F. Mondol’fo, Structure and Properties of Aluminum Alloys [Russian translation], Metallurgiya, Moscow (1979).

  8. I. J. Polmear, Light Alloys: from Traditional Alloys to Nanocrystals, Elsevier Ltd, Amsterdam (2005).

    Google Scholar 

  9. V. S. Zolotarevskii and N. A. Belov, Cast Aluminum Alloy Materials Science [in Russian], MiSIS, Moscow (2005).

  10. V. K. Afanas’ev, M. V. Popova, A. V. Gorshenin, et al., “Nature of plastic deformation processes for alloy Al – 15% Si,” Metall. Mashin., No. 3, 2 – 9 (2014).

  11. V. I. Napalkov, S. V. Makhov, and A. V. Pozdnyakov, Aluminum Alloy Modification [in Russian], MiSIS, Moscow (2017).

  12. A. O. Kuznetzov, D. A. Shadeev, and V. Yu. Konkevich, “Modification of silumins — different approaches for a single alloy system,” Tekhnol. Legk. Splavov, No. 4, 75 – 81 (2014)

  13. J. H. Li, M. Albu, T. H. Ludwig, et al., “Modification of eutectic Si in Al – Si based alloys,” Mater. Sci. Forum, 794 – 796, 130 – 136 (2014) 10.4028www.scientific.netMSF.794-796.130.

  14. Kawther Al-Helal, Yun Wang, Ian Stone, Zhongyun Fan, “Effect of Ca level on the formation of silicon phases during solidification of hypereutectic Al – Si alloys,” Mater. Sci. Forum, 765, 117 – 122 (2013) 10.4028www.scientific.netMSF.765.117.

  15. J. Zhang, H. Chen, H. Yu, and Y. Jin, “Study on dual modification of Al – 17% Si alloys by structural heredity,” Metals, 5, 1112 – 1126 (2015) 10.3390met5021112.

  16. J. Cais, V. Weiss, and J. Svobodova, “Relation between porosity and mechanical properties of Al – Si alloys produced by low-pressure casting,” Archives of Foundry Engineering (2014) (yadda.icm.edu.pl).

  17. S. P. Nikanorov, M. P. Volkov, V. N. Gurin, et al., “Structural and mechanical properties of Al – Si alloys obtained by fast cooling of a levitated melt,” Mater. Sci. Eng. A, 390(1–2), 63 – 69 (2005).

    Article  Google Scholar 

  18. V. C. Srivastava, R. K. Mandal, and S. N. Ojha, “Microstructure and mechanical properties of Al – Si alloys produced by spray forming process,” Mater. Sci. Eng. A, 304 – 306, 555 – 558 (2001).

    Article  Google Scholar 

  19. E. I. Marukovich and V. Yu. Stetsenko, “Modification of primary β-phase crystals of silumin castings,” Metall. Mashin., No. 3, 10 – 12 (2019).

  20. Zu Fangqiu and Li Xiaoyun, “Functions and mechanism of modification elements in eutectic solidification of Al – Si alloys: A brief review,” China Foundry, 11(4), 287 – 295 (2014).

    Google Scholar 

  21. B. A. KOlachev, “Hydrogen in metals and alloys,” Metalloved. Term. Obrab. Met., No. 3, 3 – 11 (1999).

  22. P. D. Hess and G. K. Tumbull, “Effects of hydrogen on properties of aluminum alloys,” in: Paper from Hydrogen in Metals, American Society for Metals (1974), pp. 277 – 287.

  23. G. P. Borisov, “Role f hydrogen in forming aluminum alloy structure and properties,” Metall. Mashin., No. 5, 11 – 20 (2005).

  24. V. A. Goltsov, “Fundamentals of hydrogen treatment of materials,” in: Progress in Hydrogen Treatment of Materials, Coral Gables: Kassiopeya Ltd., Donetsk (2001).

  25. V. K. Afanas’ev and M. V. Popova, “New treatment methods for liquid aluminum alloys with 30 – 50% silicon,” Steel Transl., 31(2), 50 – 53 (2001).

    Google Scholar 

  26. V. K. Afanasyev, M. V. Popova, S. V. Dolgova, et al., “Effect of melt treatment with water vapor on thermal expansion of alloy Al – (20 – 40)% Si,” Metallurgist, 63(1–2), 87 – 95 (2019).

    Article  Google Scholar 

  27. V. K. Afanasyev, A. N. Prudnikov, V. A. Prudnikov, et al., “Deformation, heat treatment and properties of piston hypereutectic silumins,” IOP Conf. Ser.: Mater. Sci. Eng., 866, 1 – 6 (012018) (2020) 10.10881757-899X8661012018.

  28. V. K. Afanasyev, M. N. Churik, M. V. Popova, et al., Hydrogen and Wrought Al(1 – 50)% Si Alloys [in Russian], Izd. Politekh. Univ., St. Petersburg (2016).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. K. Afanas’ev.

Additional information

Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 6, pp. 10 – 16, June, 2022.

Rights and permissions

Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Afanas’ev, V.K., Popova, M.V. & Prudnikov, A.N. Effect of Hydrogen on the Structure and Properties of Eutectic Silumin with 15% Silicon. Met Sci Heat Treat 64, 301–308 (2022). https://doi.org/10.1007/s11041-022-00805-x

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11041-022-00805-x

Keywords

Navigation