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Effect of SiO2 Nanoparticles and Soluble Silicate on the Composition and Properties of Oxide Layers Formed by Microarc Oxidizing on Magnesium Mg96

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Metal Science and Heat Treatment Aims and scope

Oxide layers deposited on magnesium by microarc oxidizing with introduction of different silicon-containing components, i.e., nanoparticles of SiO2 and Na2SiO3 sodium metasilicate, into the electrolyte are studied. The effects due to individual and joint use of these substances as components of the electrolyte are compared. It is shown that the best wear resistance of the oxide layers is provided after addition of SiO2 nanoparticles into the electrolyte, and the best corrosion resistance is obtained due to joint introduction of SiO2 nanoparticles and sodium metasilicate. The mechanisms of interaction between SiO2 nanoparticles and the forming oxide layer are suggested.

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References

  1. D. Hanshan, Surface engineering of light alloys. Aluminum, Magnesium and Titanium Alloys, Woodhead Publishing Limited (2010).

  2. Y. Chen, Y. Yang, T. Zhang, et al., “Interaction effect between different constituents in silicate-containing electrolyte on PEO coatings on Mg alloy,” Surf. Coat. Technol., 307, Pt. A, 825 – 836 (2016).

  3. A. Ghasemi, V. S. Raja, C. Blawert, et al., “The role of anions in the formation and corrosion resistance of the plasma electrolytic oxidation coatings,” Surf. Coat. Technol., 204(9 – 10), 1469 – 1478 (2010).

    Article  CAS  Google Scholar 

  4. X. Lu, S. P. Sah, N. Scharnagl, et al., “Degradation behavior of PEO coating on AM50 magnesium alloy produced from electrolytes with clay particle addition,” Surf. Coat. Technol., 269, 155 – 169 (2015).

    Article  CAS  Google Scholar 

  5. X. Lu, M. Mohedano, C. Blawert, et al., “Plasma electrolytic oxidation coatings with particle additions – A review,” Surf. Coat. Technol., 307, 1165 – 1182 (2016).

    Article  CAS  Google Scholar 

  6. X. Lu, C. Blawert, Y. Huang, et al., “Plasma electrolytic oxidation coatings on Mg alloy with addition of SiO2 particles,” Electrochim. Acta, 187, 20 – 33 (2016).

    Article  CAS  Google Scholar 

  7. X. Lu, C. Blawert, K. U. Kainer, and M. L. Zheludkevich, “Investigation of the formation mechanisms of plasma electrolytic oxidation coatings on Mg alloy AM50 using particles,” Electrochim. Acta, 196, 680 – 691 (2016).

    Article  CAS  Google Scholar 

  8. X. Lu, C. Blawert, M. L. Zheludkevich, and K. U. Kainer, “Insights into plasma electrolytic oxidation treatment with particle addition,” Corros. Sci., 101, 201 – 207 (2015).

    Article  CAS  Google Scholar 

  9. S. V. Gnedenkov, S. L. Sinebryukhov, D. V. Mashtalyar, et al., “Fabrication of coatings on the surface of magnesium alloy by plasma electrolytic oxidation using ZrO2 and SiO2 nanoparticles,” J. Nanomater., No. 196 (2015).

  10. M. M. Krishtal, A. V. Polunin, P. V. Ivashin, et al., “Changes in the phase composition of oxide layers produced by microarc oxidation on Al – Si and Mg alloys induced by additions of SiO2 nanoparticles to the electrolyte,” Dokl. Phys. Chem., 469(1), 93 – 96 (2016).

    Article  CAS  Google Scholar 

  11. S. V. Gnedenkov, O. A. Khrisanfova, A. G. Zavidnaya, et al., “PEO coatings obtained on an Mg – Mn type alloy under unipolar and bipolar modes in silicate-containing electrolytes,” Surf. Coat. Technol., 204, 2316 – 2322 (2010).

    Article  CAS  Google Scholar 

  12. M. V. Sidorova, S. L. Sinebryukhov, O. A. Khrisanfova, and S. V. Gnedenkov, “Effect PEO-modes on the electrochemical and mechanical properties MA8 magnesium alloy,” Phys. Proc., 23, 90 – 93 (2012).

    Article  CAS  Google Scholar 

  13. Yu. A. Abzaev, N. O. Kopanitsa, V. A. Klimenov, et al., “Simulation of structural state of amorphous tarñosil,” Vest. Tomsk. Gos. Arkhitect.-Stroit. Univers., No. 3(50), 121 – 133 (2015).

  14. A. V. Chichinadze, A. V. Berliner, E. M. Chichinadze, et al., Friction, Wear and Lubrication (Tribology and Triboengineering) [in Russian], Mashinostroenie, Moscow (2003), 576 p.

  15. X. Lu, C. Blawert, M. Mohedano, et al., “Influence of electrical parameters on particle uptake during plasma electrolytic oxidation processing of AM50 Mg alloy,” Surf. Coat. Technol., 289, 179 – 185 (2016).

    Article  CAS  Google Scholar 

  16. L. Zu, Y. Lu, and W. Li, “Influence of silica sol particle behavior on the magnesium anodizing process with different anions addition,” Surf. Coat. Technol., 202(24), 5853 – 5857 (2008).

  17. G. Rapheal, S. Kumar, N. Scharnagl, and C. Blawert, “Effect of current density on the microstructure and corrosion properties of plasma electrolytic oxidation (PEO) coatings on AM50 Mg alloy produced in an electrolyte containing clay additive,” Surf. Coat. Technol., 289, 150 – 164 (2016).

    Article  CAS  Google Scholar 

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The work has been performed with financial support of the Russian Foundation for Basic Research and of the Samara Regional Research and Education Association with Scientific Project No. 16-48-630785“p a”.

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Authors and Affiliations

  1. Tolyatti State University, Tolyatti, Russia

    M. M. Krishtal, P. V. Ivashin, A. V. Polunin, E. D. Borgardt & P. A. Glukhov

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  1. M. M. Krishtal
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  2. P. V. Ivashin
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  3. A. V. Polunin
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  4. E. D. Borgardt
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  5. P. A. Glukhov
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Correspondence to M. M. Krishtal.

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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 3, pp. 8 – 16, March, 2019.

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Krishtal, M.M., Ivashin, P.V., Polunin, A.V. et al. Effect of SiO2 Nanoparticles and Soluble Silicate on the Composition and Properties of Oxide Layers Formed by Microarc Oxidizing on Magnesium Mg96. Met Sci Heat Treat 61, 149–156 (2019). https://doi.org/10.1007/s11041-019-00391-5

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  • DOI: https://doi.org/10.1007/s11041-019-00391-5

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