X-ray diffractometry with mathematical processing of the diffraction patterns by the Tikhonov method of regularization, which enhances the resolution, is used to study the phase state in Nd – Fe – Co – B – Zr-base alloys during the reverse reaction of HDDR process at different hydrogen pressures. The range of hydrogen pressures in which the reverse reaction (recombination) of the HDDR process develops fully is determined experimentally.
Similar content being viewed by others
References
H. Yamomoto, S. Hirosawa, S. Fujimura, et al., “Metallographic study on Nd – Fe – Co – B sintered magnet,” J. IEEE Trans. Magn., 23(5), 2100 – 2006 (1987).
P. P. Pashkov, D. V. Pakrovskii, and A. A. Fridman, “Phase diagram of the Fe – Nd – B system and special features of the structure of its alloys,” in: Abstr. IX All-Union Conf. on Permanent Magnets, Suzdal, 20 – 23.IX.1988 [in Russian], Infelectro, Moscow (1988), Vol. 2, pp. 93 – 120.
T. Takeshita and R. Nakayama, Proc. 11th Int. Workshop on Rare-Earth Magnets and Their Applications, Carnegie-Mellon University, Pittsburgh (1990), pp. 49 – 63.
H. Nakamura, R. Suefuji, S. Sujimoto, et al., “Effects of HDDR treatment conditions on magnetic properties of Nd – Fe – B anisotropic powders,” J. Appl. Phys., 76(10), 6828 – 6831 (1994).
V. V. Kotunov and D. A. Shumakov, “Highly anisotropic powders of alloys of the Nd – Fe – B system with magnetic energy up to 27 MGOe obtained by the method of hydration-dehydration,” Metalloved. Term. Obrab. Met., No. 4, 30 – 33 (2005).
R. S. Sheridan, R. Sillitoe, M. Zakotnik, et al., “Anisotropic powder from NdFeB magnets by the HDDR processing route,” School Metal. Mater., University of Birmingham, Edgbaston, Birmingham B15 2TT, United Kingdom, J. Magn. Magn. Mater., 324(1), 63 – 67 (2012).
P. M. Ahmed and I. R. Harris, “Improvement of microstructure and magnetic properties of Nd – Fe – B alloys by Nb and Co additions,” School Metal. Mater., University of Birmingham, Edgbaston, Birmingham B15 2TT, United Kingdom, J. Magn. Magn. Mater., 320(21), 2808 – 2813 (2008).
B. E. Vintaikin and R. N. Kuz’min, “Isolation of instrumental widening and of Kα2 component and Kα doublet on two-dimensional maps of distribution of the intensity of scattering of x-ray beams by direct variational computer methods,” Kristallografiya, 31(4), 656 – 660 (1986).
B. E. Vintaikin and A. A. Loboiko, “Structural states in Fe – Nd – B-base alloys during HDDR process,” Fundam. Prob. Radioelecktr. Priborostr., 13, 141 – 142 (2013).
M. Xing, J. Han, Z. Lin, et al., “Anisotropic Ce13Fe80B7 powders prepared by hydrogenation-disproportionation-desorption-recombination process and the diffusion of Ce – Cu eutectic alloys,” J. Magn. Magn. Mater., 331, 140 – 143 (2013).
R.-C. He, F.-L. Wang, and J.-F. Hu, “Magnetic moment angle error and alignment degree of sintered Nd – Fe – B magnet,” J. Func. Mater.: Gongneng Cailiao, 43(20, 30), 2863 – 2866 (2012).
Y. Ma, D. Chen, A. Zhou, et al., “Enhanced alignment and magnetic properties of die-upset nano-crystal Nd2Fe14B magnets with Nb addition,” Phys. B: Cond. Mat., 407(23), 4562 – 4566 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 9, pp. 53 – 55, September, 2020.
Rights and permissions
About this article
Cite this article
Vintaikin, B.E., Boruta, V.S. & Litvinov, O.S. Effect of Hydrogen Pressure in the Stage of Recombination of HDDR Process on Phase Equilibrium in Nd – Fe – Co – B – Zr-Base Alloys. Met Sci Heat Treat 62, 594–596 (2021). https://doi.org/10.1007/s11041-021-00608-6
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11041-021-00608-6