The structure and mechanical properties of an ultrahigh-carbon steel modified with amorphous ferrosilicon with a low melting point are studied. The methods of x-ray diffraction, optical and scanning electron microscopy are used to study the effect of the amorphous modifier on the structure of eutectic ledeburite in the cast steel. Tests for tensile strength and impact toughness are conducted. It is shown that the mechanical properties increase as a result of the modification without subsequent heat treatment.
Similar content being viewed by others
References
O. D. Sherby, B. Walser, and C. M. Young, “Superplastic ultra- high carbon steels,” Scr. Metall., 9, 569 – 573 (1975).
H. Sunada, J. Wadsworth, and J. Lin, “Mechanical properties and microstructure of heat-treated ultrahigh carbon steels,” Mater. Sci. Eng., 38, 35 (1979).
D. R. Lesuer, C. K. Syn, and A. Goldberg, “The case for ultrahigh- carbon steels as structural materials, JOM, 45, 40 – 46 (1993).
C. K. Syn, D. R. Lesuer, and O. D. Sherby, “Influence of microstructure on tensile properties of spheroidized ultrahigh-carbon steel,” Mater. Sci. Eng. A, 25, 1481 – 1493 (1994).
J. C. Zhang, Y. J. Lin, and M. Hillert, “Microstructure and mechanical properties of spray formed ultrahigh-carbon steels,” Mater. Sci. Eng. A, 383, 45 – 49 (2004).
S. Szczepanik, P. Nikiel, and S. C. Mitchell, “Microstructure evolution in warm forged sintered ultrahigh carbon steel,” Arch. Civ. Mech. Eng., 15, 301 – 307 (2015).
T. Oyama, O. D. Sherby, and J. Wadsworth, “Application of the divorced eutectoid transformation to the development of fine-grained, spheroidized structures in ultrahigh carbon steels,” Scr. Metall., 18, 799 – 804 (1984).
Y. Chen, S. Shi, and J. Sun, “Influence of spheroidization process on microstructure and mechanical properties of ultrahigh carbon steel Fe – 1.3C – 1.5Cr – 1.5Al,” Mater. Sci. Eng. (2015).
M. Hull, “Spray forming poised to enter mainstream,” Powder Metall., 40, 23 – 26 (1977).
W. J. Kim, E. M. Taleff, and O. D. Sherby, “Superplasticity of fine-grained Fe – C alloys prepared by ingot- and powder processing routes,” J. Mater. Sci., 33, 4977 – 4985 (1988).
R. Q. Brooks, C. Moore, and A. G. Leatham, “The Osprey process,” Powder Metall., 2, 100 – 102 (1977).
E. M. Taleff, C. K. Syn, and D. R. Lesuer, “Pearlite in ultrahigh carbon steels: Heat treatments and mechanical properties,” Metall. Mater. Trans. A, 27, 111 (1995).
J. Wang, H. S. Shi, and J. G. Zhang, “High-stain-rate superplasticity of big grains in spray forming ultrahigh carbon steel containing 1.6 wt.% Al,” Adv. Mater. Res., 535 – 537, 639 – 642, (2012).
F. Z. Pan, H. Yang, and J. L. Jiao, “Effect of K/Na-RE multiple modification on structure and mechanical property of highspeed steel used for roll collar,” Foundry, 55, 164 (2006).
K. P. Liu, X. L. Dun, and J. P. Lai, “Effects of modification on microstructure and properties of ultrahigh carbon (1.9 wt.% C) steel,” Mater. Sci. Eng. A, 528, 8263 – 8268 (2011).
S. C. Liu, S. S. Dong, and F. Yang, “Application of quenching- partitioning-tempering process and modification to a newly designed ultrahigh carbon steel,” Mater. Des., 56, 37 – 43 (2014).
J. M. Wang, H. Zhu, and S. Yang, “Effects of rare earth modification on structures and properties of low-alloy cast steel,” Foundry, 2, 57 – 64 (2007).
Q. F. Guan, J. R. Fang, and Q. C. Liang, “Effect of rare earth composite modification on microstructure and properties of a new cast hot-work die steel,” J. Rare Earths, 21, 368 – 371 (2003).
L. Lei, H. Bin, and L. Sheng-gen, “Effect of Mo on mechanical properties of modified ultrahigh carbon steels after heat treatment,” J. Cent. South. Univ., 21, 1683 – 1688 (2014).
H. Dadkhah, “Microstructure of cast ultrahigh carbon steel (UHCS) modified via Fe – Si – Mg – Ca – RE,” Trans. Inst. Min. Met., 67, 1001 – 1004 (2014).
H. Liu, X. H. Kong, and Y. H. Sun, “Dynamic continuous cooling transformation of supercooled austenite in spring steel 55SiCrA,” Trans. Mat. Heat Treat., 32, 73 – 77 (2011).
Q. S. Liu, M. J. Zhao, and H. X. Zhang, “The novel technique of grain refinement in the aluminum-free ultrahigh carbon steel,” Steel Res. Int., 1444 – 1449 (2016).
C. X. Hong, S. Q. Wang, and W. U. Hong, “Granulation of eutectic carbide through heat-treatment in modified ledeburite steel,” J. Jilin Univ. Technol., 32, 42 – 46 (2002).
The work has been supported by research project No. 15JCTPJC64600 “Tianjin Science and Technology Support Project of China” and by the National Natural Science Foundation of China (No. 51601126).
Author information
Authors and Affiliations
Additional information
Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 9, pp. 18 – 21, September, 2019.
Rights and permissions
About this article
Cite this article
Liu, Q., Wang, F., Zhang, X. et al. Novel Method for Refining Coarse Eutectic Carbides in Ultrahigh-Carbon Steel. Met Sci Heat Treat 61, 543–546 (2020). https://doi.org/10.1007/s11041-020-00458-8
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11041-020-00458-8