The ferroelectric properties of the surface of SrTiO3 strontium titanate ceramics are studied by the method of piezoresponse force microscopy. It is shown that polar nanoareas exist in the surface layer of the SrTiO3 ceramics in the temperature range of 8 – 295 K. The results of thermodynamic computations are presented, which reflect the important role of crystal lattice deformations and oxygen vacancies in the low-temperature evolution of the piezoelectric response of the near-surface layers of the SrTiO3 ceramics.
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The authors are grateful to Professor N. A. Pertsev for the discussion and consultations.
References
O. E. Kvyatkovskii, “Quantum effects in virtual and low-temperature ferroelectric materials,” Fiz. Tverd. Tela, 43(8), 1345 – 1362 (2001).
G. Sorge, E. Hegenbarth, and G. Schmidt, “Mechanical relaxation and nonlinearity in strontium titanate single crystal,” Phys. Stat. Sol. (b), 37(2), 599 – 603 (1970).
K. A. Muller, W. Berlinger, and E. Tosatti, “Indication for a novel phase in the quantum paraelectric regime of SrTiO3,” Z. Phys. B. Condensed Matter, 84, 277 – 283 (1991).
O.-M. Nes, K. A. Muller, T. Suzuki, and F. Fossheim, “Elastic anomalies in the quantum paraelectric regime of SrTiO3,” Europhys. Lett., 19, 397 – 403 (1992).
E. V. Balashova, V. V. Lemanov, R. Kunze, et al., “Ultrasonic study on the tetragonal and Muller phase in SrTiO3,” Ferroelectrics, 183, 75 – 83 (1996).
K. A. Muller, “Macroscopic quantum phenomena,” Ferroelectrics, 183, 11 – 24 (1996).
E. Curtens, “Is there an unusual condensation in quantum paraelectrics?” Ferroelectrics, 183, 25 – 38 (1996).
R. C. Neville, B. Hoeneisen, and C. A. Mead, “Permittivity of strontium titanate,” J. Appl. Phys., 43(5), 2124 – 2135 (1972).
S. O. Lukianov, N. V. Andreeva, S. V. Vakhrushev, et al., “Surface polar nanoregions structure of potassium titanate doped with lithium obtained at cryogenic temperatures using piezoresponse force microscopy technique,” St. Petersburg State Polytech. Univ. J., Phys. Math., No. 4-2(182), 84 – 89 (2013).
A. Kholkin, I. Bdikin, T. Ostapchuk, and J. Petzelt, “Room temperature surface piezoelectricity in SrTiO3 ceramics via piezoresponse force microscopy,” Appl. Phys. Lett., 93, 222905–1 – 222905–3 (2008).
A. K. Tagantsev, “Pyro-, piezo-, flexoelectric and thermopolarization effects in ionic crystals,” Usp. Fiz. Nauk, 152, 423 – 448 (1987).
T. Mitsui and W. B. Westphal, “Dielectric and x-ray studies of Ca x Ba1 – x TiO3 and Ca x Sr1 – x TiO3, Phys. Rev., 124, 1354 – 1359 (1961).
H. Uwe and T. Sakido, “Stress-induced ferroelectricity and soft phonon modes in SrTiO3, Phys. Rev. B, 13, 271 – 286 (1976).
N. A. Pertsev, A. K. Tagantsev, and N. Setter, “Phase transitions and strain-induced ferroelectricity in SrTiO3 epitaxial thin films,” Phys. Rev. B, 61, R825 – R829 (2000).
J. H. Haeni, P. Irvin,W. Chang, et al., “Room-temperature ferroelectricity in strained SrTiO3,” Nature (London), 430, 758 – 761 (2004).
M. Tyunina, J. Narkilahti, M. Plekh, et al., “Evidence for strain-induced ferroelectric order in epitaxial thin-film KTaO3,” Phys. Rev. Lett., 104, 227601 – 227605 (2010).
N. A. Pertsev, A. G. Zembilgotov, and A. K. Tagantsev, “Effect of mechanical boundary conditions on phase diagrams of epitaxial ferroelectric thin films,” Phys. Rev. Lett., 80, 1988 – 1991 (1998).
H. Thomas and K. A. Muller, “Structural phase transitions in perovskite-type crystals,” Phys. Rev. Lett., 21, 1256 – 1259 (1968).
J. C. Slonczewski and H. Thomas, “Interaction of elastic strain with the structural transition of strontium titanate,” Phys. Rev. B, 1, 3599 – 3608 (1970).
E. Heifets, R. I. Eglitis, E. A. Kotomin, et al., Ab initio modeling of surface structure for SrTiO3 perovskite crystals,” Phys. Rev. B, 64, 235417–1 – 235417–5 (2001).
J. Petzelt, T. Ostapchuk, I. Gregora, et al., “Dielectric, infrared, and Raman response of undoped SrTiO3 ceramics: evidence of polar grain boundaries,” Phys. Rev. B, 64, 184111–1 – 184111–10 (2001).
S. V. Kalinin, A. N. Morozovska, L. Q. Chen, et al., “Local polarization dynamics in ferroelectric materials,” Rep. Prog. Phys., 73, Art. 056502 (2010).
W. Gong, H. Yun, Y. B. Ning, et al., “Oxygen-deficient SrTiO3 – x , x = 0.28, 0.17, and 0.08. Crystal growth, crystal structure, magnetic and transport properties,” J. Solid State Chem., 90, 320 – 330 (1991).
Y. S. Kim, J. Y. Jo, T. H. Kim, et al., “Observation of homogeneous domain nucleation in epitaxial Pb(Zr, Ti))3 capacitors,” Appl. Phys. Lett., 91, 132903 – 132903–3 (2007).
N. D. Browning, J. P. Buban, H. O. Moltaji, et al., “The influence of atomic structure on the formation of electrical barriers at grain boundaries in SrTiO3,” Appl. Phys. Lett., 74, 2638 – 2640 (1999).
N. V. Andreeva, M. Tyunina, A. V. Filimonov, et al., “Low-temperature evolution of local polarization properties of PbZr0.65Ti0.35O3 thin films probed by piezoresponse force microscopy,” Appl. Phys. Lett., 104, 112905 (2014).
A. K. Tagantsev, K. Vaideeswaran, S. B. Vakhrushev, et al.,“The origin of antiferroelectricity in PbZrO3,” Nature Communic., 4, Art. 3229 (2013).
The work has been performed with support of the Program for Raising International Competitiveness of the St. Petersburg State Polytechnic University.
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Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 10, pp. 48 – 53, October, 2014.
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Andreeva, V.N., Filimonov, A.V., Rudskoy, A.I. et al. A Study of the Physical Properties of Strontium Titanate Ceramics in the Temperature Range of 8 – 295 K by the Method of Piezoresponse Force Microscopy. Met Sci Heat Treat 56, 564–569 (2015). https://doi.org/10.1007/s11041-015-9800-y
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DOI: https://doi.org/10.1007/s11041-015-9800-y